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Use of inverse quasi-epitaxy to modify order during post-deposition processing of organic photovoltaics

Patent ·
OSTI ID:1414404
Disclosed herein are methods for fabricating an organic photovoltaic device comprising depositing an amorphous organic layer and a crystalline organic layer over a first electrode, wherein the amorphous organic layer and the crystalline organic layer contact one another at an interface; annealing the amorphous organic layer and the crystalline organic layer for a time sufficient to induce at least partial crystallinity in the amorphous organic layer; and depositing a second electrode over the amorphous organic layer and the crystalline organic layer. In the methods and devices herein, the amorphous organic layer may comprise at least one material that undergoes inverse-quasi epitaxial (IQE) alignment to a material of the crystalline organic layer as a result of the annealing.
Research Organization:
The Regents of the University of Michigan, Ann Arbor, MI (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0000957; EE0005310
Assignee:
The Regents of the University of Michigan (Ann Arbor, MI)
Patent Number(s):
9,847,487
Application Number:
14/646,136
OSTI ID:
1414404
Country of Publication:
United States
Language:
English

References (6)

Functionalized Squaraine Donors for Nanocrystalline Organic Photovoltaics journal December 2011
Small-Molecule Photovoltaics Based on Functionalized Squaraine Donor Blends journal March 2012
Independent Control of Bulk and Interfacial Morphologies of Small Molecular Weight Organic Heterojunction Solar Cells journal July 2012
Efficient, Ordered Bulk Heterojunction Nanocrystalline Solar Cells by Annealing of Ultrathin Squaraine Thin Films journal September 2010
Control of Interface Order by Inverse Quasi-Epitaxial Growth of Squaraine/Fullerene Thin Film Photovoltaics journal September 2013
Solvent-Annealed Crystalline Squaraine: PC70BM (1:6) Solar Cells journal February 2011

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