All-acrylic multigraft copolymer superelastomers

Mays, Jimmy W.; Lu, Wei; Kang, Nam-Goo

All-acrylic multigraft copolymer superelastomers

Patent · Tue May 10 00:00:00 EDT 2022

OSTI ID:1892910

Mays, Jimmy W.; Lu, Wei; Kang, Nam-Goo

Thermoplastic elastomer compositions comprising acrylic multigraft copolymers are described. The multigraft copolymers comprise a rubbery polyacrylate backbone and a plurality of randomly spaced glassy polyacrylate side chains. The multigraft copolymers can be prepared using a facile grafting through method that can provide copolymers with enhanced purity. The acrylic multigraft copolymers exhibit microphase separated morphologies and “superelastomeric” properties, including an elongation at break, stress at break, and/or strain recovery behavior that exceeds that of conventional triblock copolymer polyacrylate thermoplastic elastomers.

View Patent

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Assignee:: University of Tennessee Research Foundation (Knoxville, TN)

Patent Number(s):: 11,325,991

Application Number:: 16/608,614

OSTI ID:: 1892910

Country of Publication:: United States

Language:: English

References (137)

Shape-Memory Effects in Polymer Networks Containing Reversibly Associating Side-Groups Li, J.; Viveros, J. A.; Wrue, M. H. Advanced Materials, Vol. 19, Issue 19 https://doi.org/10.1002/adma.200602260	journal	October 2007
Simple Method for the Esterification of Carboxylic Acids Neises, Bernhard; Steglich, Wolfgang Angewandte Chemie International Edition in English, Vol. 17, Issue 7 https://doi.org/10.1002/anie.197805221	journal	July 1978
Synthesis of Poly(tert-butyl acrylate)-block-Polystyrene-block-Poly(4-vinylpyridine) by Living Anionic Polymerization Liu, Futian; Eisenberg, Adi Angewandte Chemie International Edition, Vol. 42, Issue 12 https://doi.org/10.1002/anie.200390361	journal	March 2003
Emulsion polymerization of isoprene. Estimation of the branching exponent with the help of a mathematical model Minari, Roque J.; Rodriguez, Virginia I.; Estenoz, Diana A. Journal of Applied Polymer Science https://doi.org/10.1002/app.31580	journal	January 2009
Synthesis of nanosized ethylene-propylene rubber latex via polyisoprene hydrogenation Kongsinlark, Anong; Rempel, Garry L.; Prasassarakich, Pattarapan Journal of Applied Polymer Science, Vol. 127, Issue 5 https://doi.org/10.1002/app.37883	journal	May 2012
Study on the influence of electron beam irradiation on the thermal, mechanical, and rheological properties of ethylene-octene copolymer with high comonomer content Poongavalappil, Sameepa; Svoboda, Petr; Theravalappil, Rajesh Journal of Applied Polymer Science, Vol. 128, Issue 5 https://doi.org/10.1002/app.38479	journal	September 2012
Synthesis and molecular weight characterization of end-functionalized N-vinyl-2-pyrrolidone oligomers Ranucci, Elisabetta; Spagnoli, Gloria; Sartore, Luciana Macromolecular Chemistry and Physics, Vol. 196, Issue 3 https://doi.org/10.1002/macp.1995.021960307	journal	March 1995
“Living” free radical polymerization of macromonomers: Preparation of well defined graft copolymers Hawker, Craig J.; Mecerreyes, David; Elce, Edmund Macromolecular Chemistry and Physics, Vol. 198, Issue 1 https://doi.org/10.1002/macp.1997.021980112	journal	January 1997
ABC triblock polyampholytes containing a neutral hydrophobic block, a polyacid and a polybase Giebeler, Ellen; Stadler, Reimund Macromolecular Chemistry and Physics, Vol. 198, Issue 12 https://doi.org/10.1002/macp.1997.021981204	journal	December 1997
Grafting of polybutadiene functionalised with chlorosilane groups Cameron, G. Gordon; Qureshi, M. Younus Die Makromolekulare Chemie, Rapid Communications, Vol. 2, Issue 4, p. 287-291 https://doi.org/10.1002/marc.1981.030020408	journal	June 1981
Acrylic thermoplastic elastomers and comb-shaped poly(methyl methacrylate) via the macromonomer technique Radke, Wolfgang; Roos, Sebastian; Stein, Helga M. Macromolecular Symposia, Vol. 101, Issue 1 https://doi.org/10.1002/masy.19961010105	journal	January 1996
Synthesis and Structure– Property Relationships for Regular Multigraft Copolymers Mays, Jimmy W.; Uhrig, David; Gido, Samuel Macromolecular Symposia, Vol. 215, Issue 1 https://doi.org/10.1002/masy.200451110	journal	August 2004
Mechanical Properties and Hysteresis Behaviour of Multigraft Copolymers Staudinger, U.; Weidisch, R.; Zhu, Y. Macromolecular Symposia, Vol. 233, Issue 1 https://doi.org/10.1002/masy.200690027	journal	February 2006
