Tandem catalysis by palladium nanoclusters encapsulated in metal–organic frameworks

Li, Xinle; Guo, Zhiyong; Xiao, Chaoxian; Goh, Tian Wei; Tesfagaber, Daniel; Huang, Wenyu

doi:10.1021/cs5006635

Tandem catalysis by palladium nanoclusters encapsulated in metal–organic frameworks

Journal Article · Mon Aug 25 00:00:00 EDT 2014 · ACS Catalysis

DOI:https://doi.org/10.1021/cs5006635· OSTI ID:1225525

Li, Xinle ^[1]; Guo, Zhiyong ^[1]; Xiao, Chaoxian ^[1]; Goh, Tian Wei ^[1]; Tesfagaber, Daniel ^[1]; Huang, Wenyu ^[1]

Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States)

A bifunctional Zr-MOF catalyst containing palladium nanoclusters (NCs) has been developed. The formation of Pd NCs was confirmed by transmission electron microscopy (TEM) and extended X-ray absorption fine structure (EXAFS). Combining the oxidation activity of Pd NCs and the acetalization activity of the Lewis acid sites in UiO-66-NH₂, this catalyst (Pd@UiO-66-NH₂) exhibits excellent catalytic activity and selectivity in a one-pot tandem oxidation-acetalization reaction. This catalyst shows 99.9% selectivity to benzaldehyde ethylene acetal in the tandem reaction of benzyl alcohol and ethylene glycol at 99.9% conversion of benzyl alcohol. We also examined various substituted benzyl alcohols and found that alcohols with electron-donating groups showed better conversion and selectivity compared to those with electron-withdrawing groups. As a result, we further proved that there was no leaching of active catalytic species during the reaction and the catalyst can be recycled at least five times without significant deactivation.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

OSTI ID:: 1225525

Alternate ID(s):: OSTI ID: 1163397

Report Number(s):: IS-J--8534

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 10 Vol. 4; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

