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Bis‐Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal–Organic Trigonal Antiprism

Journal Article · · Chemistry - A European Journal
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  1. Institute of Chemical Sciences Heriot–Watt University Riccarton Edinburgh EH14 4AS UK
  2. EaStCHEM School of Chemistry The University of Edinburgh David Brewster Road Edinburgh EH9 3FJ UK
  3. Department of Chemistry University of Liverpool Crown Street Liverpool L69 7ZD UK
  4. Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 947240 USA
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Abstract

Calix[4]arenes (C[4]s) are versatile platforms for the construction of polymetallic clusters containing paramagnetic metal ions. Synthetic modification at the C[4] methylene bridge allows for the design of bis‐C[4]s that, depending on the linker employed, can be used to either dictate which clusters can be formed or direct the assembly of a new metal–organic polyhedron (MOP). The assembly resulting from the latter approach displays thermal stability and uptake of N 2 or H 2 gas, confirming that this is a viable route to the synthesis of new, functional supramolecular architectures.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1400973
Journal Information:
Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 26 Vol. 22; ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

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