Synthesis of styrene- g -polyisoprene nanoparticles by emulsion polymerization and its effect on properties of polyisoprene composites: STYRENE-G-POLYISOPRENE NANOPARTICLES AND ITS COMPOSITES Suppaibulsuk, Bunthita; Rempel, Garry L.; Prasassarakich, Pattarapan Polymers for Advanced Technologies, Vol. 23, Issue 11 https://doi.org/10.1002/pat.2069	journal	December 2011
Preparation and properties of monodisperse branched polystyrene Morton, M.; Helminiak, T. E.; Gadkary, S. D. Journal of Polymer Science, Vol. 57, Issue 165 https://doi.org/10.1002/pol.1962.1205716537	journal	March 1962
Lithiation of diene polymers Minoura, Yuji; Shiina, Kyo; Harada, Hiroshi Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 6, Issue 3 https://doi.org/10.1002/pol.1968.150060312	journal	March 1968
Anionic graft copolymerization of diene polymers with vinyl monomers Minoura, Yuji; Harada, Hiroshi Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 7, Issue 1 https://doi.org/10.1002/pol.1969.150070102	journal	January 1969
Metallation of unsaturated polymers and formation of graft copolymers Tate, D. P.; Halasa, A. F.; Webb, F. J. Journal of Polymer Science Part A-1: Polymer Chemistry, Vol. 9, Issue 1 https://doi.org/10.1002/pol.1971.150090112	journal	January 1971
Dynamic viscoelastic behavior of ABA block polymers and the nature of the domain boundary Kraus, Gerard; Rollmann, K. W. Journal of Polymer Science: Polymer Physics Edition, Vol. 14, Issue 6 https://doi.org/10.1002/pol.1976.180140615	journal	June 1976
Conformation of poly(isoprene-gstyrene) in dilute solution Hadjichristidis, N.; Roovers, J. Journal of Polymer Science: Polymer Physics Edition, Vol. 16, Issue 5 https://doi.org/10.1002/pol.1978.180160510	journal	May 1978
Graft copolymers from star-shaped and hyperbranched polystyrene macromonomers Al-Muallem, Hasan A.; Knauss, Daniel M. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 39, Issue 20 https://doi.org/10.1002/pola.10005	journal	January 2001
Synthesis of comb-branched polyacrylamide with cationic poly[(2-dimethylamino)ethyl methacrylate dimethylsulfate] quat Zeng, Faquan; Shen, Youqing; Zhu, Shiping Journal of Polymer Science Part A: Polymer Chemistry, Vol. 40, Issue 14 https://doi.org/10.1002/pola.10323	journal	June 2002
Block copolymerization oftert-butyl methacrylate with ?,?-difunctionalized polystyrene macroiniferter and hydrolysis to amphiphilic block copolymer Qin, Shu-Hui; Qiu, Kun-Yuan Journal of Polymer Science Part A: Polymer Chemistry, Vol. 39, Issue 9 https://doi.org/10.1002/pola.1121	journal	January 2001
Anionic homo- and copolymerization of double-tailed macromonomers: A route to novel macromolecular architectures Driva, Paraskevi; Iatrou, Hermis; Lohse, David J. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 18 https://doi.org/10.1002/pola.20895	journal	January 2005
Experimental techniques in high-vacuum anionic polymerization Uhrig, David; Mays, Jimmy W. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 24 https://doi.org/10.1002/pola.21016	journal	January 2005
Anionic homo- and copolymerization of styrenic triple-tailed polybutadiene macromonomers Nikopoulou, Anastasia; Iatrou, Hermis; Lohse, David J. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 45, Issue 16 https://doi.org/10.1002/pola.22098	journal	January 2007
Hydrodynamic properties of model 3-miktoarm star copolymers Iatrou, Hermis; Siakali-Kioulafa, E.; Hadjichristidis, Nikos Journal of Polymer Science Part B: Polymer Physics, Vol. 33, Issue 13 https://doi.org/10.1002/polb.1995.090331308	journal	September 1995
Solution properties, unperturbed dimensions, and chain flexibility of poly(1-adamantyl acrylate) Lu, Wei; Yin, Panchao; Osa, Masashi Journal of Polymer Science Part B: Polymer Physics, Vol. 55, Issue 20 https://doi.org/10.1002/polb.24408	journal	August 2017
Synthesis of ?simple graft? poly(isoprene-g-styrene) by anionic polymerization Mays, Jimmy W. Polymer Bulletin, Vol. 23, Issue 3 https://doi.org/10.1007/BF01032437	journal	March 1990
Other Thermoplastic Elastomers Drobny, Jiri George Handbook of Thermoplastic Elastomers, p. 291-296 https://doi.org/10.1016/B978-0-323-22136-8.00013-2	book	January 2014
The analysis of organolithium compounds Gilman, Henry; Cartledge, Frank K. Journal of Organometallic Chemistry, Vol. 2, Issue 6 https://doi.org/10.1016/S0022-328X(00)83259-3	journal	December 1964