Cascade Reactions in Total Synthesis Nicolaou, K. C.; Edmonds, David J.; Bulger, Paul G. Angewandte Chemie International Edition, Vol. 45, Issue 43 https://doi.org/10.1002/anie.200601872	journal	November 2006
Metal-Organic Frameworks: Opportunities for Catalysis Farrusseng, David; Aguado, Sonia; Pinel, Catherine Angewandte Chemie International Edition, Vol. 48, Issue 41 https://doi.org/10.1002/anie.200806063	journal	September 2009
Mesoporous Organosilicas with Acidic Frameworks and Basic Sites in the Pores: An Approach to Cooperative Catalytic Reactions Shylesh, Sankaranarayanapillai; Wagener, Alex; Seifert, Andreas Angewandte Chemie International Edition, Vol. 49, Issue 1 https://doi.org/10.1002/anie.200903985	journal	December 2009
Mesoporous Silica with Site-Isolated Amine and Phosphotungstic Acid Groups: A Solid Catalyst with Tunable Antagonistic Functions for One-Pot Tandem Reactions Shiju, N. Raveendran; Alberts, Albert H.; Khalid, Syed Angewandte Chemie International Edition, Vol. 50, Issue 41 https://doi.org/10.1002/anie.201101449	journal	September 2011
Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks Vermoortele, Frederik; Vandichel, Matthias; Van de Voorde, Ben Angewandte Chemie International Edition, Vol. 51, Issue 20 https://doi.org/10.1002/anie.201108565	journal	April 2012
Efficient Iron-Catalyzed Acetal Formation from Styrene Derivatives Ray, Ritwika; Chowdhury, Abhishek Dutta; Lahiri, Goutam Kumar ChemCatChem, Vol. 5, Issue 8 https://doi.org/10.1002/cctc.201300270	journal	May 2013
Deposition of Gold Clusters on Porous Coordination Polymers by Solid Grinding and Their Catalytic Activity in Aerobic Oxidation of Alcohols Ishida, Tamao; Nagaoka, Megumi; Akita, Tomoki Chemistry - A European Journal, Vol. 14, Issue 28 https://doi.org/10.1002/chem.200800980	journal	September 2008
Selective Palladium-Loaded MIL-101 Catalysts Hermannsdörfer, Justus; Kempe, Rhett Chemistry - A European Journal, Vol. 17, Issue 29 https://doi.org/10.1002/chem.201101004	journal	June 2011
Highly Efficient and Versatile Acetalization of Glycol Catalyzed by Cupricp-Toluenesulfonate Liu, Cai-Hua; Yu, Xin-Yu; Liang, Xue-Zheng Chinese Journal of Chemistry, Vol. 25, Issue 1 https://doi.org/10.1002/cjoc.200790022	journal	January 2007
From Alkyl Aromatics to Aromatic Esters: Efficient and Selective CH Activation Promoted by a Bimetallic Heterogeneous Catalyst Liu, Hongli; Chen, Gongzhou; Jiang, Huanfeng ChemSusChem, Vol. 5, Issue 10 https://doi.org/10.1002/cssc.201200611	journal	September 2012
Performance and Characterization of a New Crystalline SbRe2O6 Catalyst for Selective Oxidation of Methanol to Methylal Yuan, Youzhu; Liu, Haichao; Imoto, Hideo Journal of Catalysis, Vol. 195, Issue 1 https://doi.org/10.1006/jcat.2000.2990	journal	October 2000
One-Step Synthesis of Acetals from Phenol/Alcohols Mixtures Using a Pd/Aluminoborate Catalyst Guan, Yejun; Zhang, Damin; Wang, Yimeng Catalysis Letters, Vol. 142, Issue 10 https://doi.org/10.1007/s10562-012-0891-4	journal	August 2012
On the Stability and Recyclability of Supported Metal–Ligand Complex Catalysts: Myths, Misconceptions and Critical Research Needs Jones, Christopher W. Topics in Catalysis, Vol. 53, Issue 13-14 https://doi.org/10.1007/s11244-010-9513-9	journal	May 2010
4.18 Photocatalytic Oxidation of Ethanol over Tantalum Oxide Supported on Silica Tanaka, Tsunehiro; Takenaka, Sakae; Funabiki, Takuzo Acid-Base Catalysis II, Proceedings of the International Symposium on Acid-Base Catalysis II https://doi.org/10.1016/S0167-2991(08)61863-7	book	January 1994
Palladium-catalyzed oxidation of primary alcohols: Highly selective direct synthesis of acetals Bueno, Aline C.; Gonçalves, José A.; Gusevskaya, Elena V. Applied Catalysis A: General, Vol. 329 https://doi.org/10.1016/j.apcata.2007.06.008	journal	October 2007
Effects of linker substitution on catalytic properties of porous zirconium terephthalate UiO-66 in acetalization of benzaldehyde with methanol Timofeeva, Maria N.; Panchenko, Valentina N.; Jun, Jong Won Applied Catalysis A: General, Vol. 471 https://doi.org/10.1016/j.apcata.2013.11.039	journal	February 2014
