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Hybrid planar-mixed heterojunction for organic photovoltaics

Patent ·
OSTI ID:1840450
Disclosed herein are organic photosensitive optoelectronic devices comprising two electrodes in superposed relation; a mixed photoactive layer located between the two electrodes, wherein the mixed photoactive layer comprises at least one donor material having a HOMO energy and at least one acceptor material having a LUMO energy, wherein the at least one donor material and the at least one acceptor material form a mixed donor-acceptor heterojunction; a photoactive layer adjacent to and interfacing with the mixed photoactive layer, wherein the photoactive layer comprises a material having a LUMO energy within 0.3 eV of the LUMO energy of the at least one acceptor material or a HOMO energy within 0.3 eV of the HOMO energy of the at least one donor material; and a buffer layer adjacent to and interfacing with the mixed photoactive layer.
Research Organization:
Univ. of Michigan, Ann Arbor, MI (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0000957
Assignee:
The Regents of the University of Michigan (Ann Arbor, MI)
Patent Number(s):
11,121,336
Application Number:
14/646,154
OSTI ID:
1840450
Country of Publication:
United States
Language:
English

References (4)

Origin of open circuit voltage in planar and bulk heterojunction organic thin-film photovoltaics depending on doped transport layers journal August 2008
Mixed donor-acceptor molecular heterojunctions for photovoltaic applications. II. Device performance journal December 2005
Effect of MoO3 as an interlayer on the performance of organic solar cells based on ZnPc and C60 journal January 2012
A Hybrid Planar-Mixed Molecular Heterojunction Photovoltaic Cell journal January 2005

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