A New Family of 3 d –4 f Bis‐Calix[4]arene‐Supported Clusters

Coletta, Marco; McLellan, Ross; Sanz, Sergio; Gagnon, Kevin J.; Teat, Simon J.; Brechin, Euan K.; Dalgarno, Scott J.

doi:10.1002/chem.201703197

A New Family of 3 d –4 f Bis‐Calix[4]arene‐Supported Clusters

Journal Article · Thu Sep 07 00:00:00 EDT 2017 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201703197· OSTI ID:1379992

Coletta, Marco ^[1]; McLellan, Ross ^[1]; Sanz, Sergio ^[2]; Gagnon, Kevin J. ^[3]; Teat, Simon J. ^[3]; ^[2]; ^[1]

Institute of Chemical Sciences Heriot-Watt University, Riccarton Edinburgh EH14 4AS UK
EaStCHEM School of Chemistry The University of Edinburgh David Brewster Road Edinburgh EH9 3FJ UK
Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 947240 USA

Abstract

Calix[4]arenes are versatile ligands that, whilst also serving other purposes, can act as platforms for the synthesis of a wide range of 3 d , 4 f , and 3 d –4 f polymetallic clusters. The empirical metal ion binding rules established for calix[4]arene are closely mirrored by bis‐calix[4]arene, a relatively new ligand in which two equivalents of the former are directly tethered at a methylene bridge position. The direct tethering within bis‐calix[4]arene gives rise to some structural features that are related to calix[4]arene coordination chemistry, but the prevailing clusters have fascinating new topologies and coordination behaviors. Here, we present the synthesis of a family of new bis‐calix[4]arene‐supported 3 d –4 f clusters, as well as their structural characterization and magnetic properties. Comparison is drawn with calix[4]arene coordination chemistry, showing logical extension of common structural fragments and cluster capping behaviors upon moving to bis‐calix[4]arene. This approach therefore holds great potential for tuning cluster formation and composition at a high level through subsequent ligand alteration.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1379992

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 56 Vol. 23; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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