Highly productive iron molybdate mixed oxides and their relevant catalytic properties for direct synthesis of 1,1-dimethoxymethane from methanol Thavornprasert, Kaew-arpha; Capron, Mickaël; Jalowiecki-Duhamel, Louise Applied Catalysis B: Environmental, Vol. 145 https://doi.org/10.1016/j.apcatb.2013.01.043	journal	February 2014
Glycerol acetals as anti-freezing additives for biodiesel Silva, Paulo H. R.; Gonçalves, Valter L. C.; Mota, Claudio J. A. Bioresource Technology, Vol. 101, Issue 15 https://doi.org/10.1016/j.biortech.2010.02.101	journal	August 2010
Ab initio theory and calculations of X-ray spectra Rehr, John J.; Kas, Joshua J.; Prange, Micah P. Comptes Rendus Physique, Vol. 10, Issue 6 https://doi.org/10.1016/j.crhy.2008.08.004	journal	July 2009
Supported oxorhenate catalysts prepared by thermal spreading of metal Re0 for methanol conversion to methylal Sécordel, Xavier; Yoboué, Anthony; Cristol, Sylvain Journal of Solid State Chemistry, Vol. 184, Issue 10 https://doi.org/10.1016/j.jssc.2011.08.002	journal	October 2011
TiO2 nanotubes supported V2O5 for the selective oxidation of methanol to dimethoxymethane Liu, Jingwei; Fu, Yuchuan; Sun, Qing Microporous and Mesoporous Materials, Vol. 116, Issue 1-3 https://doi.org/10.1016/j.micromeso.2008.05.032	journal	December 2008
Reaction of benzaldehyde with various aliphatic glycols in the presence of hydrophobic Al-MCM-41: A convenient synthesis of cyclic acetals Ajaikumar, S.; Pandurangan, A. Journal of Molecular Catalysis A: Chemical, Vol. 290, Issue 1-2 https://doi.org/10.1016/j.molcata.2008.04.008	journal	July 2008
Sequential and tandem oxidation/acetalization procedures for the direct generation of acetals from alcohols Smith, Brendan M.; Graham, Andrew E. Tetrahedron Letters, Vol. 48, Issue 28 https://doi.org/10.1016/j.tetlet.2007.05.060	journal	July 2007
Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory Valenzano, Loredana; Civalleri, Bartolomeo; Chavan, Sachin Chemistry of Materials, Vol. 23, Issue 7, p. 1700-1718 https://doi.org/10.1021/cm1022882	journal	April 2011
Au@ZIFs: Stabilization and Encapsulation of Cavity-Size Matching Gold Clusters inside Functionalized Zeolite Imidazolate Frameworks, ZIFs Esken, Daniel; Turner, Stuart; Lebedev, Oleg I. Chemistry of Materials, Vol. 22, Issue 23 https://doi.org/10.1021/cm102529c	journal	December 2010
Metal–Organic Framework Thin Films: From Fundamentals to Applications. Bétard, Angélique; Fischer, Roland A. Chemical Reviews, Vol. 112, Issue 2, p. 1055-1083 https://doi.org/10.1021/cr200167v	journal	September 2011
Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks Getman, Rachel B.; Bae, Youn-Sang; Wilmer, Christopher E. Chemical Reviews, Vol. 112, Issue 2, p. 703-723 https://doi.org/10.1021/cr200217c	journal	September 2011
Metal–Organic Frameworks in Biomedicine Horcajada, Patricia; Gref, Ruxandra; Baati, Tarek Chemical Reviews, Vol. 112, Issue 2, p. 1232-1268 https://doi.org/10.1021/cr200256v	journal	September 2011
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
A Multifunction Pd/Sc(OTf) ₃ /Ionic Liquid Catalyst System for the Tandem One-Pot Conversion of Phenol to ε-Caprolactam Shin, Ju Yeon; Jung, Da Jung; Lee, Sang-gi ACS Catalysis, Vol. 3, Issue 4 https://doi.org/10.1021/cs400009w	journal	February 2013
Improved Low-Temperature CO Oxidation Performance of Pd Supported on La-Stabilized Alumina Gaudet, Jason R.; de la Riva, Andrew; Peterson, Eric J. ACS Catalysis, Vol. 3, Issue 5 https://doi.org/10.1021/cs400024u	journal	April 2013
Pt Nanoclusters Confined within Metal–Organic Framework Cavities for Chemoselective Cinnamaldehyde Hydrogenation Guo, Zhiyong; Xiao, Chaoxian; Maligal-Ganesh, Raghu V. ACS Catalysis, Vol. 4, Issue 5, p. 1340-1348 https://doi.org/10.1021/cs400982n	journal	April 2014