Characterization of hydroxyl-end-capped polybutadiene and polystyrene produced by anionic polymerization technique via TLC/MALDI TOF mass spectrometry Ji, Haining; Sato, Nobuyuki; Nonidez, William K. Polymer, Vol. 43, Issue 25 https://doi.org/10.1016/S0032-3861(02)00452-4	journal	January 2002
π-Shaped double-graft copolymers: effect of molecular architecture on morphology Lee, Chin; Gido, Samuel P.; Poulos, Yiannis Polymer, Vol. 39, Issue 19 https://doi.org/10.1016/S0032-3861(97)10316-0	journal	September 1998
Synthesis of poly(methyl methacrylate)-b-poly(n-butyl acrylate)-b-poly(methyl methacrylate) triblocks and their potential as thermoplastic elastomers Tong, J. D.; Jerôme, R. Polymer, Vol. 41, Issue 7 https://doi.org/10.1016/S0032-3861(99)00412-7	journal	March 2000
Structure/property relationships in polystyrene–polyisobutylene–polystyrene block copolymers Crawford, Dawn M.; Napadensky, Eugene; Beck Tan, Nora C. Thermochimica Acta, Vol. 367-368 https://doi.org/10.1016/S0040-6031(00)00692-4	journal	March 2001
Thermoplastic elastomers: fundamentals and applications Spontak, Richard J.; Patel, Nikunj P. Current Opinion in Colloid & Interface Science, Vol. 5, Issue 5-6 https://doi.org/10.1016/S1359-0294(00)00070-4	journal	November 2000
Designing biodegradable multiblock PCL/PLA thermoplastic elastomers Cohn, D.; Hotovely Salomon, A. Biomaterials, Vol. 26, Issue 15 https://doi.org/10.1016/j.biomaterials.2004.07.052	journal	May 2005
Interpretation of hysteresis behaviour of PI–PS multigraft copolymers by adapting to the dynamic flocculation model Staudinger, Ulrike; Schlegel, Ralf; Weidisch, Roland European Polymer Journal, Vol. 44, Issue 11 https://doi.org/10.1016/j.eurpolymj.2008.08.005	journal	November 2008
Investigations on mechanical properties of PI–PS multigraft copolymers Schlegel, R.; Staudinger, U.; Thunga, M. European Polymer Journal, Vol. 45, Issue 10 https://doi.org/10.1016/j.eurpolymj.2009.06.028	journal	October 2009
Multigraft copolymer superelastomers: Synthesis morphology, and properties Uhrig, David; Schlegel, Ralf; Weidisch, Roland European Polymer Journal, Vol. 47, Issue 4 https://doi.org/10.1016/j.eurpolymj.2010.10.030	journal	April 2011
Synthesis and surface properties of PDMS-containing latexes by emulsion polymerization using AIBN as the initiator Zhang, Quanyuan; Galvan-Miyoshi, Julian M.; Pezzotti, Fabio European Polymer Journal, Vol. 49, Issue 8 https://doi.org/10.1016/j.eurpolymj.2013.05.018	journal	August 2013
Synthesis and self-association in dilute aqueous solution of hydrophobically modified polycations and polyampholytes based on 4-vinylbenzyl chloride Koromilas, Nikos D.; Lainioti, Georgia Ch.; Oikonomou, Evdokia K. European Polymer Journal, Vol. 54 https://doi.org/10.1016/j.eurpolymj.2014.02.009	journal	May 2014
Synthesis of poly (methyl methacrylate)-b-polystyrene with high molecular weight by DPE seeded emulsion polymerization and its application in proton exchange membrane Wang, Wenwen; Zhang, Hepeng; Geng, Wangchang Journal of Colloid and Interface Science, Vol. 406 https://doi.org/10.1016/j.jcis.2013.05.049	journal	September 2013
Synthesis and cross-linking of polyisoprene latexes Cheong, In Woo; Fellows, Christopher M.; Gilbert, Robert G. Polymer, Vol. 45, Issue 3 https://doi.org/10.1016/j.polymer.2003.12.002	journal	February 2004
Nanostructured latex particles synthesized by nitroxide-mediated controlled/living free-radical polymerization in emulsion Nicolas, Julien; Ruzette, Anne-Valérie; Farcet, Céline Polymer, Vol. 48, Issue 24 https://doi.org/10.1016/j.polymer.2007.09.039	journal	November 2007
Methacrylate/acrylate ABA triblock copolymers by atom transfer radical polymerization; their properties and application as a mediator for organically dispersible gold nanoparticles Datta, Haimanti; Bhowmick, Anil K.; Singha, Nikhil K. Polymer, Vol. 50, Issue 14 https://doi.org/10.1016/j.polymer.2009.04.071	journal	July 2009
Stress softening of multigraft copolymers Schlegel, R.; Wilkin, D.; Duan, Y. Polymer, Vol. 50, Issue 26 https://doi.org/10.1016/j.polymer.2009.10.026	journal	December 2009
Star-like poly (n-butyl acrylate)-b-poly (α-methylene-γ-butyrolactone) block copolymers for high temperature thermoplastic elastomers applications Juhari, Azhar; Mosnáček, Jaroslav; Yoon, Jeong Ae Polymer, Vol. 51, Issue 21 https://doi.org/10.1016/j.polymer.2010.08.017	journal	October 2010
Macromolecular architectures by living and controlled/living polymerizations Hadjichristidis, Nikos; Iatrou, Hermis; Pitsikalis, Marinos Progress in Polymer Science, Vol. 31, Issue 12 https://doi.org/10.1016/j.progpolymsci.2006.07.002	journal	December 2006
