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Title: A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V

Abstract

Here, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), as an additive in conventional electrolyte for LiNi 0.5Mn 1.5O 4, exhibits improved coulombic efficiencies and cycling stability. Cyclic voltammograms indicate the cells with additive form good SEIs during the first cycle whereas no additive cell needs more cycles to form a functional SEI. XPS reveals LiBMFMB could reduce the decomposition of LiPF 6 salt and solvents, resulting in thinner SEI.

Authors:
 [1];  [2];  [2];  [2];  [1];  [1];  [2]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); The Univ. of Tennessee, Knoxville, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1344993
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 7; Journal Issue: 4; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; solid electrolyte interfaces (SEI); lithium bis(2-methyl-2-fluoromalonato) borate (LiBMFMB); electrolyte additives; spinel LiNi1.5Mn0.5O4 (LNMO); high voltage batteries

Citation Formats

Li, Yunchao, Wan, Shun, Veith, Gabriel M., Unocic, Raymond R., Paranthaman, Mariappan Parans, Dai, Sheng, and Sun, Xiao -Guang. A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V. United States: N. p., 2016. Web. doi:10.1002/aenm.201601397.
Li, Yunchao, Wan, Shun, Veith, Gabriel M., Unocic, Raymond R., Paranthaman, Mariappan Parans, Dai, Sheng, & Sun, Xiao -Guang. A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V. United States. doi:10.1002/aenm.201601397.
Li, Yunchao, Wan, Shun, Veith, Gabriel M., Unocic, Raymond R., Paranthaman, Mariappan Parans, Dai, Sheng, and Sun, Xiao -Guang. Mon . "A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V". United States. doi:10.1002/aenm.201601397. https://www.osti.gov/servlets/purl/1344993.
@article{osti_1344993,
title = {A novel electrolyte salt additive for lithium-ion batteries with voltages greater than 4.7 V},
author = {Li, Yunchao and Wan, Shun and Veith, Gabriel M. and Unocic, Raymond R. and Paranthaman, Mariappan Parans and Dai, Sheng and Sun, Xiao -Guang},
abstractNote = {Here, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), as an additive in conventional electrolyte for LiNi0.5Mn1.5O4, exhibits improved coulombic efficiencies and cycling stability. Cyclic voltammograms indicate the cells with additive form good SEIs during the first cycle whereas no additive cell needs more cycles to form a functional SEI. XPS reveals LiBMFMB could reduce the decomposition of LiPF6 salt and solvents, resulting in thinner SEI.},
doi = {10.1002/aenm.201601397},
journal = {Advanced Energy Materials},
issn = {1614-6832},
number = 4,
volume = 7,
place = {United States},
year = {2016},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 5 works
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Works referenced in this record:

Surface chemistry of metal oxide coated lithium manganese nickel oxide thin film cathodes studied by XPS
journal, February 2013


Generation of Cathode Passivation Films via Oxidation of Lithium Bis(oxalato) Borate on High Voltage Spinel (LiNi 0.5 Mn 1.5 O 4 )
journal, March 2014

  • Xu, Mengqing; Tsiouvaras, Nikolaos; Garsuch, Arnd
  • The Journal of Physical Chemistry C, Vol. 118, Issue 14
  • DOI: 10.1021/jp501970j

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

A review on electrolyte additives for lithium-ion batteries
journal, November 2006


Synthesis and Characterization of Lithium Bis(fluoromalonato)borate for Lithium-Ion Battery Applications
journal, November 2013

  • Liao, Chen; Han, Kee Sung; Baggetto, Loïc
  • Advanced Energy Materials, Vol. 4, Issue 6
  • DOI: 10.1002/aenm.201301368

Kinetics Study of the 5 V Spinel Cathode LiMn1.5Ni0.5O4 Before and After Surface Modifications
journal, January 2009

  • Liu, J.; Manthiram, A.
  • Journal of The Electrochemical Society, Vol. 156, Issue 11, p. A833-A838
  • DOI: 10.1149/1.3206590

Electrolyte additives for lithium ion battery electrodes: progress and perspectives
journal, January 2016

  • Haregewoin, Atetegeb Meazah; Wotango, Aselefech Sorsa; Hwang, Bing-Joe
  • Energy Environ. Sci., Vol. 9, Issue 6
  • DOI: 10.1039/C6EE00123H

Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
journal, January 2015

  • Choi, Nam-Soon; Han, Jung-Gu; Ha, Se-Young
  • RSC Advances, Vol. 5, Issue 4
  • DOI: 10.1039/C4RA11575A

Impact of Lithium Bis(oxalate)borate Electrolyte Additive on the Performance of High-Voltage Spinel/Graphite Li-Ion Batteries
journal, October 2013

  • Pieczonka, Nicholas P. W.; Yang, Li; Balogh, Michael P.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 44
  • DOI: 10.1021/jp408717x

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

Materials Challenges and Opportunities of Lithium Ion Batteries
journal, January 2011

  • Manthiram, Arumugam
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 3
  • DOI: 10.1021/jz1015422

Effect of Added LiBOB on High Voltage (LiNi0.5Mn1.5O4) Spinel Cathodes
journal, January 2011

  • Dalavi, S.; Xu, M.; Knight, B.
  • Electrochemical and Solid-State Letters, Vol. 15, Issue 2
  • DOI: 10.1149/2.015202esl

Research progress in high voltage spinel LiNi0.5Mn1.5O4 material
journal, September 2010


Electrolyte Additive in Support of 5 V Li Ion Chemistry
journal, January 2011

  • von Cresce, Arthur; Xu, Kang
  • Journal of The Electrochemical Society, Vol. 158, Issue 3, p. A337-A342
  • DOI: 10.1149/1.3532047

Recent progress in high-voltage lithium ion batteries
journal, September 2013


A multifunctional phosphite-containing electrolyte for 5 V-class LiNi 0.5 Mn 1.5 O 4 cathodes with superior electrochemical performance
journal, January 2014

  • Song, Young-Min; Han, Jung-Gu; Park, Soojin
  • J. Mater. Chem. A, Vol. 2, Issue 25
  • DOI: 10.1039/C4TA01129E

Challenges and Approaches for High-Voltage Spinel Lithium-Ion Batteries
journal, May 2014

  • Kim, Jung-Hyun; Pieczonka, Nicholas P. W.; Yang, Li
  • ChemPhysChem, Vol. 15, Issue 10
  • DOI: 10.1002/cphc.201400052

Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high energy density and long cycle life
journal, January 2013

  • Fang, Xin; Ge, Mingyuan; Rong, Jiepeng
  • Journal of Materials Chemistry A, Vol. 1, Issue 12
  • DOI: 10.1039/c3ta01534c

LiBOB as Additive in LiPF[sub 6]-Based Lithium Ion Electrolytes
journal, January 2005

  • Xu, Kang; Zhang, Shengshui; Jow, T. Richard
  • Electrochemical and Solid-State Letters, Vol. 8, Issue 7
  • DOI: 10.1149/1.1924930

Bis(fluoromalonato)borate (BFMB) anion based ionic liquid as an additive for lithium-ion battery electrolytes
journal, January 2014

  • Sun, Xiao-Guang; Liao, Chen; Baggetto, Loïc
  • J. Mater. Chem. A, Vol. 2, Issue 20
  • DOI: 10.1039/C3TA14943A

LiPF6/LiBOB blend salt electrolyte for high-power lithium-ion batteries
journal, April 2006


Understanding Transition-Metal Dissolution Behavior in LiNi 0.5 Mn 1.5 O 4 High-Voltage Spinel for Lithium Ion Batteries
journal, July 2013

  • Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng
  • The Journal of Physical Chemistry C, Vol. 117, Issue 31
  • DOI: 10.1021/jp405158m

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Spinel materials for high-voltage cathodes in Li-ion batteries
journal, January 2014


Development of novel lithium borate additives for designed surface modification of high voltage LiNi 0.5 Mn 1.5 O 4 cathodes
journal, January 2016

  • Xu, Mengqing; Zhou, Liu; Dong, Yingnan
  • Energy & Environmental Science, Vol. 9, Issue 4
  • DOI: 10.1039/C5EE03360H

Higher, Stronger, Better…︁ A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries
journal, June 2012


An Artificial Solid Electrolyte Interphase Enables the Use of a LiNi 0.5 Mn 1.5 O 4 5 V Cathode with Conventional Electrolytes
journal, August 2013

  • Li, Juchuan; Baggetto, Loïc; Martha, Surendra K.
  • Advanced Energy Materials, Vol. 3, Issue 10
  • DOI: 10.1002/aenm201300378