Synthesis of Monodisperse Palladium Nanoclusters Using Metal–Organic Frameworks as Sacrificial Templates

Li, Xinle; Goh, Tian Wei; Xiao, Chaoxian; Stanton, Alexandria L. D.; Pei, Yuchen; Jain, Prashant K.; Huang, Wenyu

doi:10.1002/cnma.201600121

Synthesis of Monodisperse Palladium Nanoclusters Using Metal–Organic Frameworks as Sacrificial Templates

Journal Article · Mon Jun 20 00:00:00 EDT 2016 · ChemNanoMat

DOI:https://doi.org/10.1002/cnma.201600121· OSTI ID:1400977

Li, Xinle ^[1]; Goh, Tian Wei ^[1]; Xiao, Chaoxian ^[1]; Stanton, Alexandria L. D. ^[2]; Pei, Yuchen ^[1]; ^[2]; ^[1]

Department of Chemistry Iowa State University Ames Laboratory U.S. Department of Energy Ames Iowa 50011 United States
Department of Chemistry University of Illinois at Urbana-Champaign Urbana Illinois 61801 United States

Abstract

An interfacial etching approach was developed for the synthesis of monodisperse and ultrasmall thiolated palladium nanoclusters (Pd NCs) using Zr‐UiO‐66‐NH ₂ metal–organic frameworks (MOFs) as sacrificial templates. The Pd NCs were originally synthesized inside the cavities of the MOFs (Pd@UiO‐66‐NH ₂ ). The Pd NCs released from the MOFs have a strikingly small size with narrow distribution (1.1±0.1 nm), amounting to a cluster size of ca. 40 Pd atoms. The ¹ H NMR spectrum indicates that thiol is the only capping agent for these Pd NCs. We derived the composition of the thiolated Pd NCs using thermogravimetric analysis (TGA) and inductively coupled plasma mass spectrometry (ICP‐MS) analysis. Moreover, the Pd NCs size can be tuned by using MOF templates with different cavity sizes. The thiolated Pd NCs are catalytically active in a model Suzuki–Miyaura coupling reaction.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1400977

Journal Information:: ChemNanoMat, Journal Name: ChemNanoMat Journal Issue: 8 Vol. 2; ISSN 2199-692X

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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