Crossed aldol reaction using cross-linked polymer-bound lithium dialkylamide Seki, Atsushi; Ishiwata, Fusae; Takizawa, Youichi Tetrahedron, Vol. 60, Issue 23 https://doi.org/10.1016/j.tet.2004.04.026	journal	May 2004
All-Acrylic Multigraft Copolymers: Effect of Side Chain Molecular Weight and Volume Fraction on Mechanical Behavior Goodwin, Andrew; Wang, Weiyu; Kang, Nam-Goo Industrial & Engineering Chemistry Research, Vol. 54, Issue 39 https://doi.org/10.1021/acs.iecr.5b02560	journal	September 2015
Poly(1-adamantyl acrylate): Living Anionic Polymerization, Block Copolymerization, and Thermal Properties Lu, Wei; Huang, Caili; Hong, Kunlun Macromolecules, Vol. 49, Issue 24 https://doi.org/10.1021/acs.macromol.6b01732	journal	December 2016
Biobased Polymers: Synthesis of Graft Copolymers and Comb Polymers Using Lactic Acid Macromonomer and Properties of the Product Polymers Ishimoto, Kiyoaki; Arimoto, Maho; Okuda, Tomoya Biomacromolecules, Vol. 13, Issue 11 https://doi.org/10.1021/bm301212a	journal	September 2012
Styrene–Butadiene–Styrene Triblock Copolymer Latex via Reversible Addition–Fragmentation Chain Transfer Miniemulsion Polymerization Wei, Renzhong; Luo, Yingwu; Zeng, Wang Industrial & Engineering Chemistry Research, Vol. 51, Issue 47 https://doi.org/10.1021/ie302067n	journal	November 2012
Synthesis and Characterization of Graft Copolymers Poly(isoprene- g -styrene) of High Molecular Weight by a Combination of Anionic Polymerization and Emulsion Polymerization Wang, Wenwen; Wang, Weiyu; Li, Hui Industrial & Engineering Chemistry Research, Vol. 54, Issue 4 https://doi.org/10.1021/ie504457e	journal	January 2015
Synthetic Rubber Production. Chelating Agents in Sulfoxylate Polymerization Prince, A. K.; Spitz, R. D. Industrial & Engineering Chemistry, Vol. 52, Issue 3 https://doi.org/10.1021/ie50603a030	journal	March 1960
New Concepts in Thermoplastic Elastomers: The Case of Syndiotactic Polypropylene, an Unconventional Elastomer with High Crystallinity and Large Modulus Auriemma, Finizia; De Rosa, Claudio Journal of the American Chemical Society, Vol. 125, Issue 43 https://doi.org/10.1021/ja036282v	journal	October 2003
Synthesis of Monodisperse Polystyrene Microlatexes by Emulsion Polymerization Using a Polymerizable Surfactant Liu, J.; Chew, C. H.; Gan, L. M. Langmuir, Vol. 13, Issue 19 https://doi.org/10.1021/la970252m	journal	September 1997
Microheterogeneity in miscible blends of 1,2-polybutadiene and 1,4-polyisoprene Roovers, J.; Toporowski, P. M. Macromolecules, Vol. 25, Issue 13 https://doi.org/10.1021/ma00039a023	journal	June 1992
Imprinted Polymers Prepared with Stoichiometric Template−Monomer Complexes: Efficient Binding of Ampicillin from Aqueous Solutions Lübke, Christian; Lübke, Markus; Whitcombe, Michael J. Macromolecules, Vol. 33, Issue 14 https://doi.org/10.1021/ma000467u	journal	July 2000
Lamellar diblock copolymer grain boundary morphology. 1. Twist boundary characterization Gido, Samuel P.; Gunther, Janelle; Thomas, Edwin L. Macromolecules, Vol. 26, Issue 17 https://doi.org/10.1021/ma00069a016	journal	August 1993
T-Junction Grain Boundaries in Block Copolymer−Homopolymer Blends Burgaz, Engin; Gido, Samuel P. Macromolecules, Vol. 33, Issue 23 https://doi.org/10.1021/ma000729s	journal	November 2000
Morphology and miscibility of miktoarm styrene-diene copolymers and terpolymers Hadjichristidis, N.; Iatrou, H.; Behal, S. K. Macromolecules, Vol. 26, Issue 21 https://doi.org/10.1021/ma00073a042	journal	October 1993
Methyl Group Dynamics in Glassy Polyisoprene: A Neutron Backscattering Investigation Frick, B.; Fetters, L. J. Macromolecules, Vol. 27, Issue 4 https://doi.org/10.1021/ma00082a014	journal	July 1994
Chain Architecture and Asymmetry in Copolymer Microphases Milner, Scott T. Macromolecules, Vol. 27, Issue 8 https://doi.org/10.1021/ma00086a057	journal	April 1994
Effect of arm number and arm molecular weight on the solid-state morphology of poly(styrene-isoprene) star block copolymers Alward, David B.; Kinning, David J.; Thomas, Edward L. Macromolecules, Vol. 19, Issue 1 https://doi.org/10.1021/ma00155a034	journal	January 1986
1,3-Cyclohexadiene Polymers. 1. Anionic Polymerization Hong, Kunlun; Mays, Jimmy W. Macromolecules, Vol. 34, Issue 4 https://doi.org/10.1021/ma0015626	journal	February 2001
