Development of Lithium Dimethyl Phosphate as an Electrolyte Additive for Lithium Ion Batteries

Milien, Mickdy S.; Tottempudi, Usha; Son, Miyoung; Ue, Makoto; Lucht, Brett L.

doi:10.1149/2.1131607jes

Development of Lithium Dimethyl Phosphate as an Electrolyte Additive for Lithium Ion Batteries

Journal Article · Wed Apr 27 00:00:00 EDT 2016 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.1131607jes· OSTI ID:1437261

Milien, Mickdy S. ^[1]; Tottempudi, Usha ^[2]; Son, Miyoung ^[3]; Ue, Makoto ^[3]; Lucht, Brett L. ^[2]

Univ. of Rhode Island, Kingston, RI (United States). Department of Chemistry; Univ Rhode Isl, Dept Chem, Kingston, RI 02881 USA
Univ. of Rhode Island, Kingston, RI (United States). Department of Chemistry
Battery R&D Center, Samsung SDI, Yeongtong-gu, Suwon-si (South Korea)

The novel electrolyte additive lithium dimethyl phosphate (LiDMP) has been synthesized and characterized. Incorporation of LiDMP (0.1% wt) into LiPF₆ in ethylene carbonate (EC) / ethyl methyl carbonate (EMC) (3:7 wt) results in improved rate performance and reduced impedance for graphite / LiNi_1/3Mn_1/3Co_1/3O₂ cells. Ex-situ surface analysis of the electrodes suggests that incorporation of LiDMP results in a modification of the solid electrolyte interphase (SEI) on the anode. A decrease in the concentration of lithium alkyl carbonates and an increase in the concentration of lithium fluoro phosphates are observed. The change in the anode SEI structure is responsible for the increased rate performance and decreased cell impedance.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Rhode Island, Kingston, RI (United States). Department of Chemistry

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0007074

OSTI ID:: 1437261

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 7 Vol. 163; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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