Multicolor Luminescence from Conjugates of Genetically Encoded Elastin-like Polymers and Terpyridine-Lanthanides

Ghosh, Koushik; Balog, Eva Rose M.; Kahn, Jennifer L.; Shepherd, Douglas P.; Martinez, Jennifer S.; Rocha, Reginaldo C.

doi:10.1002/macp.201500103

Multicolor Luminescence from Conjugates of Genetically Encoded Elastin-like Polymers and Terpyridine-Lanthanides

Journal Article · Thu Aug 20 00:00:00 EDT 2015 · Macromolecular Chemistry and Physics

DOI:https://doi.org/10.1002/macp.201500103· OSTI ID:1254844

Ghosh, Koushik ^[1]; Balog, Eva Rose M. ^[1]; Kahn, Jennifer L. ^[1]; Shepherd, Douglas P. ^[2]; Martinez, Jennifer S. ^[3]; Rocha, Reginaldo C. ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies (CINT)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Center for Nonlinear Studies (CNLS)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Institute for Materials Science

Functional hybrid materials with optically active metal-ligand moieties embedded within a polymer matrix have a great potential in (bio)materials science, including applications in light-emitting diode devices. Here, we report a simple strategy to incorporate terpyridine derivatives into the side chains of elastin-like polymers (ELPs). The further binding of trivalent lanthanide ions with the terpyridine ligands generated an array of photoluminescence ranging from the visible to the near-infrared regions. Lastly, as thin films, these ELP-based optical materials also exhibited distinct morphologies that depend upon the temperature of the aqueous solutions from which the hybrid polymers were spin coated or drop cast.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1254844

Report Number(s):: LA-UR--15-21799

Journal Information:: Macromolecular Chemistry and Physics, Journal Name: Macromolecular Chemistry and Physics Journal Issue: 18 Vol. 216; ISSN 1022-1352

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Selective Recognition of Fe(III) in Aqueous Environment over Covalently-Bonded Tb-Complex-Containing Fluorescent Porous Copolymer Microspheres Zhang, Chunyan; Luo, Jianxin; Li, Wenjun Macromolecular Chemistry and Physics, Vol. 219, Issue 24 https://doi.org/10.1002/macp.201800403	journal	November 2018
Luminescent lanthanide (Eu( iii )) cross-linked supramolecular metallo co-polymeric hydrogels: the effect of ligand symmetry Bradberry, Samuel J.; Dee, Garret; Kotova, Oxana Chemical Communications, Vol. 55, Issue 12 https://doi.org/10.1039/c8cc08888h	journal	January 2019
Recent advances in the development of luminescent lanthanide-based supramolecular polymers and soft materials Kotova, Oxana; Bradberry, Samuel J.; Savyasachi, Aramballi J. Dalton Transactions, Vol. 47, Issue 46 https://doi.org/10.1039/c8dt03768j	journal	January 2018

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
biomaterials
conjugation
elastin
genetically encoded polymers
lanthanides
luminescence
polypeptides
terpyridine

Multicolor Luminescence from Conjugates of Genetically Encoded Elastin-like Polymers and Terpyridine-Lanthanides

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References (19)

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