Synergistic Catalysis of Au@Ag Core−Shell Nanoparticles Stabilized on Metal−Organic Framework Jiang, Hai-Long; Akita, Tomoki; Ishida, Tamao Journal of the American Chemical Society, Vol. 133, Issue 5 https://doi.org/10.1021/ja1099006	journal	February 2011
Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage Gu, Xiaojun; Lu, Zhang-Hui; Jiang, Hai-Long Journal of the American Chemical Society, Vol. 133, Issue 31 https://doi.org/10.1021/ja200122f	journal	August 2011
Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal–Organic Framework: A Double Solvents Approach Aijaz, Arshad; Karkamkar, Abhi; Choi, Young Joon Journal of the American Chemical Society, Vol. 134, Issue 34 https://doi.org/10.1021/ja3043905	journal	August 2012
Immobilizing Metal Nanoparticles to Metal–Organic Frameworks with Size and Location Control for Optimizing Catalytic Performance Zhu, Qi-Long; Li, Jun; Xu, Qiang Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja403330m	journal	May 2013
Core–Shell Palladium Nanoparticle@Metal–Organic Frameworks as Multifunctional Catalysts for Cascade Reactions Zhao, Meiting; Deng, Ke; He, Liangcan Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja411468e	journal	January 2014
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Selective One-Step Synthesis of Dimethoxymethane via Methanol or Dimethyl Ether Oxidation on H _{3+ n} V _n Mo _{12- n} PO ₄₀ Keggin Structures Liu, Haichao; Iglesia, Enrique The Journal of Physical Chemistry B, Vol. 107, Issue 39 https://doi.org/10.1021/jp0301554	journal	October 2003
Methanol Reactions over Oxygen-Modified Re Surfaces: Influence of Surface Structure and Oxidation ^† Chan, Ally S. Y.; Chen, Wenhua; Wang, Hao The Journal of Physical Chemistry B, Vol. 108, Issue 38 https://doi.org/10.1021/jp040168x	journal	September 2004
Selective Oxidation of Methanol and Ethanol on Supported Ruthenium Oxide Clusters at Low Temperatures ^† Liu, Haichao; Iglesia, Enrique The Journal of Physical Chemistry B, Vol. 109, Issue 6 https://doi.org/10.1021/jp0401980	journal	February 2005
Metal−Organic Framework Supported Gold Nanoparticles as a Highly Active Heterogeneous Catalyst for Aerobic Oxidation of Alcohols Liu, Hongli; Liu, Yaling; Li, Yingwei The Journal of Physical Chemistry C, Vol. 114, Issue 31 https://doi.org/10.1021/jp105666f	journal	July 2010
Reversible Structural Transformation of Palladium Catalyst Supported on La−Al ₂ O ₃ Probed with X-ray Absorption Fine Structure Cho, Sung June; Kang, Sung Kyu The Journal of Physical Chemistry B, Vol. 104, Issue 34 https://doi.org/10.1021/jp991857p	journal	August 2000
Palladium-Catalyzed Intramolecular Trapping of the Blaise Reaction Intermediate for Tandem One-Pot Synthesis of Indole Derivatives Kim, Ju Hyun; Lee, Sang-gi Organic Letters, Vol. 13, Issue 6 https://doi.org/10.1021/ol200045q	journal	March 2011
TPAP-Catalyzed Direct Oxidation of Primary Alcohols to Carboxylic Acids through Stabilized Aldehyde Hydrates Schmidt, Andrea-Katharina C.; Stark, Christian B. W. Organic Letters, Vol. 13, Issue 16 https://doi.org/10.1021/ol2014335	journal	August 2011
Coordination and Reactivity Study of Group 4 and 10 Transition Metal Complexes of N -Imidazol-2-ylidene- N ′- p -tolylureate and Thioureate Ligands Harkness, Michael B.; Alvarado, Edwin; Badaj, Anna C. Organometallics, Vol. 32, Issue 11 https://doi.org/10.1021/om400220v	journal	March 2013
Organocatalytic cascade reactions as a new tool in total synthesis Grondal, Christoph; Jeanty, Matthieu; Enders, Dieter Nature Chemistry, Vol. 2, Issue 3 https://doi.org/10.1038/nchem.539	journal	February 2010
An amino-modified Zr-terephthalate metal–organic framework as an acid–base catalyst for cross-aldol condensation Vermoortele, Frederik; Ameloot, Rob; Vimont, Alexandre Chem. Commun., Vol. 47, Issue 5 https://doi.org/10.1039/C0CC03038D	journal	January 2011
Discovery, development, and functionalization of Zr( iv )-based metal–organic frameworks Kim, Min; Cohen, Seth M. CrystEngComm, Vol. 14, Issue 12 https://doi.org/10.1039/C2CE06491J	journal	January 2012
Green oxidation with aqueous hydrogen peroxide Noyori, Ryoji; Aoki, Masao; Sato, Kazuhiko Chemical Communications, Issue 16 https://doi.org/10.1039/b303160h	journal	January 2003
