Design, synthesis, and characterization of lightly sulfonated multigraft acrylate-based copolymer superelastomers

Misichronis, Konstantinos; Wang, Weiyu; Cheng, Shiwang; Wang, Yangyang; Shrestha, Umesh; Dadmun, Mark; Mays, Jimmy W.; Saito, Tomonori

doi:10.1039/C7RA08641E

Design, synthesis, and characterization of lightly sulfonated multigraft acrylate-based copolymer superelastomers

Journal Article · Sun Dec 31 23:00:00 EST 2017 · RSC Advances

DOI:https://doi.org/10.1039/C7RA08641E· OSTI ID:1418384

^[1]; Wang, Weiyu ^[2]; Cheng, Shiwang ^[3]; ^[2]; Shrestha, Umesh ^[4]; ^[1]; Mays, Jimmy W. ^[1]; ^[3]

Department of Chemistry, University of Tennessee, Knoxville, USA, Chemical Sciences Division
Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, USA
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, USA
Department of Chemistry, University of Tennessee, Knoxville, USA

Lightly sulfonated acrylate-based multigraft superelastomers with tunable true stress and elongation (>700%) at room temperature.

View Journal Article

Sponsoring Organization:: USDOE

OSTI ID:: 1418384

Alternate ID(s):: OSTI ID: 1423075

Journal Information:: RSC Advances, Journal Name: RSC Advances Journal Issue: 10 Vol. 8; ISSN 2046-2069; ISSN RSCACL

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (44)