Ordered bicontinuous double-diamond structure of star block copolymers: a new equilibrium microdomain morphology Thomas, Edwin L.; Alward, David B.; Kinning, David J. Macromolecules, Vol. 19, Issue 8 https://doi.org/10.1021/ma00162a016	journal	August 1986
1,3-Cyclohexadiene Polymers. 2. Near-Monodisperse Star and Star-Block Polymers Based on Poly(1,3-cyclohexadiene) Hong, Kunlun; Wan, Yunan; Mays, Jimmy W. Macromolecules, Vol. 34, Issue 8 https://doi.org/10.1021/ma001679u	journal	April 2001
Ordered packing arrangements of spherical micelles of diblock copolymers in two and three dimensions Thomas, Edwin L.; Kinning, David J.; Alward, David B. Macromolecules, Vol. 20, Issue 11 https://doi.org/10.1021/ma00177a049	journal	November 1987
Transport coefficients of helical wormlike chains. 4. Intrinsic viscosity of the touched-bead model Yoshizaki, Takenao; Nitta, Itaru; Yamakawa, Hiromi Macromolecules, Vol. 21, Issue 1 https://doi.org/10.1021/ma00179a033	journal	January 1988
Phase Behavior of I₂S Single Graft Block Copolymer/Homopolymer Blends Yang, Lizhang; Gido, Samuel P.; Mays, Jimmy W. Macromolecules, Vol. 34, Issue 12 https://doi.org/10.1021/ma001901v	journal	May 2001
1,3-Cyclohexadiene Polymers. 3. Synthesis and Characterization of Poly(1,3-cyclohexadiene- block -styrene) Hong, Kunlun; Mays, Jimmy W. Macromolecules, Vol. 34, Issue 11 https://doi.org/10.1021/ma001926u	journal	May 2001
Tetrafunctional Multigraft Copolymers as Novel Thermoplastic Elastomers Weidisch, R.; Gido, S. P.; Uhrig, D. Macromolecules, Vol. 34, Issue 18 https://doi.org/10.1021/ma001966y	journal	August 2001
I ₅ S Miktoarm Star Block Copolymers: Packing Constraints on Morphology and Discontinuous Chevron Tilt Grain Boundaries Yang, Lizhang; Hong, Sheng; Gido, Samuel P. Macromolecules, Vol. 34, Issue 26 https://doi.org/10.1021/ma010737o	journal	December 2001
Analysis of Grain Structure in Partially Ordered Block Copolymers by Depolarized Light Scattering and Transmission Electron Microscopy Chang, M. Y.; Abuzaina, F. M.; Kim, W. G. Macromolecules, Vol. 35, Issue 11 https://doi.org/10.1021/ma0201025	journal	May 2002
Morphologies and Mechanical Properties of a Series of Block-Double-Graft Copolymers and Terpolymers Zhu, Yuqing; Weidisch, Roland; Gido, Samuel P. Macromolecules, Vol. 35, Issue 15 https://doi.org/10.1021/ma020345x	journal	June 2002
Functional Polymers from Novel Carboxyl-Terminated Trithiocarbonates as Highly Efficient RAFT Agents Lai, John T.; Filla, Debby; Shea, Ronald Macromolecules, Vol. 35, Issue 18 https://doi.org/10.1021/ma020362m	journal	August 2002
Synthesis of Combs, Centipedes, and Barbwires: Poly(isoprene- graft -styrene) Regular Multigraft Copolymers with Trifunctional, Tetrafunctional, and Hexafunctional Branch Points Uhrig, David; Mays, Jimmy W. Macromolecules, Vol. 35, Issue 19 https://doi.org/10.1021/ma020427l	journal	September 2002
Model Linear Block Co-, Ter-, and Quaterpolymers of 1,3-Cyclohexadiene with Styrene, Isoprene, and Butadiene Tsoukatos, Thodoris; Avgeropoulos, Apostolos; Hadjichristidis, Nikos Macromolecules, Vol. 35, Issue 21 https://doi.org/10.1021/ma020513l	journal	October 2002
Microphase Separation of Cyclic Block Copolymers of Styrene and Butadiene and of Their Corresponding Linear Triblock Copolymers Zhu, Yuqing; Gido, Samuel P.; Iatrou, Hermis Macromolecules, Vol. 36, Issue 1 https://doi.org/10.1021/ma021408e	journal	December 2002
Anionic Polymerization of Styrenic Macromonomers Pantazis, Dimitris; Chalari, Ioanna; Hadjichristidis, Nikos Macromolecules, Vol. 36, Issue 11 https://doi.org/10.1021/ma025898m	journal	May 2003
Effect of Junction Point Functionality on the Lamellar Spacing of Symmetric (PS) _n (PI) _n Miktoarm Star Block Copolymers Zhu, Yuqing; Gido, Samuel P.; Moshakou, Maria Macromolecules, Vol. 36, Issue 15 https://doi.org/10.1021/ma030254f	journal	July 2003
Utility of Interaction Chromatography for Probing Structural Purity of Model Branched Copolymers: 4-Miktoarm Star Copolymer Park, Soojin; Cho, Donghyun; Im, Kyuhyun Macromolecules, Vol. 36, Issue 15 https://doi.org/10.1021/ma034603h	journal	July 2003
Effect of Molecular Architecture on Dynamics of Multigraft Copolymers: Combs, Centipedes, and Barbwires Mijović, Jovan; Sun, Mingyun; Pejanović, Srdjan Macromolecules, Vol. 36, Issue 20 https://doi.org/10.1021/ma034881g	journal	October 2003
Interfacial Tension in Binary Polymer Blends in the Presence of Block Copolymers. 2. Effects of Additive Architecture and Composition Retsos, H.; Anastasiadis, S. H.; Pispas, S. Macromolecules, Vol. 37, Issue 2 https://doi.org/10.1021/ma035463e	journal	December 2003
