A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V

Li, Yunchao; Wan, Shun; Veith, Gabriel M.; Unocic, Raymond R.; Paranthaman, Mariappan Parans; Dai, Sheng; Sun, Xiao -Guang

doi:10.1002/aenm.201601397

A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V

Journal Article · Mon Nov 07 04:00:00 EST 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201601397· OSTI ID:1344993

Li, Yunchao ^[1]; Wan, Shun ^[2]; Veith, Gabriel M. ^[2]; Unocic, Raymond R. ^[2]; Paranthaman, Mariappan Parans ^[1]; Dai, Sheng ^[1]; Sun, Xiao -Guang ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); The Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Here, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), as an additive in conventional electrolyte for LiNi_0.5Mn_1.5O₄, exhibits improved coulombic efficiencies and cycling stability. Cyclic voltammograms indicate the cells with additive form good SEIs during the first cycle whereas no additive cell needs more cycles to form a functional SEI. XPS reveals LiBMFMB could reduce the decomposition of LiPF₆ salt and solvents, resulting in thinner SEI.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1344993

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 4 Vol. 7; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

25 ENERGY STORAGE
electrolyte additives
high voltage batteries
lithium bis(2-methyl-2-fluoromalonato) borate (LiBMFMB)
solid electrolyte interfaces (SEI)
spinel LiNi1.5Mn0.5O4 (LNMO)

A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V

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