New promising lithium malonatoborate salts for high voltage lithium ion batteries

Sun, Xiao -Guang; Wan, Shun; Guang, Hong Yu; Fang, Youxing; Reeves, Kimberly Shawn; Chi, Miaofang; Dai, Sheng

doi:10.1039/C6TA07757A

New promising lithium malonatoborate salts for high voltage lithium ion batteries

Journal Article · Thu Dec 01 00:00:00 EST 2016 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C6TA07757A· OSTI ID:1344276

Sun, Xiao -Guang ^[1]; Wan, Shun ^[1]; Guang, Hong Yu ^[2]; Fang, Youxing ^[3]; Reeves, Kimberly Shawn ^[1]; Chi, Miaofang ^[1]; Dai, Sheng ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Northeast Normal Univ., Changchun (People's Republic of China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Here, three new lithium salts, lithium difluoro-2-methyl-2-fluoromalonaoborate (LiDFMFMB), lithium difluoro-2-ethyl-2-fluoromalonaoborate (LiDFEFMB), and lithium difluoro-2-propyl-2-fluoro malonaoborate (LiDFPFMB), have been synthesized and evaluated for application in lithium ion batteries. These new salts are soluble in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.) and 1.0 M salt solutions can be easily prepared. The ionic conductivities of these new salts are close to those of LiBF₄ and LiPF₆. Cyclic voltammograms reveal that these new salt based electrolytes can passivate both natural graphite and high voltage spinel LiNi_0.5Mn_1.5O₄ (LNMO) to form effective solid electrolyte interphases (SEIs). In addition, these new salts based electrolytes exhibit good cycling stability with high coulombic efficiencies in both LiNi_0.5Mn_1.5O₄ and graphite based half-cells and full cells.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1344276

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 3 Vol. 5; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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