Exploratory studies into 3 d /4 f cluster formation with fully bridge-substituted calix[4]arenes

Fong, Angela; McCormick, Laura; Teat, Simon J.; Brechin, Euan K.; Dalgarno, Scott J.

doi:10.1080/10610278.2018.1430894

Title: Exploratory studies into 3 d /4 f cluster formation with fully bridge-substituted calix[4]arenes

Journal Article · Thu Feb 01 00:00:00 EST 2018 · Supramolecular Chemistry

DOI:https://doi.org/10.1080/10610278.2018.1430894· OSTI ID:1571103

Fong, Angela ^[1]; McCormick, Laura ^[2]; Teat, Simon J. ^[2]; Brechin, Euan K. ^[3]; Dalgarno, Scott J. ^[1]

Heriot-Watt Univ., Edinburgh (United Kingdom). Inst. of Chemical Sciences
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of Edinburgh, (United Kingdom). EaStCHEM School of Chemistry

Calix[4]arenes are extremely versatile ligands that are capable of supporting the formation of a wide variety of polymetallic clusters of paramagnetic metal ions. One can exert influence over cluster formation through alteration of the calix[4]arene framework and subsequent ‘expansion’ of the lower-rim polyphenolic binding site. The present contribution investigates cluster formation with calix[4]arenes substituted at all four methylene bridge positions with furan moieties. Finally, two known cluster types have been isolated with this ligand, the structures of which lend insight into factors that may ultimately preclude the formation of mixed-metal species.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1571103

Journal Information:: Supramolecular Chemistry, Vol. 30, Issue 5-6; ISSN 1061-0278

Publisher:: Taylor & FrancisCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

References (20)

The Use of Calixarenes in Metal-Based Catalysis Homden, Damien M.; Redshaw, Carl Chemical Reviews, Vol. 108, Issue 12 https://doi.org/10.1021/cr8002196	journal	December 2008
Quantum Phase Interference and Parity Effects in Magnetic Molecular Clusters Wernsdorfer, W. Science, Vol. 284, Issue 5411 https://doi.org/10.1126/science.284.5411.133	journal	April 1999
Calix[4]arene-Based Single-Molecule Magnets Karotsis, Georgios; Teat, Simon J.; Wernsdorfer, Wolfgang Angewandte Chemie International Edition, Vol. 48, Issue 44 https://doi.org/10.1002/anie.200904094	journal	September 2009
Calix[4]arene-supported rare earth octahedra Sanz, Sergio; McIntosh, Ruaraidh D.; Beavers, Christine M. Chem. Commun., Vol. 48, Issue 10 https://doi.org/10.1039/C1CC14603C	journal	January 2012
Investigations into cluster formation with alkyl-tethered bis-calix[4]arenes Coletta, Marco; McLellan, Ross; Cols, Jean-Marie Supramolecular Chemistry, Vol. 28, Issue 5-6 https://doi.org/10.1080/10610278.2015.1136412	journal	December 2015
Calixarene-supported hexadysprosium cluster showing single molecule magnet behavior Bi, YanFeng; Xu, GuanCheng; Liao, WuPing Science China Chemistry, Vol. 55, Issue 6 https://doi.org/10.1007/s11426-012-4570-5	journal	April 2012
Calix[4]arene Derivatives Monosubstituted at All Four Methylene Bridges Columbus, Ishay The Journal of Organic Chemistry, Vol. 73, Issue 7 https://doi.org/10.1021/jo702474n	journal	April 2008
Metallocalixarene catalysts: α-olefin polymerization and ROP of cyclic esters Redshaw, Carl Dalton Transactions, Vol. 45, Issue 22 https://doi.org/10.1039/C6DT01529H	journal	January 2016
A Mixed-Valence Polyoxovanadate(III,IV) Cluster with a Calixarene Cap Exhibiting Ferromagnetic V(III)−V(IV) Interactions Aronica, Christophe; Chastanet, Guillaume; Zueva, Ekaterina Journal of the American Chemical Society, Vol. 130, Issue 7 https://doi.org/10.1021/ja078030q	journal	February 2008
Thiacalixarene-based nanoscale polyhedral coordination cages Bi, Yanfeng; Du, Shangchao; Liao, Wuping Coordination Chemistry Reviews, Vol. 276 https://doi.org/10.1016/j.ccr.2014.06.011	journal	September 2014
Calixarene supported enneanuclear Cu(ii) clusters Karotsis, Georgios; Kennedy, Stuart; Dalgarno, Scott J. Chemical Communications, Vol. 46, Issue 22 https://doi.org/10.1039/c0cc00011f	journal	January 2010
Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper( ii ) clusters Fairbairn, Robyn E.; McLellan, Ross; McIntosh, Ruaraidh D. Dalton Trans., Vol. 43, Issue 14 https://doi.org/10.1039/C3DT53088D	journal	January 2014
New mixed-valence Mn ^II ₂ Mn ^III ₂ clusters exhibiting an unprecedented Mn ^II/III oxidation state distribution in their magnetically coupled cores Wittick, Lisa M.; Jones, Leigh F.; Jensen, Paul Dalton Trans., Issue 12 https://doi.org/10.1039/B511817D	journal	January 2006
Thiacalixarenes as cluster keepers: synthesis and structural analysis of a magnetically coupled tetracopper(II) square Mislin, Gilles; Graf, Ernest; Hosseini, Mir Wais Chemical Communications, Issue 4 https://doi.org/10.1039/a809184f	journal	January 1999
Single-Molecule Magnets: A New Class of Tetranuclear Manganese Magnets Yoo, Jae; Brechin, Euan K.; Yamaguchi, Akira Inorganic Chemistry, Vol. 39, Issue 16 https://doi.org/10.1021/ic000237w	journal	August 2000
Electrically driven nuclear spin resonance in single-molecule magnets Thiele, S.; Balestro, F.; Ballou, R. Science, Vol. 344, Issue 6188 https://doi.org/10.1126/science.1249802	journal	June 2014
Calix[4]arene-supported FeIII2LnIII2 clusters Sanz, Sergio; Ferreira, Kerry; McIntosh, Ruaraidh D. Chemical Communications, Vol. 47, Issue 32 https://doi.org/10.1039/c1cc13055b	journal	January 2011
Lanthanide ion complexes of the calixarenes. Part 4. Double inclusion by p-t-butylcalix[4]arene (H4L). Crystal structures of [Eu2(HL)2(dmf)4].7dmf (dmf = dimethylformamide) and H4L.dmso (dmso = dimethyl sulphoxide) Furphy, Brenda M.; Harrowfield, Jack MacB.; Ogden, Mark I. Journal of the Chemical Society, Dalton Transactions, Issue 11 https://doi.org/10.1039/dt9890002217	journal	January 1989
A new class of single-molecule magnets: mixed-valent [Mn4(O2CMe)2(Hpdm)6][ClO4]2 with an S = 8 ground state Brechin, Euan K.; Huffman, John C.; Christou, George Chemical Communications, Issue 9 https://doi.org/10.1039/a901106d	journal	January 1999
Calix[4]arene-Based Single-Molecule Magnets Karotsis, Georgios; Teat, Simon J.; Wernsdorfer, Wolfgang Angewandte Chemie, Vol. 121, Issue 44 https://doi.org/10.1002/ange.200904094	journal	September 2009

