All-acrylic superelastomers: facile synthesis and exceptional mechanical behavior

Lu, Wei; Goodwin, Andrew; Wang, Yangyang; Yin, Panchao; Wang, Weiyu; Zhu, Jiahua; Wu, Ting; Lu, Xinyi; Hu, Bin; Hong, Kunlun; Kang, Nam-Goo; Mays, Jimmy

doi:10.1039/C7PY01518F

All-acrylic superelastomers: facile synthesis and exceptional mechanical behavior

Journal Article · Sun Dec 31 23:00:00 EST 2017 · Polymer Chemistry

DOI:https://doi.org/10.1039/C7PY01518F· OSTI ID:1418062

^[1]; Goodwin, Andrew ^[1]; Wang, Yangyang ^[2]; ^[3]; Wang, Weiyu ^[2]; Zhu, Jiahua ^[2]; Wu, Ting ^[4]; Lu, Xinyi ^[1]; ^[4]; ^[2]; ^[1]; Mays, Jimmy ^[1]

Department of Chemistry; University of Tennessee; Knoxville; USA
Center for Nanophase Materials Sciences; Oak Ridge National Laboratory; Oak Ridge; USA
Chemical and Engineering Materials Division; Oak Ridge National Laboratory; Oak Ridge; USA
Department of Materials Science and Engineering; University of Tennessee; Knoxville; USA

All-acrylic multigraft copolymers made by a facile synthesis procedure exhibit elongation at break >1700% and strain recovery behavior far exceeding those of commercial acrylic and styrenic triblock copolymers.

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: DOE - BASIC ENERGY SCIENCES

OSTI ID:: 1418062

Journal Information:: Polymer Chemistry, Journal Name: Polymer Chemistry Journal Issue: 2 Vol. 9; ISSN PCOHC2; ISSN 1759-9954

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: ENGLISH

References (37)