Characterization and thermal properties of poly(n-butyl acrylate-g-styrene) graft copolymers de la Fuente, Jos� Luis; Fern�ndez-Garc�a, Marta; L�pez Madruga, Enrique Journal of Applied Polymer Science, Vol. 80, Issue 5 https://doi.org/10.1002/1097-4628(20010502)80:5<783::AID-APP1155>3.0.CO;2-5	journal	January 2001
Styrolux+ and styroflex+ - from transparent high impact polystyrene to new thermoplastic elastomers: Syntheses, applications and blends with other styrene based polymers Knoll, Konrad; Nießner, Norbert Macromolecular Symposia, Vol. 132, Issue 1 https://doi.org/10.1002/masy.19981320122	journal	July 1998
Experimental techniques in high-vacuum anionic polymerization Uhrig, David; Mays, Jimmy W. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 24 https://doi.org/10.1002/pola.21016	journal	January 2005
Block copolymer ionomers: 2. Viscoelastic and mechanical properties of sulphonated poly(styrene-ethylene/butylene-styrene) Weiss, R. A.; Sen, A.; Pottick, L. A. Polymer, Vol. 32, Issue 15 https://doi.org/10.1016/0032-3861(91)90109-V	journal	January 1991
Block copolymer ionomers: 1. Synthesis and physical properties of sulphonated poly(styrene-ethylene/butylene-styrene) Weiss, R. A.; Sen, Ashish; Willis, C. L. Polymer, Vol. 32, Issue 10 https://doi.org/10.1016/0032-3861(91)90378-V	journal	January 1991
Morphology and mechanical properties of poly(methylmethacrylate)-b-poly(alkylacrylate)-b-poly(methylmethacrylate) Tong, J. D.; Leclère, Ph; Doneux, C. Polymer, Vol. 42, Issue 8 https://doi.org/10.1016/S0032-3861(00)00759-X	journal	April 2001
Synthesis of poly(methyl methacrylate)-b-poly(n-butyl acrylate)-b-poly(methyl methacrylate) triblocks and their potential as thermoplastic elastomers Tong, J. D.; Jerôme, R. Polymer, Vol. 41, Issue 7 https://doi.org/10.1016/S0032-3861(99)00412-7	journal	March 2000
Structural characterization and surface modification of sulfonated polystyrene–(ethylene–butylene)–styrene triblock proton exchange membranes Won, Jongok; Choi, Sang Wook; Kang, Yong Soo Journal of Membrane Science, Vol. 214, Issue 2 https://doi.org/10.1016/S0376-7388(02)00555-0	journal	April 2003
Triblock copolymer ionomer membranes Elabd, Yossef A.; Napadensky, Eugene; Sloan, James M. Journal of Membrane Science, Vol. 217, Issue 1-2 https://doi.org/10.1016/S0376-7388(03)00127-3	journal	June 2003
Thermoplastic elastomers: fundamentals and applications Spontak, Richard J.; Patel, Nikunj P. Current Opinion in Colloid & Interface Science, Vol. 5, Issue 5-6 https://doi.org/10.1016/S1359-0294(00)00070-4	journal	November 2000
Selective modification of block copolymers as proton exchange membranes Yang, Jung-Eun; Lee, Jae-Suk Electrochimica Acta, Vol. 50, Issue 2-3 https://doi.org/10.1016/j.electacta.2004.03.064	journal	November 2004
Interpretation of hysteresis behaviour of PI–PS multigraft copolymers by adapting to the dynamic flocculation model Staudinger, Ulrike; Schlegel, Ralf; Weidisch, Roland European Polymer Journal, Vol. 44, Issue 11 https://doi.org/10.1016/j.eurpolymj.2008.08.005	journal	November 2008
Investigations on mechanical properties of PI–PS multigraft copolymers Schlegel, R.; Staudinger, U.; Thunga, M. European Polymer Journal, Vol. 45, Issue 10 https://doi.org/10.1016/j.eurpolymj.2009.06.028	journal	October 2009
Multigraft copolymer superelastomers: Synthesis morphology, and properties Uhrig, David; Schlegel, Ralf; Weidisch, Roland European Polymer Journal, Vol. 47, Issue 4 https://doi.org/10.1016/j.eurpolymj.2010.10.030	journal	April 2011
Synthesis and characterization of brush-like multigraft copolymers P n BA- g -PMMA by a combination of emulsion AGET ATRP and emulsion polymerization Li, Hui; Wang, Wenwen; Li, Chunmei Journal of Colloid and Interface Science, Vol. 453 https://doi.org/10.1016/j.jcis.2015.04.051	journal	September 2015
Triblock copolymer ionomer membranes Elabd, Yossef A.; Walker, Charles W.; Beyer, Frederick L. Journal of Membrane Science, Vol. 231, Issue 1-2 https://doi.org/10.1016/j.memsci.2003.11.019	journal	March 2004
Morphology and transport properties of protons and methanol through partially sulfonated block copolymers Kim, B.; Kim, J.; Jung, B. Journal of Membrane Science, Vol. 250, Issue 1-2 https://doi.org/10.1016/j.memsci.2004.10.025	journal	March 2005
Direct sulfonation and photocrosslinking of unsaturated poly(styrene-b-butadiene-b-styrene) for proton exchange membrane of direct methanol fuel cell Kim, Seulgi; Lee, Hyunjung; Ahn, Dahee Journal of Membrane Science, Vol. 427 https://doi.org/10.1016/j.memsci.2012.09.008	journal	January 2013
Viscoelastic properties and morphology of sulfonated poly(styrene-b-ethylene/butylene-b-styrene) block copolymers (sBCP), and sBCP/[silicate] nanostructured materials Mauritz, Kenneth A.; Blackwell, Richard I.; Beyer, Frederick L. Polymer, Vol. 45, Issue 9 https://doi.org/10.1016/j.polymer.2003.12.078	journal	April 2004
Dynamic mechanical properties of annealed sulfonated poly(styrene-b-[ethylene/butylene]-b-styrene) block copolymers Blackwell, R. I.; Mauritz, K. A. Polymer, Vol. 45, Issue 10 https://doi.org/10.1016/j.polymer.2004.02.010	journal	May 2004
Sulfonation and characterization of poly(styrene-isobutylene-styrene) triblock copolymers at high ion-exchange capacities Elabd, Yossef A.; Napadensky, Eugene Polymer, Vol. 45, Issue 9 https://doi.org/10.1016/j.polymer.2004.02.061	journal	April 2004
Stress softening of multigraft copolymers Schlegel, R.; Wilkin, D.; Duan, Y. Polymer, Vol. 50, Issue 26 https://doi.org/10.1016/j.polymer.2009.10.026	journal	December 2009