Catalytically active palladium pyridylidene complexes: pyridinium ionic liquids as N-heterocyclic carbene precursors Albrecht, Martin; Stoeckli-Evans, Helen Chemical Communications, Issue 37 https://doi.org/10.1039/b508225k	journal	January 2005
Selective oxidation of methanol to dimethoxymethane under mild conditions over V2O5/TiO2 with enhanced surface acidity Fu, Yuchuan; Shen, Jianyi Chemical Communications, Issue 21 https://doi.org/10.1039/b618898b	journal	January 2007
Multifunctional catalysis by Pd@MIL-101: one-step synthesis of methyl isobutyl ketone over palladium nanoparticles deposited on a metal–organic framework Pan, Yingyi; Yuan, Bizhen; Li, Yingwei Chemical Communications, Vol. 46, Issue 13 https://doi.org/10.1039/b922061e	journal	January 2010
Selective oxidation of methanol to dimethoxymethane over bifunctional VOx/TS-1 catalysts Chen, Shuang; Wang, Shengping; Ma, Xinbin Chemical Communications, Vol. 47, Issue 33 https://doi.org/10.1039/c1cc12391b	journal	January 2011
ZIF-8 immobilized nickel nanoparticles: highly effective catalysts for hydrogen generation from hydrolysis of ammonia borane Li, Pei-Zhou; Aranishi, Kengo; Xu, Qiang Chemical Communications, Vol. 48, Issue 26 https://doi.org/10.1039/c2cc17302f	journal	January 2012
Significant promoting effects of Lewis acidity on Au–Pd systems in the selective oxidation of aromatic hydrocarbons Liu, Hongli; Li, Yingwei; Jiang, Huanfeng Chemical Communications, Vol. 48, Issue 67 https://doi.org/10.1039/c2cc32024j	journal	January 2012
Catalysis by metal nanoparticles embedded on metal–organic frameworks Dhakshinamoorthy, Amarajothi; Garcia, Hermenegildo Chemical Society Reviews, Vol. 41, Issue 15 https://doi.org/10.1039/c2cs35047e	journal	January 2012
MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst Cirujano, F. G.; Llabrés i. Xamena, F. X.; Corma, A. Dalton Transactions, Vol. 41, Issue 14 https://doi.org/10.1039/c2dt12480g	journal	January 2012
Catalytic chromium reduction using formic acid and metal nanoparticles immobilized in a metal–organic framework Yadav, Mahendra; Xu, Qiang Chemical Communications, Vol. 49, Issue 32 https://doi.org/10.1039/c3cc00293d	journal	January 2013
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals Dhakshinamoorthy, Amarajothi; Opanasenko, Maksym; Čejka, Jiří Catalysis Science & Technology, Vol. 3, Issue 10 https://doi.org/10.1039/c3cy00350g	journal	January 2013
Oriented synthesis of target products in liquid-phase tandem reaction over a tripartite zeolite capsule catalyst Yang, Guohui; Kawata, Hajime; Lin, Qihang Chemical Science, Vol. 4, Issue 10 https://doi.org/10.1039/c3sc51499d	journal	January 2013
EXAFS study of the influence of hydrogen desorption and oxygen adsorption on the structural properties of small iridium particles supported on Al2O3 Kampers, F. W. H.; Koningsberger, D. C. Faraday Discussions of the Chemical Society, Vol. 89 https://doi.org/10.1039/dc9908900137	journal	January 1990
The oxidation of ethanol by hydrogen peroxide. Part I. Catalysis by ferric ion Heitler, C.; Scaife, D. B.; Thompson, B. W. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/j19670001409	journal	January 1967
Multiple-scattering calculations of x-ray-absorption spectra Zabinsky, S. I.; Rehr, J. J.; Ankudinov, A. Physical Review B, Vol. 52, Issue 4 https://doi.org/10.1103/PhysRevB.52.2995	journal	July 1995
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/S0909049500016964	journal	March 2001
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
ATHENA and ARTEMIS Interactive Graphical Data Analysisusing IFEFFIT Ravel, B.; Newville, M. Physica Scripta https://doi.org/10.1238/Physica.Topical.115a01007	journal	January 2005
Selective Formation of Acetal by Photooxidation of Ethanol over Silica-supported Niobium Oxide Catalysts Tanaka, Tsunehiro; Takenaka, Sakae; Funabiki, Takuzo Chemistry Letters, Vol. 23, Issue 4 https://doi.org/10.1246/cl.1994.809	journal	April 1994