Experimental techniques in high-vacuum anionic polymerization Uhrig, David; Mays, Jimmy W. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 24 https://doi.org/10.1002/pola.21016	journal	January 2005
Synthesis and Structure– Property Relationships for Regular Multigraft Copolymers Mays, Jimmy W.; Uhrig, David; Gido, Samuel Macromolecular Symposia, Vol. 215, Issue 1 https://doi.org/10.1002/masy.200451110	journal	August 2004
Solution properties, unperturbed dimensions, and chain flexibility of poly(1-adamantyl acrylate) Lu, Wei; Yin, Panchao; Osa, Masashi Journal of Polymer Science Part B: Polymer Physics, Vol. 55, Issue 20 https://doi.org/10.1002/polb.24408	journal	August 2017
Thin Film Knitting Pattern Morphology from a Miktoarm Star Terpolymer Choi, Hong Kyoon; Nunns, Adam; Sun, Xue Yin Advanced Materials, Vol. 26, Issue 16 https://doi.org/10.1002/adma.201305243	journal	January 2014
Thermoplastic Elastomers Holden, Geoffrey Kirk‐Othmer Encyclopedia of Chemical Technology https://doi.org/10.1002/0471238961.2008051808151204.a01.pub2	book	January 2002
Multigraft copolymer superelastomers: Synthesis morphology, and properties Uhrig, David; Schlegel, Ralf; Weidisch, Roland European Polymer Journal, Vol. 47, Issue 4 https://doi.org/10.1016/j.eurpolymj.2010.10.030	journal	April 2011
Synthesis of well-defined multigraft copolymers Uhrig, David; Mays, Jimmy Polym. Chem., Vol. 2, Issue 1 https://doi.org/10.1039/C0PY00185F	journal	January 2011
Phase imaging and stiffness in tapping-mode atomic force microscopy Magonov, S. N.; Elings, V.; Whangbo, M. -H. Surface Science, Vol. 375, Issue 2-3 https://doi.org/10.1016/S0039-6028(96)01591-9	journal	April 1997
Anionic polymerization: High vacuum techniques Hadjichristidis, Nikos; Iatrou, Hermis; Pispas, Stergios Journal of Polymer Science Part A: Polymer Chemistry, Vol. 38, Issue 18 https://doi.org/10.1002/1099-0518(20000915)38:18<3211::AID-POLA10>3.0.CO;2-L	journal	January 2000
Monomer reactivity ratios of styrene-butyl acrylate copolymers at low and high conversions Ziaee, F.; Nekoomanesh, M. Polymer, Vol. 39, Issue 1 https://doi.org/10.1016/S0032-3861(97)00249-8	journal	January 1998
Block Copolymer Thermodynamics: Theory and Experiment Bates, Frank S.; Fredrickson, Glenn H. Annual Review of Physical Chemistry, Vol. 41, Issue 1 https://doi.org/10.1146/annurev.pc.41.100190.002521	journal	October 1990
Morphology and Deformation Mechanisms and Tensile Properties of Tetrafunctional Multigraft Copolymers Duan, Yongxin; Thunga, Mahendra; Schlegel, Ralf Macromolecules, Vol. 42, Issue 12 https://doi.org/10.1021/ma900414h	journal	June 2009
Morphologies of Microphase-Separated A ₂ B Simple Graft Copolymers Pochan, Darrin J.; Gido, Samuel P.; Pispas, Stergios Macromolecules, Vol. 29, Issue 15 https://doi.org/10.1021/ma951696x	journal	January 1996
Acrylic thermoplastic elastomers and comb-shaped poly(methyl methacrylate) via the macromonomer technique Radke, Wolfgang; Roos, Sebastian; Stein, Helga M. Macromolecular Symposia, Vol. 101, Issue 1 https://doi.org/10.1002/masy.19961010105	journal	January 1996
Synthesis and Characterization of Poly(methyl methacrylate)- block -poly( n -butyl acrylate)- block -poly(methyl methacrylate) Copolymers by Two-Step Controlled Radical Polymerization (ATRP) Catalyzed by NiBr ₂ (PPh ₃ ) ₂ , 1 ^† Moineau, C.; Minet, M.; Teyssié, P. Macromolecules, Vol. 32, Issue 25 https://doi.org/10.1021/ma990783c	journal	December 1999
Synthesis of Styrenic-Terminated Methacrylate Macromonomers by Nitroanion-Initiated Living Anionic Polymerization Zeng, Faquan; Shen, Youqing; Zhu, Shiping Macromolecular Rapid Communications, Vol. 22, Issue 17 https://doi.org/10.1002/1521-3927(20011101)22:17<1399::AID-MARC1399>3.0.CO;2-I	journal	November 2001
Synthesis of poly(methyl methacrylate)-b-poly(n-butyl acrylate)-b-poly(methyl methacrylate) triblocks and their potential as thermoplastic elastomers Tong, J. D.; Jerôme, R. Polymer, Vol. 41, Issue 7 https://doi.org/10.1016/S0032-3861(99)00412-7	journal	March 2000
Dependence of the Ultimate Tensile Strength of Thermoplastic Elastomers of the Triblock Type on the Molecular Weight between Chain Entanglements of the Central Block Tong, Jiang-Dong; Jerôme, Robert Macromolecules, Vol. 33, Issue 5 https://doi.org/10.1021/ma990404f	journal	March 2000
The Cleavage of some Ethers by Organolithium Compounds Gilman, Henry; Haubein, A. H.; Hartzfeld, Howard The Journal of Organic Chemistry, Vol. 19, Issue 7 https://doi.org/10.1021/jo01372a007	journal	July 1954
Design and Synthesis of Multigraft Copolymer Thermoplastic Elastomers: Superelastomers Wang, Huiqun; Lu, Wei; Wang, Weiyu Macromolecular Chemistry and Physics, Vol. 219, Issue 1 https://doi.org/10.1002/macp.201700254	journal	September 2017
Effect of Molecular Architecture on Dynamics of Multigraft Copolymers: Combs, Centipedes, and Barbwires Mijović, Jovan; Sun, Mingyun; Pejanović, Srdjan Macromolecules, Vol. 36, Issue 20 https://doi.org/10.1021/ma034881g	journal	October 2003
Deformation Behavior of Sphere-Forming Trifunctional Multigraft Copolymer Duan, Yongxin; Rettler, Erik; Schneider, Konrad Macromolecules, Vol. 41, Issue 13 https://doi.org/10.1021/ma801036y	journal	July 2008