All-Acrylic Multigraft Copolymers: Effect of Side Chain Molecular Weight and Volume Fraction on Mechanical Behavior Goodwin, Andrew; Wang, Weiyu; Kang, Nam-Goo Industrial & Engineering Chemistry Research, Vol. 54, Issue 39 https://doi.org/10.1021/acs.iecr.5b02560	journal	September 2015
Polymers with Complex Architecture by Living Anionic Polymerization Hadjichristidis, Nikos; Pitsikalis, Marinos; Pispas, Stergios Chemical Reviews, Vol. 101, Issue 12 https://doi.org/10.1021/cr9901337	journal	December 2001
Synthesis and Characterization of Graft Copolymers Poly(isoprene- g -styrene) of High Molecular Weight by a Combination of Anionic Polymerization and Emulsion Polymerization Wang, Wenwen; Wang, Weiyu; Li, Hui Industrial & Engineering Chemistry Research, Vol. 54, Issue 4 https://doi.org/10.1021/ie504457e	journal	January 2015
Effect of Molecular Architecture on Phase Behavior of Graft Copolymers Zhang, Liangshun; Lin, Jiaping; Lin, Shaoliang The Journal of Physical Chemistry B, Vol. 112, Issue 32 https://doi.org/10.1021/jp802770z	journal	August 2008
Morphological studies of a triblock copolymer ionomer by small-angle x-ray scattering Lu, Xinya; Steckle, W. P.; Weiss, R. A. Macromolecules, Vol. 26, Issue 24 https://doi.org/10.1021/ma00076a033	journal	November 1993
A new multiplet-cluster model for the morphology of random ionomers Eisenberg, A.; Hird, B.; Moore, R. B. Macromolecules, Vol. 23, Issue 18 https://doi.org/10.1021/ma00220a012	journal	September 1990
Synthesis of Combs, Centipedes, and Barbwires: Poly(isoprene- graft -styrene) Regular Multigraft Copolymers with Trifunctional, Tetrafunctional, and Hexafunctional Branch Points Uhrig, David; Mays, Jimmy W. Macromolecules, Vol. 35, Issue 19 https://doi.org/10.1021/ma020427l	journal	September 2002
Effect of Molecular Architecture on Dynamics of Multigraft Copolymers: Combs, Centipedes, and Barbwires Mijović, Jovan; Sun, Mingyun; Pejanović, Srdjan Macromolecules, Vol. 36, Issue 20 https://doi.org/10.1021/ma034881g	journal	October 2003
Transport Properties of Sulfonated Poly(styrene- b -isobutylene- b -styrene) Triblock Copolymers at High Ion-Exchange Capacities Elabd, Yossef A.; Napadensky, Eugene; Walker, Charles W. Macromolecules, Vol. 39, Issue 1 https://doi.org/10.1021/ma051958n	journal	January 2006
Morphology and Tensile Properties of Multigraft Copolymers with Regularly Spaced Tri-, Tetra-, and Hexafunctional Junction Points Zhu, Yuqing; Burgaz, Engin; Gido, Samuel P. Macromolecules, Vol. 39, Issue 13 https://doi.org/10.1021/ma060067s	journal	June 2006
Polystyrene- block -poly( n -butyl acrylate)- block -polystyrene Triblock Copolymer Thermoplastic Elastomer Synthesized via RAFT Emulsion Polymerization Luo, Yingwu; Wang, Xiaoguang; Zhu, Yue Macromolecules, Vol. 43, Issue 18 https://doi.org/10.1021/ma101348k	journal	September 2010
High-Strain-Induced Deformation Mechanisms in Block–Graft and Multigraft Copolymers Schlegel, R.; Duan, Y. X.; Weidisch, R. Macromolecules, Vol. 44, Issue 23 https://doi.org/10.1021/ma201353w	journal	December 2011
Novel Synthetic Strategy for the Sulfonation of Polybutadiene and Styrene–Butadiene Copolymers Buonerba, Antonio; Speranza, Vito; Grassi, Alfonso Macromolecules, Vol. 46, Issue 3 https://doi.org/10.1021/ma301972m	journal	January 2013
Synthesis and Characterization of Comb and Centipede Multigraft Copolymers P n BA- g -PS with High Molecular Weight Using Miniemulsion Polymerization Wang, Wenwen; Wang, Weiyu; Lu, Xinyi Macromolecules, Vol. 47, Issue 21 https://doi.org/10.1021/ma501866t	journal	October 2014
Theory of Microphase Separation in Block Copolymers Leibler, Ludwik Macromolecules, Vol. 13, Issue 6 https://doi.org/10.1021/ma60078a047	journal	November 1980
Influence of Site-Specific Sulfonation on Acrylic Graft Copolymer Morphology Saito, Tomonori; Mather, Brian D.; Costanzo, Philip J. Macromolecules, Vol. 41, Issue 10 https://doi.org/10.1021/ma800178d	journal	May 2008
Prediction of the Glass Transition Temperature of Multicyclic and Bulky Substituted Acrylate and Methacrylate Polymers Using the Energy, Volume, Mass (EVM) QSPR Model Cypcar, Christopher C.; Camelio, Philippe; Lazzeri, Veronique Macromolecules, Vol. 29, Issue 27 https://doi.org/10.1021/ma961170s	journal	January 1996
Synthesis of well-defined multigraft copolymers Uhrig, David; Mays, Jimmy Polym. Chem., Vol. 2, Issue 1 https://doi.org/10.1039/C0PY00185F	journal	January 2011
Rheological properties and crystallization behavior of comb-like graft poly( l -lactide): influences of graft length and graft density Leng, Xuefei; Wei, Zhiyong; Bian, Yufei RSC Advances, Vol. 6, Issue 36 https://doi.org/10.1039/C6RA02697D	journal	January 2016
Mechanically and structurally robust sulfonated block copolymer membranes for water purification applications Yeo, J.; Kim, S. Y.; Kim, S. Nanotechnology, Vol. 23, Issue 24 https://doi.org/10.1088/0957-4484/23/24/245703	journal	May 2012
Toughening elastomers using mussel-inspired iron-catechol complexes Filippidi, Emmanouela; Cristiani, Thomas R.; Eisenbach, Claus D. Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aao0350	journal	October 2017
Thermoplastic Elastomers—Three Decades of Progress Legge, N. R. Rubber Chemistry and Technology, Vol. 62, Issue 3 https://doi.org/10.5254/1.3536257	journal	July 1989

Similar Records

All-acrylic multigraft copolymer superelastomers

Patent · Tue May 10 00:00:00 EDT 2022 · OSTI ID:1892910

Design, synthesis, and characterization of lightly sulfonated multigraft acrylate-based copolymer superelastomers

Citation Formats

References (44)

Similar Records

Related Subjects