Rapid Screening of Immobilized Amine CO 2 Sorbents for Steam Stability by Their Direct Contact with Liquid H 2 O

Wilfong, Walter Christopher; Kail, Brian W.; Gray, McMahan L.

doi:10.1002/cssc.201500189

Rapid Screening of Immobilized Amine CO ₂ Sorbents for Steam Stability by Their Direct Contact with Liquid H ₂ O

Journal Article · Tue May 26 00:00:00 EDT 2015 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201500189· OSTI ID:1401388

Wilfong, Walter Christopher; Kail, Brian W.; Gray, McMahan L.

Abstract

Rapid testing of hydrophilic and hydrophobic basic immobilized amine sorbents (BIAS) for CO ₂ capture stability under practical conditions was achieved by direct contact of the sorbents with flowing liquid water. Losses in both CO ₂ capture capacity and amine content of sorbents after exposure to 0.5 mL min ⁻¹ of H ₂ O at 25 °C for 40 min followed similar trends as losses observed after exposure to N ₂ /steam (105 °C, 7 % H ₂ O) for 10 h. We also found that hydrophobic TMPED helped stabilize sorbents to H ₂ O, which was confirmed by DRIFTS and combined TGA‐DSC.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1401388

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 12 Vol. 8; ISSN 1864-5631

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Rapid Screening of Immobilized Amine CO ₂ Sorbents for Steam Stability by Their Direct Contact with Liquid H ₂ O