Copolymerization of n -Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers: Comparison of Reactivity Ratios in Conventional and Atom Transfer Radical Copolymerization Roos, Sebastian G.; Müller, Axel H. E.; Matyjaszewski, Krzysztof Macromolecules, Vol. 32, Issue 25 https://doi.org/10.1021/ma9819337	journal	December 1999
Regular Comb Polystyrenes and Graft Polyisoprene/Polystyrene Copolymers with Double Branches (“Centipedes”). Quality of (1,3-Phenylene)bis(3-methyl-1-phenylpentylidene)dilithium Initiator in the Presence of Polar Additives Iatrou, Hermis; Mays, Jimmy W.; Hadjichristidis, Nikos Macromolecules, Vol. 31, Issue 19 https://doi.org/10.1021/ma980738p	journal	September 1998
Poly(1-adamantyl acrylate): Living Anionic Polymerization, Block Copolymerization, and Thermal Properties Lu, Wei; Huang, Caili; Hong, Kunlun Macromolecules, Vol. 49, Issue 24 https://doi.org/10.1021/acs.macromol.6b01732	journal	December 2016
Synthesis and Characterization of Comb and Centipede Multigraft Copolymers P n BA- g -PS with High Molecular Weight Using Miniemulsion Polymerization Wang, Wenwen; Wang, Weiyu; Lu, Xinyi Macromolecules, Vol. 47, Issue 21 https://doi.org/10.1021/ma501866t	journal	October 2014
New Concepts in Thermoplastic Elastomers: The Case of Syndiotactic Polypropylene, an Unconventional Elastomer with High Crystallinity and Large Modulus Auriemma, Finizia; De Rosa, Claudio Journal of the American Chemical Society, Vol. 125, Issue 43 https://doi.org/10.1021/ja036282v	journal	October 2003
Synthesis of Combs, Centipedes, and Barbwires: Poly(isoprene- graft -styrene) Regular Multigraft Copolymers with Trifunctional, Tetrafunctional, and Hexafunctional Branch Points Uhrig, David; Mays, Jimmy W. Macromolecules, Vol. 35, Issue 19 https://doi.org/10.1021/ma020427l	journal	September 2002
Synthesis of well-controlled graft polymers by living anionic polymerization towards exact graft polymers Ito, Shotaro; Goseki, Raita; Ishizone, Takashi Polymer Chemistry, Vol. 5, Issue 19 https://doi.org/10.1039/C4PY00584H	journal	January 2014
All-Acrylic Multigraft Copolymers: Effect of Side Chain Molecular Weight and Volume Fraction on Mechanical Behavior Goodwin, Andrew; Wang, Weiyu; Kang, Nam-Goo Industrial & Engineering Chemistry Research, Vol. 54, Issue 39 https://doi.org/10.1021/acs.iecr.5b02560	journal	September 2015
Shape-Memory Effects in Polymer Networks Containing Reversibly Associating Side-Groups Li, J.; Viveros, J. A.; Wrue, M. H. Advanced Materials, Vol. 19, Issue 19 https://doi.org/10.1002/adma.200602260	journal	October 2007
All acrylic-based thermoplastic elastomers with high upper service temperature and superior mechanical properties Lu, Wei; Wang, Yangyang; Wang, Weiyu Polymer Chemistry, Vol. 8, Issue 37 https://doi.org/10.1039/C7PY01225J	journal	January 2017
Functional Polymers from Novel Carboxyl-Terminated Trithiocarbonates as Highly Efficient RAFT Agents Lai, John T.; Filla, Debby; Shea, Ronald Macromolecules, Vol. 35, Issue 18 https://doi.org/10.1021/ma020362m	journal	August 2002
Crossed aldol reaction using cross-linked polymer-bound lithium dialkylamide Seki, Atsushi; Ishiwata, Fusae; Takizawa, Youichi Tetrahedron, Vol. 60, Issue 23 https://doi.org/10.1016/j.tet.2004.04.026	journal	May 2004
Binuclear Initiators for the Telechelic Synthesis of Elastomeric Polyolefins Coffin, Robert C.; Schneider, Yanika; Kramer, Edward J. Journal of the American Chemical Society, Vol. 132, Issue 39 https://doi.org/10.1021/ja1056938	journal	October 2010
Morphology and Tensile Properties of Multigraft Copolymers with Regularly Spaced Tri-, Tetra-, and Hexafunctional Junction Points Zhu, Yuqing; Burgaz, Engin; Gido, Samuel P. Macromolecules, Vol. 39, Issue 13 https://doi.org/10.1021/ma060067s	journal	June 2006
New initiator system for the living anionic polymerization of tert-alkyl acrylates Fayt, R.; Forte, R.; Jacobs, C. Macromolecules, Vol. 20, Issue 6 https://doi.org/10.1021/ma00172a058	journal	November 1987

Cited By (1)

Synthesis of acrylic hot-melt adhesive based on poly(methyl methacrylate)- b -poly(2-ethylhexyl acrylate) copolymer using atom transfer radical polymerization for a nylon fabric bonding system Kuo, Chung-Feng Jeffrey; Chen, Jiong-Bo; Chen, Po-Yen Textile Research Journal, Vol. 89, Issue 23-24 https://doi.org/10.1177/0040517519850836	journal	May 2019

Similar Records

All-acrylic superelastomers: facile synthesis and exceptional mechanical behavior

Journal Article · Tue Oct 17 00:00:00 EDT 2017 · Polymer Chemistry · OSTI ID:1479807

All-acrylic multigraft copolymer superelastomers

Patent · Tue May 10 00:00:00 EDT 2022 · OSTI ID:1892910

Design, synthesis, and characterization of lightly sulfonated multigraft acrylate-based copolymer superelastomers

Journal Article · Sun Dec 31 23:00:00 EST 2017 · RSC Advances · OSTI ID:1418384

Related Subjects

36 MATERIALS SCIENCE

All-acrylic superelastomers: facile synthesis and exceptional mechanical behavior

Citation Formats

References (37)

Cited By (1)

Similar Records

Related Subjects