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Frontiers of in situ electron microscopy

Journal Article · · MRS Bulletin
DOI:https://doi.org/10.1557/mrs.2014.305· OSTI ID:1193214
 [1];  [2];  [3]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Univ. of California-San Diego, San Diego, CA (United States)
In situ transmission electron microscopy (TEM) has become an increasingly important tool for materials characterization. It provides key information on the structural dynamics of a material during transformations and the correlation between structure and properties of materials. With the recent advances in instrumentation, including aberration corrected optics, sample environment control, the sample stage, and fast and sensitive data acquisition, in situ TEM characterization has become more and more powerful. In this article, a brief review of the current status and future opportunities of in situ TEM is included. It also provides an introduction to the six articles covered by in this issue of MRS Bulletin explore the frontiers of in situ electron microscopy, including liquid and gas environmental TEM, dynamic four-dimensional TEM, nanomechanics, ferroelectric domain switching studied by in situ TEM, and state-of-the-art atomic imaging of light elements (i.e., carbon atoms) and individual defects.
Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI ID:
1193214
Report Number(s):
BNL--108005-2015-JA; KC0201010
Journal Information:
MRS Bulletin, Journal Name: MRS Bulletin Journal Issue: 01 Vol. 40; ISSN 0883-7694
Publisher:
Materials Research SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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Control of Double-Vortex Domain Configurations in a Shape-Engineered Trilayer Nanomagnet System journal January 2010
Dynamic Visualization of the Electric Potential in an All-Solid-State Rechargeable Lithium Battery journal June 2010
Design and Applications of Environmental Cell Transmission Electron Microscope for In Situ Observations of Gas–Solid Reactions journal November 2001
In situ Lorentz TEM magnetization studies on a Fe–Pd–Co martensitic alloy journal October 2011
Imaging Protein Structure in Water at 2.7 nm Resolution by Transmission Electron Microscopy journal February 2012
Environmental electron microscopy (ETEM) for catalysts with a closed E-cell with carbon windows journal April 2006
In Situ Liquid Cell Transmission Electron Microscopic Observation of Electron Beam Induced Au Crystal Growth in a Solution journal July 2012
In Situ TEM Study of Catalytic Nanoparticle Reactions in Atmospheric Pressure Gas Environment journal September 2013
First Cross-Section Observation of an All Solid-State Lithium-Ion “Nanobattery” by Transmission Electron Microscopy journal March 2008
Liquid Cell Transmission Electron Microscopy Study of Platinum Iron Nanocrystal Growth and Shape Evolution journal March 2013
Direct Observations of Oxygen-induced Platinum Nanoparticle Ripening Studied by In Situ TEM journal June 2010
Interface Limited Lithium Transport in Solid-State Batteries journal December 2013
Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries journal December 2011
Mechanical Properties of Si Nanowires as Revealed by in Situ Transmission Electron Microscopy and Molecular Dynamics Simulations journal January 2012
In Situ Liquid Cell Electron Microscopy of the Solution Growth of Au–Pd Core–Shell Nanostructures journal May 2013
Demonstration of an Electrochemical Liquid Cell for Operando Transmission Electron Microscopy Observation of the Lithiation/Delithiation Behavior of Si Nanowire Battery Anodes journal November 2013
Visualization of Electrode–Electrolyte Interfaces in LiPF 6 /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM journal March 2014
Revealing the Atomic Restructuring of Pt–Co Nanoparticles journal May 2014
Nanocrystal Diffusion in a Liquid Thin Film Observed by in Situ Transmission Electron Microscopy journal June 2009
Direct Observation of Nanoparticle Superlattice Formation by Using Liquid Cell Transmission Electron Microscopy journal February 2012
Revealing Correlation of Valence State with Nanoporous Structure in Cobalt Catalyst Nanoparticles by In Situ Environmental TEM journal April 2012
In Situ Transmission Electron Microscopy of Lead Dendrites and Lead Ions in Aqueous Solution journal June 2012
Developments in in situ Environmental Cell High-Resolution Electron Microscopy and Applications to Catalysis journal January 2002
Atomic-scale imaging of individual dopant atoms and clusters in highly n-type bulk Si journal April 2002
Strong crystal size effect on deformation twinning journal January 2010
Real-space observation of a two-dimensional skyrmion crystal journal June 2010
Discrete plasticity in sub-10-nm-sized gold crystals journal December 2010
