Electrically conducting porphyrin and porphyrin-fullerene electropolymers

Gust, Jr., John Devens; Liddell, Paul Anthony; Gervaldo, Miguel Andres; Bridgewater, James Ward; Brennan, Bradley James; Moore, Thomas Andrew; Moore, Ana Lorenzelli

Electrically conducting porphyrin and porphyrin-fullerene electropolymers

Patent · Tue Mar 11 04:00:00 EDT 2014

OSTI ID:1126698

Gust, Jr., John Devens; Liddell, Paul Anthony; Gervaldo, Miguel Andres; Bridgewater, James Ward; Brennan, Bradley James; Moore, Thomas Andrew; Moore, Ana Lorenzelli

Compounds with aryl ring(s) at porphyrin meso position(s) bearing an amino group in position 4 relative to the porphyrin macrocycle, and at least one unsubstituted 5 (hydrogen-bearing) meso position with the 10-, 15-, and/or 20-relationship to the aryl ring bearing the amino group, and metal complexes thereof, feature broad spectral absorption throughout the visible region. These compounds are electropolymerized to form electrically conducting porphyrin and porphyrin-fullerene polymers that are useful in photovoltaic applications. The structure of one such electrically conducting porphyrin polymer is shown below. ##STR00001##

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Research Organization:: Arizona State University, Scottsdale, AZ, USA

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-03ER15393

Assignee:: Arizona Board of Regents for and on behalf of Arizona State University (Scottsdale, AZ)

Patent Number(s):: 8,669,359

Application Number:: 12/552,187

OSTI ID:: 1126698

Country of Publication:: United States

Language:: English

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