A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

Wan, Shun; Jiang, Xueguang; Guo, Bingkun; Dai, Sheng; Goodenough, John B.; Sun, Xiao-Guang

doi:10.1039/C5CC01428J

A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

Journal Article · Mon Apr 27 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/C5CC01428J· OSTI ID:1185994

Wan, Shun ^[1]; Jiang, Xueguang ^[2]; Guo, Bingkun ^[3]; Dai, Sheng ^[4]; Goodenough, John B. ^[3]; Sun, Xiao-Guang ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Texas, Austin, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1185994

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 48 Vol. 51; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (32)

Synthesis and Characterization of Lithium Bis(fluoromalonato)borate for Lithium-Ion Battery Applications Liao, Chen; Han, Kee Sung; Baggetto, Loïc Advanced Energy Materials, Vol. 4, Issue 6 https://doi.org/10.1002/aenm.201301368	journal	November 2013
Chloride-Free Method to Synthesise New Ionic Liquids with Mixed Borate Anions Schreiner, Christian; Amereller, Marius; Gores, Heiner J. Chemistry - A European Journal, Vol. 15, Issue 10 https://doi.org/10.1002/chem.200802243	journal	February 2009
Lithium-Ion Conducting Electrolyte Salts for Lithium Batteries Aravindan, Vanchiappan; Gnanaraj, Joe; Madhavi, Srinivasan Chemistry - A European Journal, Vol. 17, Issue 51 https://doi.org/10.1002/chem.201101486	journal	November 2011
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450271	journal	December 2004
Surface film formation on a graphite negative electrode in lithium-ion batteries: AFM study on the effects of co-solvents in ethylene carbonate-based solutions Jeong, Soon-Ki; Inaba, Minoru; Iriyama, Yasutoshi Electrochimica Acta, Vol. 47, Issue 12 https://doi.org/10.1016/S0013-4686(02)00099-3	journal	May 2002
Doped sulfone electrolytes for high voltage Li-ion cell applications Sun, Xiaoguang; Angell, C. Austen Electrochemistry Communications, Vol. 11, Issue 7, p. 1418-1421 https://doi.org/10.1016/j.elecom.2009.05.020	journal	July 2009
The influence of preparation conditions on electrochemical properties of LiNi0.5Mn1.5O4 thin film electrodes by PLD Xia, H.; Tang, S. B.; Lu, L. Electrochimica Acta, Vol. 52, Issue 8 https://doi.org/10.1016/j.electacta.2006.07.013	journal	February 2007
Synthesis and electrochemistry of 5V LiNi0.4Mn1.6O4 cathode materials synthesized by different methods Yi, Ting-Feng; Zhu, Yan-Rong Electrochimica Acta, Vol. 53, Issue 7 https://doi.org/10.1016/j.electacta.2007.11.062	journal	February 2008
Film formation in LiBOB-containing electrolytes Panitz, Jan-Christoph; Wietelmann, Ulrich; Wachtler, Mario Journal of Power Sources, Vol. 153, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.05.025	journal	February 2006
Interfacial reactions between graphite electrodes and propylene carbonate-based solutions: Electrolyte-concentration dependence of electrochemical lithium intercalation reaction Jeong, Soon-Ki; Inaba, Minoru; Iriyama, Yasutoshi Journal of Power Sources, Vol. 175, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.08.065	journal	January 2008
New gel polyelectrolytes for rechargeable lithium batteries Sun, X. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2003.11.043	journal	November 2004
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Synthesis and Characterization of Network Type Single Ion Conductors Sun, Xiao-Guang; Reeder, Craig L.; Kerr, John B. Macromolecules, Vol. 37, Issue 6 https://doi.org/10.1021/ma035690g	journal	March 2004
Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate Sun, Xiao-Guang; Kerr, John B.; Reeder, Craig L. Macromolecules, Vol. 37, Issue 14 https://doi.org/10.1021/ma049331c	journal	July 2004
Synthesis and Characterization of Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate Sun, Xiao-Guang; Kerr, John B. Macromolecules, Vol. 39, Issue 1 https://doi.org/10.1021/ma0507701	journal	January 2006
Bis(fluoromalonato)borate (BFMB) anion based ionic liquid as an additive for lithium-ion battery electrolytes Sun, Xiao-Guang; Liao, Chen; Baggetto, Loïc J. Mater. Chem. A, Vol. 2, Issue 20 https://doi.org/10.1039/C3TA14943A	journal	January 2014
Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions Xu, Wu; Angell, C. Austen Electrochemical and Solid-State Letters, Vol. 4, Issue 1 https://doi.org/10.1149/1.1344281	journal	January 2001
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes. V. Synthesis and Properties of Lithium Bis[2,3-pyridinediolato(2−)-O,Oʹ]borate Barthel, J.; Schmid, A.; Gores, H. J. Journal of The Electrochemical Society, Vol. 147, Issue 1 https://doi.org/10.1149/1.1393138	journal	January 2000
Electrochemical and Infrared Studies of the Reduction of Organic Carbonates Zhang, Xuerong; Kostecki, Robert; Richardson, Thomas J. Journal of The Electrochemical Society, Vol. 148, Issue 12 https://doi.org/10.1149/1.1415547	journal	January 2001
Formation of Solid Electrolyte Interface in Lithium Nickel Mixed Oxide Electrodes during the First Cycling Zhang, S. S.; Xu, K.; Jow, T. R. Electrochemical and Solid-State Letters, Vol. 5, Issue 5 https://doi.org/10.1149/1.1464506	journal	January 2002
Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate Xu, Kang; Zhang, Shengshui; Poese, Bruce A. Electrochemical and Solid-State Letters, Vol. 5, Issue 11, p. A259-A262 https://doi.org/10.1149/1.1510322	journal	September 2002
Electrochemical Intercalation of Lithium Ion within Graphite from Propylene Carbonate Solutions Jeong, Soon-Ki; Inaba, Minoru; Iriyama, Yasutoshi Electrochemical and Solid-State Letters, Vol. 6, Issue 1 https://doi.org/10.1149/1.1526781	journal	January 2003
Formation of the Graphite/Electrolyte Interface by Lithium Bis(oxalato)borate Xu, Kang; Zhang, Shengshui; Jow, T. Richard Electrochemical and Solid-State Letters, Vol. 6, Issue 6 https://doi.org/10.1149/1.1568173	journal	January 2003
How Conductivities and Viscosities of PC-DEC and PC-EC Solutions of LiBF[sub 4], LiPF[sub 6], LiBOB, Et[sub 4]NBF[sub 4], and Et[sub 4]NPF[sub 6] Differ and Why Ding, Michael S.; Richard Jow, T. Journal of The Electrochemical Society, Vol. 151, Issue 12 https://doi.org/10.1149/1.1809575	journal	January 2004
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes Barthel, J. Journal of The Electrochemical Society, Vol. 143, Issue 11 https://doi.org/10.1149/1.1837254	journal	January 1996
Synthesis and Electrochemistry of LiNi[sub x]Mn[sub 2−x]O[sub 4] Zhong, Qiming Journal of The Electrochemical Society, Vol. 144, Issue 1 https://doi.org/10.1149/1.1837386	journal	January 1997
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes: IV. Investigations of the Electrochemical Oxidation of Lithium Organoborates Barthel, J.; Buestrich, R.; Gores, H. J. Journal of The Electrochemical Society, Vol. 144, Issue 11 https://doi.org/10.1149/1.1838103	journal	November 1997
Lithium Bis[5-fluoro-2-olato-1-benzenesulfonato (2-)-O,Oʹ]borate(1-), a New Anodically and Cathodically Stable Salt for Electrolytes of Lithium-Ion Cells Barthel, J. Journal of The Electrochemical Society, Vol. 145, Issue 2 https://doi.org/10.1149/1.1838265	journal	January 1998
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes Barthel, J. Journal of The Electrochemical Society, Vol. 142, Issue 8 https://doi.org/10.1149/1.2050048	journal	January 1995
Polyelectrolyte Membranes Containing Lithium Malonato(difluoro)borate for Lithium-Ion Systems Driscoll, Peter F.; Yang, Li; Gervais, Matthieu 218th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.3557699	conference	January 2011
Six-Membered-Ring Malonatoborate-Based Lithium Salts as Electrolytes for Lithium Ion Batteries Yang, Li; Zhang, Hanjun; Driscoll, Peter F. 218th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.3589921	conference	January 2011
New Gel polyelectrolytes for rechargeable lithium batteries Sun, Xiao-Guang; Liu, Gao; Xie, Jiangbing https://doi.org/10.2172/838538	report	June 2003