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Synthesis of imidazo[1,5-a]pyridines via oxidative amination of the C(sp ³ )–H bond under air using metal–organic framework Cu-MOF-74 as an efficient heterogeneous catalyst Nguyen, Hanh T. H.; Nguyen, Oanh T. K.; Truong, Thanh RSC Advances, Vol. 6, Issue 42 https://doi.org/10.1039/c6ra00852f	journal	January 2016
Morphology inherence from hollow MOFs to hollow carbon polyhedrons in preparing carbon-based electrocatalysts Pei, Yuchen; Qi, Zhiyuan; Li, Xinle Journal of Materials Chemistry A, Vol. 5, Issue 13 https://doi.org/10.1039/c6ta10609a	journal	January 2017
Low-cost CuNi@MIL-101 as an excellent catalyst toward cascade reaction: integration of ammonia borane dehydrogenation with nitroarene hydrogenation Zhou, Ying-Hua; Yang, Qihao; Chen, Yu-Zhen Chemical Communications, Vol. 53, Issue 91 https://doi.org/10.1039/c7cc06530b	journal	January 2017
Insight into the epitaxial encapsulation of Pd catalysts in an oriented metalloporphyrin network thin film for tandem catalysis Vohra, M. Ismail; Li, De-Jing; Gu, Zhi-Gang Nanoscale, Vol. 9, Issue 23 https://doi.org/10.1039/c7nr02284k	journal	January 2017
Catalysis and photocatalysis by metal organic frameworks Dhakshinamoorthy, Amarajothi; Li, Zhaohui; Garcia, Hermenegildo Chemical Society Reviews, Vol. 47, Issue 22 https://doi.org/10.1039/c8cs00256h	journal	January 2018
A ppm level Rh-based composite as an ecofriendly catalyst for transfer hydrogenation of nitriles: triple guarantee of selectivity for primary amines Liu, Lei; Li, Jifan; Ai, Yongjian Green Chemistry, Vol. 21, Issue 6 https://doi.org/10.1039/c8gc03595d	journal	January 2019
Palladium NPs supported on sulfonic acid functionalized metal–organic frameworks as catalysts for biomass cascade reactions Zhang, Xibo; Chen, Luning; Li, Yongjian Dalton Transactions, Vol. 48, Issue 17 https://doi.org/10.1039/c9dt00348g	journal	January 2019
Exploitation of missing linker in Zr-based metal-organic framework as the catalyst support for selective oxidation of benzyl alcohol Jumpathong, Watthanachai; Pila, Taweesak; Lekjing, Yuwanda APL Materials, Vol. 7, Issue 11 https://doi.org/10.1063/1.5126077	journal	November 2019
Immobilized Pd-Ag bimetallic nanoparticles on polymeric nanofibers as an effective catalyst: effective loading of Ag with bimetallic functionality through Pd nucleated nanofibers Ranjith, Kugalur Shanmugam; Celebioglu, Asli; Uyar, Tamer Nanotechnology, Vol. 29, Issue 24 https://doi.org/10.1088/1361-6528/aab9da	journal	April 2018
Encapsulation of Metal Nanoparticles within Metal–Organic Frameworks for the Reduction of Nitro Compounds Navalón, Sergio; Álvaro, Mercedes; Dhakshinamoorthy, Amarajothi Molecules, Vol. 24, Issue 17 https://doi.org/10.3390/molecules24173050	journal	August 2019

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77 NANOSCIENCE AND NANOTECHNOLOGY
UiO-66
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heterogeneous catalysis
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Tandem catalysis by palladium nanoclusters encapsulated in metal–organic frameworks

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