Novel Rapid Screening of Basic Immobilized Amine Sorbent/Catalyst Water Stability by a UV/Vis/Cu 2+ Technique

Wilfong, Walter Christopher; Kail, Brian W.; Wang, Qiuming; Gray, McMahan L.

doi:10.1002/cssc.201801851

Novel Rapid Screening of Basic Immobilized Amine Sorbent/Catalyst Water Stability by a UV/Vis/Cu ²⁺ Technique

Journal Article · Tue Oct 30 00:00:00 EDT 2018 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201801851· OSTI ID:1479835

^[1]; Kail, Brian W. ^[1]; Wang, Qiuming ^[2]; Gray, McMahan L. ^[3]

Functional Materials Development Division AECOM/Department of Energy 626 Cochrans Mill Rd. Pittsburgh PA 15236 USA
Functional Materials Development Division Oak Ridge Institute for Science and Education (ORISE)/Department of Energy USA
Functional Materials Development Division Department of Energy USA

Abstract

Time‐consuming thermogravimetric analysis (TGA) decomposition study is a typical practice to assess the stability of fresh and water‐treated basic immobilized amine sorbents (BIAS)/catalysts. This work presents a faster and more precise spectroscopic UV/Vis/Cu ²⁺ sorbent screening technique that quantifies aqueous amines washed from the BIAS by using UV‐active amine/Cu ²⁺ complexes. Six BIAS‐based catalysts, containing different amine species and a crosslinker within silica, were treated with ultrapure water and then analyzed for their CO ₂ capture performance and amine leach resistance/stability by using TGA (catalysts, approximately 4 h) and UV/Vis/Cu ²⁺ techniques (wash solution, few minutes). A comparative analysis revealed that directly quantifying washed amines with UV/Vis/Cu ²⁺ is 9–127 times more precise than indirect testing of the sorbents by TGA. Similar trends in the H ₂ O stability profiles of the catalysts [organic content retained values (OCR)] were reported by both analysis methods, allowing UV/Vis/Cu ²⁺ to replace TGA for quantifying unstable leached amines. The UV/Vis/Cu ²⁺ OCR results could be used to predict the CO ₂ ‐capture stability profile of the sorbents, confirming the reliability of this technique to rapidly screen catalyst stability and performance.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0004000

OSTI ID:: 1479835

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 23 Vol. 11; ISSN 1864-5631

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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