All-acrylic multigraft copolymer superelastomers

Mays, Jimmy W.; Lu, Wei; Kang, Nam-Goo

Title: All-acrylic multigraft copolymer superelastomers

Patent · Tue May 10 00:00:00 EDT 2022

OSTI ID:1892910

Mays, Jimmy W.; Lu, Wei; Kang, Nam-Goo

Thermoplastic elastomer compositions comprising acrylic multigraft copolymers are described. The multigraft copolymers comprise a rubbery polyacrylate backbone and a plurality of randomly spaced glassy polyacrylate side chains. The multigraft copolymers can be prepared using a facile grafting through method that can provide copolymers with enhanced purity. The acrylic multigraft copolymers exhibit microphase separated morphologies and “superelastomeric” properties, including an elongation at break, stress at break, and/or strain recovery behavior that exceeds that of conventional triblock copolymer polyacrylate thermoplastic elastomers.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: ACO5-000R22725

Assignee:: University of Tennessee Research Foundation (Knoxville, TN)

Patent Number(s):: 11,325,991

Application Number:: 16/608,614

OSTI ID:: 1892910

Resource Relation:: Patent File Date: 04/25/2018

Country of Publication:: United States

Language:: English

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