Efficient Synthesis of ω-( p -Vinylbenzyl)polystyrene by Direct Functionalization of Poly(styryl)lithium with p -Vinylbenzyl Chloride in Hydrocarbon Solvent with Lithium 2,3-Dimethyl-3-pentoxide Quirk, Roderic P.; Pickel, Joseph M.; Arnould, Mark A. Macromolecules, Vol. 39, Issue 5 https://doi.org/10.1021/ma0511604	journal	March 2006
Morphology and Tensile Properties of Multigraft Copolymers with Regularly Spaced Tri-, Tetra-, and Hexafunctional Junction Points Zhu, Yuqing; Burgaz, Engin; Gido, Samuel P. Macromolecules, Vol. 39, Issue 13 https://doi.org/10.1021/ma060067s	journal	June 2006
Synthesis and Interfacial Behavior of Amphiphilic Hyperbranched Polymers: Poly(ethylene oxide)−Polystyrene Hyperbranches Peleshanko, S.; Gunawidjaja, R.; Petrash, S. Macromolecules, Vol. 39, Issue 14 https://doi.org/10.1021/ma060442g	journal	June 2006
Anthracene−Maleimide-Based Diels−Alder “Click Chemistry” as a Novel Route to Graft Copolymers Gacal, B.; Durmaz, H.; Tasdelen, M. A. Macromolecules, Vol. 39, Issue 16 https://doi.org/10.1021/ma060690c	journal	August 2006
New “All-Acrylate” Block Copolymers: Synthesis and Influence of the Architecture on the Morphology and the Mechanical Properties Jeusette, M.; Leclère, Ph.; Lazzaroni, R. Macromolecules, Vol. 40, Issue 4 https://doi.org/10.1021/ma061613k	journal	February 2007
Effect of Molecular Weight on the Mechanical and Electrical Properties of Block Copolymer Electrolytes Singh, Mohit; Odusanya, Omolola; Wilmes, Gregg M. Macromolecules, Vol. 40, Issue 13 https://doi.org/10.1021/ma0629541	journal	June 2007
Tough Polylactide Graft Copolymers Theryo, Grayce; Jing, Feng; Pitet, Louis M. Macromolecules, Vol. 43, Issue 18 https://doi.org/10.1021/ma101155p	journal	September 2010
Polystyrene- block -poly( n -butyl acrylate)- block -polystyrene Triblock Copolymer Thermoplastic Elastomer Synthesized via RAFT Emulsion Polymerization Luo, Yingwu; Wang, Xiaoguang; Zhu, Yue Macromolecules, Vol. 43, Issue 18 https://doi.org/10.1021/ma101348k	journal	September 2010
Precision Synthesis of ω-Branch, End-Functionalized Comb Polystyrenes Using Living Anionic Polymerization and Thiol–Ene “Click” Chemistry Liu, Boxi; Quirk, Roderic P.; Wesdemiotis, Chrys Macromolecules, Vol. 45, Issue 23 https://doi.org/10.1021/ma301897s	journal	November 2012
Linear-, Cyclic-, and Multiblock Amphiphilic Polyelectrolytes as Surfactants in Emulsion Polymerization: Role of Topological Structure Li, Lianwei; Yang, Jinxian; Zhou, Jianfeng Macromolecules, Vol. 46, Issue 7 https://doi.org/10.1021/ma3022025	journal	March 2013
A Novel Architecture toward Third-Generation Thermoplastic Elastomers by a Grafting Strategy Jiang, Feng; Wang, Zhongkai; Qiao, Yali Macromolecules, Vol. 46, Issue 12 https://doi.org/10.1021/ma4007472	journal	June 2013
Synthesis and Characterization of Comb and Centipede Multigraft Copolymers P n BA- g -PS with High Molecular Weight Using Miniemulsion Polymerization Wang, Wenwen; Wang, Weiyu; Lu, Xinyi Macromolecules, Vol. 47, Issue 21 https://doi.org/10.1021/ma501866t	journal	October 2014
Ionic Clusters in High-Strength Carboxylic Rubbers Tobolsky, A. V.; Lyons, P. F.; Hata, N. Macromolecules, Vol. 1, Issue 6 https://doi.org/10.1021/ma60006a012	journal	November 1968
Synthesis and Properties of Block Copolymers. 3. Polystyrene-Polydiene Star Block Copolymers Bi, Le-Khac; Fetters, Lewis J. Macromolecules, Vol. 9, Issue 5 https://doi.org/10.1021/ma60053a010	journal	September 1976
Polar Three-Arm Star Block Copolymer Thermoplastic Elastomers Based on Polyacrylonitrile Dufour, Bruno; Tang, Chuanbing; Koynov, Kaloian Macromolecules, Vol. 41, Issue 7 https://doi.org/10.1021/ma702561b	journal	April 2008
Deformation Behavior of Sphere-Forming Trifunctional Multigraft Copolymer Duan, Yongxin; Rettler, Erik; Schneider, Konrad Macromolecules, Vol. 41, Issue 13 https://doi.org/10.1021/ma801036y	journal	July 2008
Synthesis and Dilute Solution Properties of Well-Defined H-Shaped Polybutadienes Rahman, M. Shahinur; Aggarwal, Ravi; Larson, Ronald G. Macromolecules, Vol. 41, Issue 21 https://doi.org/10.1021/ma801646u	journal	October 2008
Segmental Orientation in Well-Defined Thermoplastic Elastomers Containing Supramolecular Fillers Wisse, Eva; Spiering, A. J. H.; Pfeifer, Frank Macromolecules, Vol. 42, Issue 2 https://doi.org/10.1021/ma801668k	journal	December 2008