Cited By (2)

Enantiomerization Barrier of all-cis C-Me-tetrahydroxy p-tert -butylcalix[4]arene and Atropisomeric Equilibrium of its Tetraacetoxy Derivatives: Enantiomerization Barrier of all-cis C-Me-tetrahydroxy p-tert -butylcalix[4]arene and Atropisomeric Equilibrium of its Tetraacetoxy Derivatives Israeli, Galon; Shalev, Ori; Biali, Silvio E. European Journal of Organic Chemistry, Vol. 2020, Issue 13 https://doi.org/10.1002/ejoc.202000212	journal	March 2020
Optical and Vapor Sensing Properties of Calix[4]arene Langmuir-Blodgett Thin Films with Host–Guest Principles Acikbas, Yaser; Bozkurt, Selahattin; Erdogan, Matem Journal of Macromolecular Science, Part A, Vol. 55, Issue 7 https://doi.org/10.1080/10601325.2018.1476824	journal	June 2018

Linked Research (5)

Similar Records

The remarkable influence of N, O-ligands in the assembly of a bis-calix[4]arene-supported [Mn^IV₂Mn^III₁₀Mn^II₈] cluster

Journal Article · Fri Nov 24 00:00:00 EST 2017 · Dalton Transactions · OSTI ID:1571103

Coletta, Marco; Sanz, Sergio; McCormick, Laura J.; +3 more

Calix[4]arene Based Single-Molecule Magnets

Journal Article · Thu Jun 04 00:00:00 EDT 2009 · Angewandte Chemie · OSTI ID:1571103

Karotsis, Georgios; Teat, Simon J; Wernsdorfer, Wolfgang; +3 more

A New Family of 3 d –4 f Bis‐Calix[4]arene‐Supported Clusters

Journal Article · Thu Sep 07 00:00:00 EDT 2017 · Chemistry - A European Journal · OSTI ID:1571103

Coletta, Marco; McLellan, Ross; Sanz, Sergio; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Calixarenes
coordination chemistry
clusters
synthesis
crystallography

CCDC 1583896: Experimental Crystal Structure Determination Fong, Angela; McCormick, Laura; Teat, Simon J. https://doi.org/10.5517/ccdc.csd.cc1q55fh The current record is supplemented by this dataset	dataset	January 2018
CCDC 1583897: Experimental Crystal Structure Determination Fong, Angela; McCormick, Laura; Teat, Simon J. https://doi.org/10.5517/ccdc.csd.cc1q55gj The current record is supplemented by this dataset	dataset	January 2018
CCDC 1583898: Experimental Crystal Structure Determination Fong, Angela; McCormick, Laura; Teat, Simon J. https://doi.org/10.5517/ccdc.csd.cc1q55hk The current record is supplemented by this dataset	dataset	January 2018
Exploratory studies into 3d/4f cluster formation with fully bridge-substituted calix[4]arenes^* Fong, Angela; McCormick, Laura; Teat, Simon J. https://doi.org/10.6084/m9.figshare.5845062 The current record is supplemented by this text	text	January 2018
Exploratory studies into 3d/4f cluster formation with fully bridge-substituted calix[4]arenes^* Fong, Angela; McCormick, Laura; Teat, Simon J. https://doi.org/10.6084/m9.figshare.5845062.v1 The current record is supplemented by this text	text	January 2018