Development of Lithium Dimethyl Phosphate as an Electrolyte Additive for Lithium Ion Batteries

Milien, Mickdy S.; Tottempudi, Usha; Son, Miyoung; Ue, Makoto; Lucht, Brett L.

doi:10.1149/2.1131607jes

Title: Development of Lithium Dimethyl Phosphate as an Electrolyte Additive for Lithium Ion Batteries

Journal Article · Wed Apr 27 00:00:00 EDT 2016 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.1131607jes· OSTI ID:1437261

Milien, Mickdy S. ^[1]; Tottempudi, Usha ^[1]; Son, Miyoung ^[2]; Ue, Makoto ^[2]; Lucht, Brett L. ^[1]

Univ. of Rhode Island, Kingston, RI (United States). Department of Chemistry
Battery R&D Center, Samsung SDI, Yeongtong-gu, Suwon-si (South Korea)

The novel electrolyte additive lithium dimethyl phosphate (LiDMP) has been synthesized and characterized. Incorporation of LiDMP (0.1% wt) into LiPF₆ in ethylene carbonate (EC) / ethyl methyl carbonate (EMC) (3:7 wt) results in improved rate performance and reduced impedance for graphite / LiNi_1/3Mn_1/3Co_1/3O₂ cells. Ex-situ surface analysis of the electrodes suggests that incorporation of LiDMP results in a modification of the solid electrolyte interphase (SEI) on the anode. A decrease in the concentration of lithium alkyl carbonates and an increase in the concentration of lithium fluoro phosphates are observed. The change in the anode SEI structure is responsible for the increased rate performance and decreased cell impedance.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Rhode Island, Kingston, RI (United States). Department of Chemistry

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0007074

OSTI ID:: 1437261

Journal Information:: Journal of the Electrochemical Society, Vol. 163, Issue 7; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 11 works

Citation information provided by
Web of Science

References (17)

Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries Verma, Pallavi; Maire, Pascal; Novák, Petr Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341 https://doi.org/10.1016/j.electacta.2010.05.072	journal	September 2010
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267 https://doi.org/10.1021/jp3118055	journal	January 2013
Development of true prismatic lithium-ion cells for high rate and low temperature applications Puglia, Frank; Gitzendanner, R.; Marsh, C. Journal of Power Sources, Vol. 96, Issue 1 https://doi.org/10.1016/S0378-7753(01)00564-X	journal	June 2001
Kinetics of Lithium Ion Transfer at the Interface between Graphite and Liquid Electrolytes: Effects of Solvent and Surface Film Yamada, Yuki; Iriyama, Yasutoshi; Abe, Takeshi Langmuir, Vol. 25, Issue 21 https://doi.org/10.1021/la901829v	journal	November 2009
Safe and fast-charging Li-ion battery with long shelf life for power applications Zaghib, K.; Dontigny, M.; Guerfi, A. Journal of Power Sources, Vol. 196, Issue 8 https://doi.org/10.1016/j.jpowsour.2010.11.093	journal	April 2011
Fluorinated phosphazene co-solvents for improved thermal and safety performance in lithium-ion battery electrolytes Rollins, Harry W.; Harrup, Mason K.; Dufek, Eric J. Journal of Power Sources, Vol. 263 https://doi.org/10.1016/j.jpowsour.2014.04.015	journal	October 2014
Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium–ion cells for EV applications Menkin, S.; Golodnitsky, D.; Peled, E. Electrochemistry Communications, Vol. 11, Issue 9 https://doi.org/10.1016/j.elecom.2009.07.019	journal	September 2009
Lithium Tetrafluoro Oxalato Phosphate as Electrolyte Additive for Lithium-Ion Cells Qin, Yan; Chen, Zonghai; Liu, Jun Electrochemical and Solid-State Letters, Vol. 13, Issue 2 https://doi.org/10.1149/1.3261738	journal	January 2010
Lithium-Ion Electrolytes Containing Ester Cosolvents for Improved Low Temperature Performance Smart, M. C.; Ratnakumar, B. V.; Chin, K. B. Journal of The Electrochemical Society, Vol. 157, Issue 12 https://doi.org/10.1149/1.3501236	journal	January 2010
Effect of propane sultone on elevated temperature performance of anode and cathode materials in lithium-ion batteries Xu, Mengqing; Li, Weishan; Lucht, Brett L. Journal of Power Sources, Vol. 193, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.03.067	journal	September 2009
Understanding the interactions of phosphonate-based flame-retarding additives with graphitic anode for lithium ion batteries Feng, Jinkui; Ma, Peng; Yang, Hanxi Electrochimica Acta, Vol. 114 https://doi.org/10.1016/j.electacta.2013.10.104	journal	December 2013
Nonflammable Electrolytes for Lithium-Ion Batteries Containing Dimethyl Methylphosphonate Dalavi, Swapnil; Xu, Mengqing; Ravdel, Boris Journal of The Electrochemical Society, Vol. 157, Issue 10, p. A1113-A1120 https://doi.org/10.1149/1.3473828	journal	January 2010
Evaluation of Fluorinated Alkyl Phosphates as Flame Retardants in Electrolytes for Li-Ion Batteries: I. Physical and Electrochemical Properties Xu, Kang; Ding, Michael S.; Zhang, Shengshui Journal of The Electrochemical Society, Vol. 150, Issue 2 https://doi.org/10.1149/1.1533040	journal	January 2003
A combination of lithium difluorophosphate and vinylene carbonate as reducible additives to improve cycling performance of graphite electrodes at high rates Kim, Ko-Eun; Jang, Jun Yeong; Park, Inbok Electrochemistry Communications, Vol. 61 https://doi.org/10.1016/j.elecom.2015.10.013	journal	December 2015
Atomic Layer Deposition of the Solid Electrolyte LiPON Kozen, Alexander C.; Pearse, Alexander J.; Lin, Chuan-Fu Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b01654	journal	July 2015
Role of 1,3-Propane Sultone and Vinylene Carbonate in Solid Electrolyte Interface Formation and Gas Generation Zhang, Bo; Metzger, Michael; Solchenbach, Sophie The Journal of Physical Chemistry C, Vol. 119, Issue 21 https://doi.org/10.1021/acs.jpcc.5b00072	journal	May 2015

Cited By (1)

Lithium Bis(2,2,2-trifluoroethyl)phosphate Li[O ₂ P(OCH ₂ CF ₃ ) ₂ ]: A High Voltage Additive for LNMO/Graphite Cells Milien, Mickdy S.; Beyer, Hans; Beichel, Witali Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0541811jes	journal	January 2018

Similar Records

Improving the Performance at Elevated Temperature of High Voltage Graphite/LiNi_0.5Mn_1.5O₄ Cells with Added Lithium Catechol Dimethyl Borate

Journal Article · Tue Dec 13 00:00:00 EST 2016 · Journal of the Electrochemical Society · OSTI ID:1437261

Dong, Yingnan; Demeaux, Julien; Zhang, Yuzi; +4 more

New promising lithium malonatoborate salts for high voltage lithium ion batteries

Journal Article · Thu Dec 01 00:00:00 EST 2016 · Journal of Materials Chemistry. A · OSTI ID:1437261

Sun, Xiao -Guang; Wan, Shun; Guang, Hong Yu; +4 more

Investigating the Chemical Reactivity of Lithium Silicate Model SEI Layers

Journal Article · Thu Mar 19 00:00:00 EDT 2020 · Journal of Physical Chemistry. C · OSTI ID:1437261

Coyle, Jaclyn E.; Brumbach, Michael T.; Veith, Gabriel M.; +1 more

Related Subjects

36 MATERIALS SCIENCE
25 ENERGY STORAGE
Additives
Electrolyte
Solid Electrolyte Interphase

Title: Development of Lithium Dimethyl Phosphate as an Electrolyte Additive for Lithium Ion Batteries

Citation Formats

References (17)

Cited By (1)

Similar Records

Related Subjects