Morphology and Deformation Mechanisms and Tensile Properties of Tetrafunctional Multigraft Copolymers Duan, Yongxin; Thunga, Mahendra; Schlegel, Ralf Macromolecules, Vol. 42, Issue 12 https://doi.org/10.1021/ma900414h	journal	June 2009
Synthesis, Characterization, and Properties of Starlike Poly( n -butyl acrylate)- b -poly(methyl methacrylate) Block Copolymers Nese, Alper; Mosnác̆ek, Jaroslav; Juhari, Azhar Macromolecules, Vol. 43, Issue 3 https://doi.org/10.1021/ma902447p	journal	February 2010
Morphologies of Microphase-Separated A ₂ B Simple Graft Copolymers Pochan, Darrin J.; Gido, Samuel P.; Pispas, Stergios Macromolecules, Vol. 29, Issue 15 https://doi.org/10.1021/ma951696x	journal	January 1996
Morphological Transitions in an I ₂ S Simple Graft Block Copolymer: From Folded Sheets to Folded Lace to Randomly Oriented Worms at Equilibrium Pochan, Darrin J.; Gido, Samuel P.; Pispas, Stergios Macromolecules, Vol. 29, Issue 15 https://doi.org/10.1021/ma9601225	journal	January 1996
Synthesis, Characterization, and Morphology of Model Graft Copolymers with Trifunctional Branch Points Gido, Samuel P.; Lee, Chin; Pochan, Darrin J. Macromolecules, Vol. 29, Issue 22 https://doi.org/10.1021/ma960715f	journal	January 1996
Morphology of Vergina Star 16-Arm Block Copolymers and Scaling Behavior of Interfacial Area with Graft Point Functionality Beyer, Frederick L.; Gido, Samuel P.; Poulos, Yiannis Macromolecules, Vol. 30, Issue 8 https://doi.org/10.1021/ma961855s	journal	April 1997
Asymmetric Single Graft Block Copolymers: Effect of Molecular Architecture on Morphology Lee, Chin; Gido, Samuel P.; Pitsikalis, Marinos Macromolecules, Vol. 30, Issue 13 https://doi.org/10.1021/ma970172p	journal	June 1997
Interfacial Curvature in Graft and Diblock Copolymers and Implications for Long-Range Order in Cylindrical Morphologies Gido, Samuel P.; Wang, Zhen-Gang Macromolecules, Vol. 30, Issue 22 https://doi.org/10.1021/ma9703564	journal	November 1997
Synthesis of Model Multigraft Copolymers of Butadiene with Randomly Placed Single and Double Polystyrene Branches Xenidou, Maria; Hadjichristidis, Nikos Macromolecules, Vol. 31, Issue 17 https://doi.org/10.1021/ma980362f	journal	August 1998
Regular Comb Polystyrenes and Graft Polyisoprene/Polystyrene Copolymers with Double Branches (“Centipedes”). Quality of (1,3-Phenylene)bis(3-methyl-1-phenylpentylidene)dilithium Initiator in the Presence of Polar Additives Iatrou, Hermis; Mays, Jimmy W.; Hadjichristidis, Nikos Macromolecules, Vol. 31, Issue 19 https://doi.org/10.1021/ma980738p	journal	September 1998
Morphology of Model Graft Copolymers with Randomly Placed Trifunctional and Tetrafunctional Branch Points Xenidou, Maria; Beyer, Frederick L.; Hadjichristidis, Nikos Macromolecules, Vol. 31, Issue 22 https://doi.org/10.1021/ma980858x	journal	November 1998
Core−Shell Cylinder Morphology in Poly(styrene- b -1,3-cyclohexadiene) Diblock Copolymers David, Jennifer L.; Gido, Samuel P.; Hong, Kunlun Macromolecules, Vol. 32, Issue 10 https://doi.org/10.1021/ma9810722	journal	April 1999
Copolymerization of n -Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers: Comparison of Reactivity Ratios in Conventional and Atom Transfer Radical Copolymerization Roos, Sebastian G.; Müller, Axel H. E.; Matyjaszewski, Krzysztof Macromolecules, Vol. 32, Issue 25 https://doi.org/10.1021/ma9819337	journal	December 1999
Dependence of the Ultimate Tensile Strength of Thermoplastic Elastomers of the Triblock Type on the Molecular Weight between Chain Entanglements of the Central Block Tong, Jiang-Dong; Jerôme, Robert Macromolecules, Vol. 33, Issue 5 https://doi.org/10.1021/ma990404f	journal	March 2000
Synthesis and Characterization of Poly(methyl methacrylate)- block -poly( n -butyl acrylate)- block -poly(methyl methacrylate) Copolymers by Two-Step Controlled Radical Polymerization (ATRP) Catalyzed by NiBr ₂ (PPh ₃ ) ₂ , 1 ^† Moineau, C.; Minet, M.; Teyssié, P. Macromolecules, Vol. 32, Issue 25 https://doi.org/10.1021/ma990783c	journal	December 1999
Morphological Behavior of A ₅ B Miktoarm Star Block Copolymers Beyer, Frederick L.; Gido, Samuel P.; Velis, Gabriel Macromolecules, Vol. 32, Issue 20 https://doi.org/10.1021/ma9909713	journal	October 1999
Graft Copolymers with Regularly Spaced, Tetrafunctional Branch Points: Morphology and Grain Structure Beyer, Frederick L.; Gido, Samuel P.; Büschl, Christine Macromolecules, Vol. 33, Issue 6 https://doi.org/10.1021/ma991141s	journal	March 2000
