Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes

Shin, Kang Ho; Park, Sul Ki; Nakhanivej, Puritut; Wang, Yixian; Liu, Pengcheng; Bak, Seong-Min; Choi, Min Sung; Mitlin, David; Park, Ho Seok

doi:10.1063/5.0020805

Title: Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes

Journal Article · Tue Dec 08 00:00:00 EST 2020 · Applied Physics Reviews

DOI:https://doi.org/10.1063/5.0020805· OSTI ID:1749906

^[1]; Park, Sul Ki ^[1];

^[1];

^[2]; Liu, Pengcheng ^[2];

^[3]; Choi, Min Sung ^[1]; Mitlin, David ^[2];

^[1]

Sungkyunkwan Univ., Suwon (Republic of Korea)
Univ. of Texas, Austin, TX (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

A biomimetic bone-inspired Na3V2(PO4)3-reduced graphene oxide (rGO) composite cathode "BI-NVP" achieves ultrahigh rate charging and ultralong cycling life in a sodium ion battery (SIB). At a charging rate of 1C, BI-NVP delivers 97% of its theoretical capacity (114 mA h g^-1 vs. 117 mA h g^-1), while at 100C and 200C, the capacities are 68 and 49 mA h g^-1, respectively. It also shows long cycling life with capacity retention of 90.5% after 10000 cycles at 50C. SIB cells with a BI-NVP cathode and Na metal anode delivered maximum specific energy of 350 W h kg^-1 and maximum specific power of 154 kW kg^-1. The Ragone chart shows a uniquely flat specific energy profile to above 10 kW kg^-1, yielding the most favorable high power characteristics reported for SIBs. Electroanalytical results indicate that the Na ion diffusivity of BI-NVP is 3.90 × 10^-10 cm² s^-1, as compared to the 1.17 × 10^-11 cm² s^-1 for the NVP baseline. The enhanced diffusivity in BI-NVP helps to explain its extremely fast redox kinetics, in turn being attributable to a combination of the ion-active rGO shell, the nanosizing of the NVP, and the interpenetrating mesoporosity. In-situ and post-mortem analyses of cycled BI-NVP, including by Raman and XRD spectra, HRTEM and STEM-EELS, indicate highly reversible dilation contraction, negligible electrode pulverization, and a stable NVP-rGO layer interface.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Research Foundation of Korea (NRF); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; NRF-2020R1A3B2079803; 1938833

OSTI ID:: 1749906

Alternate ID(s):: OSTI ID: 1734801

Report Number(s):: BNL-220740-2020-JAAM; TRN: US2205518

Journal Information:: Applied Physics Reviews, Vol. 7, Issue 4; ISSN 1931-9401

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Ultrafast Cathode Characteristics of Nanocrystalline-Li ₃ V ₂ (PO ₄ ) ₃ /Carbon Nanofiber Composites Naoi, Katsuhiko; Kisu, Kazuaki; Iwama, Etsuro Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.0021506jes	journal	January 2015
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Stability enhancing ionic liquid hybrid electrolyte for NVP@C cathode based sodium batteries Manohar, C. V.; Raj K., Anish; Kar, Mega Sustainable Energy & Fuels, Vol. 2, Issue 3 https://doi.org/10.1039/C7SE00537G	journal	January 2018
Template-Free Synthesis of VO ₂ Hollow Microspheres with Various Interiors and Their Conversion into V ₂ O ₅ for Lithium-Ion Batteries Pan, Anqiang; Wu, Hao Bin; Yu, Le Angewandte Chemie, Vol. 125, Issue 8 https://doi.org/10.1002/ange.201209535	journal	January 2013

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