Solution-processable glass LiI-Li4SnS4 superionic conductors for all-solid-state Li-ion batteries

Oh, Dae Yang; Choi, Young Eun; Nam, Young Jin; Han, Lili; Kim, Ju -Young; Xin, Huolin; Lin, Feng; Oh, Seung M.; Jung, Yoon Seok

doi:10.1002/adma.201505008

Solution-processable glass LiI-Li₄SnS₄ superionic conductors for all-solid-state Li-ion batteries

Journal Article · Tue Dec 22 00:00:00 EST 2015 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201505008· OSTI ID:1235861

Oh, Dae Yang ^[1]; Choi, Young Eun ^[1]; Nam, Young Jin ^[1]; Han, Lili ^[2]; Kim, Ju -Young ^[1]; Xin, Huolin ^[2]; Lin, Feng ^[3]; Oh, Seung M. ^[4]; Jung, Yoon Seok ^[1]

Ulsan National Institute of Science and Technology (UNIST), Ulsan (South Korea)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Seoul National Univ., Seoul (South Korea)

The new, highly conductive (4.1 × 10^–4 S cm^–1 at 30 °C), highly deformable, and dry-air-stable glass 0.4LiI-0.6Li₄SnS₄ is prepared using a homogeneous methanol solution. Furthermore, the solution process enables the wetting of any exposed surface of the active materials with highly conductive solidified electrolytes (0.4LiI-0.6Li₄SnS₄), resulting in considerable improvements in electrochemical performances of these electrodes over conventional mixture electrodes.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1235861

Report Number(s):: BNL--111621-2015-JA

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 4 Vol. 8; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Slurry-Based Processing of Solid Electrolytes: A Comparative Binder Study Riphaus, Nathalie; Strobl, Philipp; Stiaszny, Barbara Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0961816jes	journal	January 2018
Synthesis and Electrochemical Characterization of a Glass-Ceramic Li ₇ P ₂ S ₈ I Solid Electrolyte for All-Solid-State Li-Ion Batteries Choi, Seon-Joo; Lee, Sang-Hun; Ha, Yoon-Cheol Journal of The Electrochemical Society, Vol. 165, Issue 5 https://doi.org/10.1149/2.0981805jes	journal	January 2018
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.1571707jes	journal	January 2017
Efficient cell design and fabrication of concentration‐gradient composite electrodes for high‐power and high‐energy‐density all‐solid‐state batteries Kim, Ju Young; Kim, Jumi; Kang, Seok Hun ETRI Journal, Vol. 42, Issue 1 https://doi.org/10.4218/etrij.2019-0176	journal	July 2019
Slurry-Based Processing of Solid Electrolytes: A Comparative Binder Study Riphaus, Nathalie; Strobl, Philipp; Stiaszny, Barbara Karlsruhe https://doi.org/10.5445/ir/1000089322	text	January 2018

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Related Subjects

36 MATERIALS SCIENCE
Center for Functional Nanomaterials
batteries
composites
electrodes
lithium ion battery
nanostructures
solid electrolytes
solid state electrolyte