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Title: A magnesium–sodium hybrid battery with high operating voltage

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c6cc03081e· OSTI ID:1346732
 [1];  [1];  [1];  [2];  [3];  [3];  [4];  [1]
  1. Univ. of Houston, Houston, TX (United States)
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Sharp Lab. of America, Camas, WA (United States)
+ Show Author Affiliations

Here, we report a high performance magnesium-sodium hybrid battery utilizing a magnesium-sodium dual-salt electrolyte, a magnesium anode, and a Berlin green cathode. The cell delivers an average discharge voltage of 2.2 V and a reversible capacity of 143 mA h g–1. We also demonstrate the cell with an energy density of 135 W h kg–1 and a high power density of up to 1.67 kW kg–1.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF); USDOE Office of Science (SC)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1346732
Journal Information:
ChemComm, Vol. 52, Issue 53; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 43 works
Citation information provided by
Web of Science

References (23)

Copper hexacyanoferrate battery electrodes with long cycle life and high power journal November 2011
Prussian blue: a new framework of electrode materials for sodium batteries journal January 2012
Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries journal October 2014
Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries journal January 2013
Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries journal February 2015
Microscopic properties of lithium, sodium, and magnesium battery anode materials related to possible dendrite growth journal November 2014
New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon journal August 2015
The Mechanisms of Lithium and Sodium Insertion in Carbon Materials journal January 2001
Prototype systems for rechargeable magnesium batteries journal October 2000
Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage journal February 2015
Improved Electrolyte Solutions for Rechargeable Magnesium Batteries journal January 2006
A concept of dual-salt polyvalent-metal storage battery journal January 2014
High performance batteries based on hybrid magnesium and lithium chemistry journal January 2014
Efficient and Inexpensive Sodium–Magnesium Hybrid Battery journal October 2015
Elucidating the structure of the magnesium aluminum chloride complex electrolyte for magnesium-ion batteries journal January 2015
Electrochemically stable cathode current collectors for rechargeable magnesium batteries journal January 2014
A high performance hybrid battery based on aluminum anode and LiFePO 4 cathode journal January 2016
An Efficient Halogen-Free Electrolyte for Use in Rechargeable Magnesium Batteries journal May 2015
Combining In Situ Synchrotron X-Ray Diffraction and Absorption Techniques with Transmission Electron Microscopy to Study the Origin of Thermal Instability in Overcharged Cathode Materials for Lithium-Ion Batteries journal June 2012
A Superior Low-Cost Cathode for a Na-Ion Battery journal January 2013
High energy density hybrid Mg 2+ /Li + battery with superior ultra-low temperature performance journal January 2016
High Areal Capacity Hybrid Magnesium–Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large-Scale Energy Storage journal March 2015
Dual-Salt Mg-Based Batteries with Conversion Cathodes journal November 2015

Cited By (9)

High Rate Magnesium-Sulfur Battery with Improved Cyclability Based on Metal-Organic Framework Derivative Carbon Host journal January 2018
KTi 2 (PO 4 ) 3 with Large Ion Diffusion Channel for High-Efficiency Sodium Storage journal May 2017
Mg Cathode Materials and Electrolytes for Rechargeable Mg Batteries: A Review journal January 2019
Four decades of electrochemical investigation of Prussian blue journal November 2019
A critical review of cathodes for rechargeable Mg batteries journal January 2018
Exploring the Synergy of LiBH 4 /NaBH 4 Additives with Mg(BH 4 ) 2 Electrolyte Using Density Functional Theory journal January 2018
Communication—Mg(TFSI) 2 -Based Hybrid Magnesium-Sodium Electrolyte: Case Study with NaTi 2 (PO 4 ) 3 //Mg Cell journal January 2018
Rechargeable Mg–Li hybrid batteries: status and challenges journal September 2016
Magnesium-Sodium Hybrid Battery With High Voltage, Capacity and Cyclability journal December 2018

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