Bis‐Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal–Organic Trigonal Antiprism
Journal Article
·
· Chemistry - A European Journal
- Institute of Chemical Sciences Heriot–Watt University Riccarton Edinburgh EH14 4AS UK
- EaStCHEM School of Chemistry The University of Edinburgh David Brewster Road Edinburgh EH9 3FJ UK
- Department of Chemistry University of Liverpool Crown Street Liverpool L69 7ZD UK
- Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 947240 USA
Abstract Calix[4]arenes (C[4]s) are versatile platforms for the construction of polymetallic clusters containing paramagnetic metal ions. Synthetic modification at the C[4] methylene bridge allows for the design of bis‐C[4]s that, depending on the linker employed, can be used to either dictate which clusters can be formed or direct the assembly of a new metal–organic polyhedron (MOP). The assembly resulting from the latter approach displays thermal stability and uptake of N 2 or H 2 gas, confirming that this is a viable route to the synthesis of new, functional supramolecular architectures.
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- AC02-05CH11231
- OSTI ID:
- 1400973
- Journal Information:
- Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Vol. 22 Journal Issue: 26; ISSN 0947-6539
- Publisher:
- Wiley Blackwell (John Wiley & Sons)Copyright Statement
- Country of Publication:
- Germany
- Language:
- English
Cited by: 8 works
Citation information provided by
Web of Science
Web of Science
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