A new regime for mechanical annealing and strong sample-size strengthening in body centred cubic molybdenum journal September 2011
Skyrmion flow near room temperature in an ultralow current density journal January 2012
Direct dynamic imaging of non-adiabatic spin torque effects journal January 2012
Coherence and modality of driven interlayer-coupled magnetic vortices journal April 2014
HOP2-MND1 modulates RAD51 binding to nucleotides and DNA journal June 2014
Interface-induced nonswitchable domains in ferroelectric thin films journal August 2014
Mechanical annealing and source-limited deformation in submicrometre-diameter Ni crystals journal December 2007
Ultrahigh stress and strain in hierarchically structured hollow nanoparticles journal October 2008
Ferroelectric order in individual nanometre-scale crystals journal July 2012
Atomic origins of the high catalytic activity of nanoporous gold journal August 2012
Liquid-like pseudoelasticity of sub-10-nm crystalline silver particles journal October 2014
Single-donor ionization energies in a nanoscale CMOS channel journal December 2009
Cold welding of ultrathin gold nanowires journal February 2010
Gate-induced quantum-confinement transition of a single dopant atom in a silicon FinFET journal June 2008
Dipolar Magnetism in Ordered and Disordered Low-Dimensional Nanoparticle Assemblies journal February 2013
The antiferromagnetic structures of IrMn3 and their influence on exchange-bias journal August 2013
Structural and Morphological Evolution of Lead Dendrites during Electrochemical Migration journal November 2013
Novel microchip for in situ TEM imaging of living organisms and bio-reactions in aqueous conditions journal January 2008
Atomic-level 2-dimensional chemical mapping and imaging of individual dopants in a phosphor crystal journal January 2013
An environmental cell transmission electron microscope journal June 1991
Electron holography of Fe-based nanocrystalline magnetic materials (invited) journal June 2004
Electron microscopy of whole cells in liquid with nanometer resolution journal January 2009
Direct observation of stick-slip movements of water nanodroplets induced by an electron beam journal April 2012
Electron beam induced deposition of silicon nanostructures from a liquid phase precursor journal September 2012
Plastic Deformation of Single Nanometer-Sized Crystals journal October 2008
Nanoscale Bending of Multilayered Boron Nitride and Graphene Ribbons: Experiment and Objective Molecular Dynamics Calculations journal July 2012
Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals journal March 2002
Carbon Nanotubes as High-Pressure Cylinders and Nanoextruders journal May 2006
Reaction-Driven Restructuring of Rh-Pd and Pt-Pd Core-Shell Nanoparticles journal November 2008
Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories journal June 2009
In Situ Studies of Chemistry and Structure of Materials in Reactive Environments journal January 2011
Visualizing Gas Molecules Interacting with Supported Nanoparticulate Catalysts at Reaction Conditions journal January 2012
High-Resolution EM of Colloidal Nanocrystal Growth Using Graphene Liquid Cells journal April 2012
Real-Time Imaging of Pt3Fe Nanorod Growth in Solution journal May 2012
Facet development during platinum nanocube growth journal August 2014
Imaging Nanobubbles in Water with Scanning Transmission Electron Microscopy journal April 2011

Cited By (13)

Electrochemical and Structural Analysis in All‐Solid‐State Lithium Batteries by Analytical Electron Microscopy: Progress and Perspectives journal October 2019
The Mechanical Properties of Nanowires journal January 2017
Direct Visualization of Li Dendrite Effect on LiCoO 2 Cathode by In Situ TEM journal November 2018
Direct observation of oxygen vacancy-driven structural and resistive phase transitions in La2/3Sr1/3MnO3 journal February 2017
Reversible superdense ordering of lithium between two graphene sheets journal November 2018
Bimetallic synergy in cobalt–palladium nanocatalysts for CO oxidation journal December 2018
The chemistry of nucleation journal January 2016
Tip-enhanced Raman spectroscopy for surfaces and interfaces journal January 2017
In situ study of nucleation and growth dynamics of Au nanoparticles on MoS 2 nanoflakes journal January 2018
Developments of cation-exchange by in situ electron microscopy journal January 2019
Pitfalls and reproducibility of in situ synchrotron powder X-ray diffraction studies of solvothermal nanoparticle formation journal March 2018
Automating material image analysis for material discovery journal April 2019
Advanced tomography techniques for inorganic, organic, and biological materials journal July 2016

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