Cited By (6)

A Novel Electrolyte Salt Additive for Lithium-Ion Batteries with Voltages Greater than 4.7 V Li, Yunchao; Wan, Shun; Veith, Gabriel M. Advanced Energy Materials, Vol. 7, Issue 4 https://doi.org/10.1002/aenm.201601397	journal	November 2016
Designing Low Impedance Interface Films Simultaneously on Anode and Cathode for High Energy Batteries Liao, Bo; Li, Hongying; Xu, Mengqing Advanced Energy Materials, Vol. 8, Issue 22 https://doi.org/10.1002/aenm.201800802	journal	May 2018
Fluor und Lithium: Ideale Partner für Elektrolyte in wiederaufladbaren Hochleistungsbatterien Aspern, N.; Röschenthaler, G. ‐V.; Winter, M. Angewandte Chemie, Vol. 131, Issue 45 https://doi.org/10.1002/ange.201901381	journal	July 2019
Fluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes Aspern, N.; Röschenthaler, G. ‐V.; Winter, M. Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201901381	journal	November 2019
Unsymmetrical fluorinated malonatoborate as an amphoteric additive for high-energy-density lithium-ion batteries Han, Jung-Gu; Lee, Jae Bin; Cha, Aming Energy & Environmental Science, Vol. 11, Issue 6 https://doi.org/10.1039/c8ee00372f	journal	January 2018
X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell Ketenoglu, Didem; Spiekermann, Georg; Harder, Manuel Journal of Synchrotron Radiation, Vol. 25, Issue 2 https://doi.org/10.1107/s1600577518001662	journal	February 2018

Similar Records

New promising lithium malonatoborate salts for high voltage lithium ion batteries

Journal Article · Wed Nov 30 19:00:00 EST 2016 · Journal of Materials Chemistry. A · OSTI ID:1344276

Development of Lithium Dimethyl Phosphate as an Electrolyte Additive for Lithium Ion Batteries

Journal Article · Tue Apr 26 20:00:00 EDT 2016 · Journal of the Electrochemical Society · OSTI ID:1437261

Methyl propyl carbonate: A promising single solvent for Li-ion battery electrolytes

Journal Article · Tue Jul 01 00:00:00 EDT 1997 · Journal of the Electrochemical Society · OSTI ID:533100

Related Subjects

25 ENERGY STORAGE

A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

Citation Formats

References (32)

Cited By (6)

Similar Records

Related Subjects