Polystyrene with Dendritic Branching by Convergent Living Anionic Polymerization Knauss, Daniel M.; Al-Muallem, Hasan A.; Huang, Tianzi Macromolecules, Vol. 33, Issue 10 https://doi.org/10.1021/ma991509l	journal	April 2000
Well-defined graft copolymers: from controlled synthesis to multipurpose applications Feng, Chun; Li, Yongjun; Yang, Dong Chem. Soc. Rev., Vol. 40, Issue 3 https://doi.org/10.1039/B921358A	journal	January 2011
Synthesis of well-defined multigraft copolymers Uhrig, David; Mays, Jimmy Polym. Chem., Vol. 2, Issue 1 https://doi.org/10.1039/C0PY00185F	journal	January 2011
Synthesis of well-controlled graft polymers by living anionic polymerization towards exact graft polymers Ito, Shotaro; Goseki, Raita; Ishizone, Takashi Polymer Chemistry, Vol. 5, Issue 19 https://doi.org/10.1039/C4PY00584H	journal	January 2014
All acrylic-based thermoplastic elastomers with high upper service temperature and superior mechanical properties Lu, Wei; Wang, Yangyang; Wang, Weiyu Polymer Chemistry, Vol. 8, Issue 37 https://doi.org/10.1039/C7PY01225J	journal	January 2017
All-acrylic superelastomers: facile synthesis and exceptional mechanical behavior Lu, Wei; Goodwin, Andrew; Wang, Yangyang Polymer Chemistry, Vol. 9, Issue 2 https://doi.org/10.1039/C7PY01518F	journal	January 2018
Organic–inorganic hybrid tinphosphonate material with mesoscopic void spaces: an excellent catalyst for the radical polymerization of styrene Pramanik, Malay; Nandi, Mahasweta; Uyama, Hiroshi Catalysis Science & Technology, Vol. 2, Issue 3 https://doi.org/10.1039/c2cy00352j	journal	January 2012
Copolymerization of isoprene and hydroxyl containing monomers by controlled radical and emulsion methods Gramlich, William M.; Theryo, Grayce; Hillmyer, Marc A. Polymer Chemistry, Vol. 3, Issue 6 https://doi.org/10.1039/c2py20072d	journal	January 2012
H‐shaped double graft copolymers: Effect of molecular architecture on morphology Lee, Chin; Gido, Samuel P.; Poulos, Yiannis The Journal of Chemical Physics, Vol. 107, Issue 16 https://doi.org/10.1063/1.3396313	journal	October 1997
Ordered morphologies in binary blends of diblock copolymer and homopolymer and characterization of their intermaterial dividing surfaces Winey, Karen I.; Thomas, Edwin L.; Fetters, Lewis J. The Journal of Chemical Physics, Vol. 95, Issue 12 https://doi.org/10.1063/1.461164	journal	December 1991
In-Situ Synthesis of PBA- graft -PMMA Copolymers to Be Used as Compatibilizing Agents in PBA/PMMA Composite Latex Particles via the Macromonomer Method Rajatapiti, Prapasri; Dimonie, Victoria L.; El-Aasser, Mohamed S. Journal of Macromolecular Science, Part A, Vol. 32, Issue 8-9 https://doi.org/10.1080/10601329508013690	journal	August 1995
Anisotropy of lamellar block copolymer grains Balsara, N. P.; Marques, C. M.; Garetz, B. A. Physical Review E, Vol. 66, Issue 5 https://doi.org/10.1103/PhysRevE.66.052802	journal	November 2002
Investigation of Thermodynamic Properties of SIS, SEBS, and Naphthenic Oil by Inverse Gas Chromatography Wu, Peng; Qi, Shuhua; Nie, Haiying Journal of Elastomers & Plastics, Vol. 43, Issue 4, p. 369-386 https://doi.org/10.1177/0095244311405000	journal	April 2011
New Polybutadiene-Based Thermoplastic Elastomers: Synthesis, Morphology and Mechanical Properties Dubois, Ph; Yu, Y. S.; Teyssié, Ph Rubber Chemistry and Technology, Vol. 70, Issue 5 https://doi.org/10.5254/1.3538455	journal	November 1997
Hydroxyl-Terminated Polybutadiene Telechelic Polymer (HTPB): Binder for Solid Rocket Propellants Ajaz, A. G. Rubber Chemistry and Technology, Vol. 68, Issue 3 https://doi.org/10.5254/1.3538752	journal	July 1995
New Thermoplastic Elastomers. Styrene Grafts on Lithiated Polydienes and Their Hydrogenated Counterparts Falk, J. C.; Schlott, R. J.; Hoeg, D. F. Rubber Chemistry and Technology, Vol. 46, Issue 4 https://doi.org/10.5254/1.3547404	journal	September 1973

Similar Records

All-acrylic superelastomers: facile synthesis and exceptional mechanical behavior

Journal Article · Tue Oct 17 00:00:00 EDT 2017 · Polymer Chemistry · OSTI ID:1479807

Multigraft Copolymer Superelastomers: Synthesis Morphology, and Properties

Journal Article · Fri Dec 31 23:00:00 EST 2010 · European Polymer Journal · OSTI ID:1081754

Synthesis and Structure - Property Relationships for Regular Multigraft Copolymers

Journal Article · Wed Dec 31 23:00:00 EST 2003 · Macromolecular Symposia · OSTI ID:1003183

All-acrylic multigraft copolymer superelastomers

Citation Formats

References (137)

Similar Records

Related Subjects