Soluble porphyrin polymers

Gust, Jr., John Devens; Liddell, Paul Anthony

Soluble porphyrin polymers

Patent · Tue Jul 07 04:00:00 EDT 2015

OSTI ID:1190903

Gust, Jr., John Devens; Liddell, Paul Anthony

Porphyrin polymers of Structure 1, where n is an integer (e.g., 1, 2, 3, 4, 5, or greater) ##STR00001## are synthesized by the method shown in FIGS. 2A and 2B. The porphyrin polymers of Structure 1 are soluble in organic solvents such as 2-MeTHF and the like, and can be synthesized in bulk (i.e., in processes other than electropolymerization). These porphyrin polymers have long excited state lifetimes, making the material suitable as an organic semiconductor for organic electronic devices including transistors and memories, as well as solar cells, sensors, light-emitting devices, and other opto-electronic devices.

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Research Organization:: Arizona Board of Regents, A Body Corporate of the State of Arizona Acting for and on Behalf of Arizona State University, Scottsdale, AZ (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-03ER15393

Assignee:: Arizona Board of Regents, A Body Corporate of the State of Arizona Acting for and on Behalf of Arizona State University (Scottsdale, AZ)

Patent Number(s):: 9,076,972

Application Number:: 13/907,452

OSTI ID:: 1190903

Country of Publication:: United States

Language:: English

References (30)

Anodic oxidation and physicochemical properties of various porphyrin-fluorenes or -spirobifluorenes: Synthesis of new polymers for heterogeneous catalytic reactions Poriel, Cyril; Ferrand, Yann; Le Maux, Paul Journal of Electroanalytical Chemistry, Vol. 583, Issue 1, p. 92-103 https://doi.org/10.1016/j.jelechem.2005.05.005	journal	September 2005
Very stable, highly electroactive polymers of zinc(II)-5,15-bisthienylphenyl porphyrin exhibiting charge-trapping effects Li, Guangtao; Bhosale, Sheshanath; Tao, Shengyang Polymer, Vol. 46, Issue 14, p. 5299-5307 https://doi.org/10.1016/j.polymer.2005.04.029	journal	June 2005
Fullerene−Porphyrin Constructs Boyd, Peter D. W.; Reed, Christopher A. Accounts of Chemical Research, Vol. 38, Issue 4 https://doi.org/10.1021/ar040168f	journal	April 2005
Energy and Electron Transfer in Polyacetylene-Linked Zinc-Porphyrin-[60]Fullerene Molecular Wires Vail, Sean A.; Krawczuk, Paul J.; Guldi, Dirk M. Chemistry - A European Journal, Vol. 11, Issue 11 https://doi.org/10.1002/chem.200401348	journal	May 2005
Hole transport in porphyrin thin films Savenije, Tom J.; Goossens, Albert Physical Review B, Vol. 64, Issue 11 https://doi.org/10.1103/PhysRevB.64.115323	journal	August 2001
Electrochemistry of various substituted aminophenyl iron porphyrins: Part I. Redox properties of dissolved, adsorbed and electropolymerized species Bettelheim, A.; Ozer, D.; Harth, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 266, Issue 1, p. 93-108 https://doi.org/10.1016/0022-0728(89)80218-9	journal	July 1989
Electrochromic materials Mortimer, Roger J. Chemical Society Reviews, Vol. 26, Issue 3 https://doi.org/10.1039/CS9972600147	journal	January 1997
Porphyrin-Based Hole Conducting Electropolymer Liddell, Paul A.; Gervaldo, Miguel; Bridgewater, James W. Chemistry of Materials, Vol. 20, Issue 1 https://doi.org/10.1021/cm7022955	journal	January 2008
Polarized Infrared Spectra of Photooriented Matrix-Isolated Free-Base Porphyrin Isotopomers Radziszewski, Juliusz G.; Nepras, Milos; Balaji, V. The Journal of Physical Chemistry, Vol. 99, Issue 39, p. 14254-14260 https://doi.org/10.1021/j100039a011	journal	September 1995
Comparative study of electropolymerized cobalt porphyrin and phthalocyanine based films for the electrochemical activation of thiols Griveau, Sophie; Albin, Valérie; Pauporté, Thierry Journal of Materials Chemistry, Vol. 12, Issue 2 https://doi.org/10.1039/B106817B	journal	January 2002
Synthesis and electrochemistry of conductive copolymeric porphyrins Fish, Judith R.; Kubaszewski, Eugeniusz; Peat, Alexander Chemistry of Materials, Vol. 4, Issue 4 https://doi.org/10.1021/cm00022a010	journal	July 1992
Synthesis, electrochemistry, absorption and electro-polymerization of aniline-ethynyl metalloporphyrins Lin, Ching-Yao; Hung, Yu-Chun; Liu, Chih-Ming Dalton Transactions, Issue 2 https://doi.org/10.1039/B410416A	journal	January 2005
Electrocatalysis of dioxygen reduction in aqueous acid and base by multimolecular layer films of electropolymerized cobalt tetra(o-aminophenyl)porphyrin Bettelheim, A.; White, B. A.; Murray, Royce W. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 217, Issue 2, p. 271-286 https://doi.org/10.1016/0022-0728(87)80224-3	journal	February 1987
Oxidative electrochemistry of electropolymerized metalloprotoporphyrin films Macor, K. A.; Spiro, T. G. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 163, Issue 1-2, p. 223-236 https://doi.org/10.1016/S0022-0728(84)80054-6	journal	March 1984
A Scalable Synthesis of Meso-Substituted Dipyrromethanes Laha, Joydev K.; Dhanalekshmi, Savithri; Taniguchi, Masahiko Organic Process Research & Development, Vol. 7, Issue 6 https://doi.org/10.1021/op034083q	journal	November 2003
Conductive polymeric Cu(II) tetrakis(3-methoxy-4-hydroxyphenyl) porphyrin as a photosensitizer in a photoelectrochemical Cell Malinski, Tadeusz; Ciszewski, Aleksander; Fish, Judith Advanced Materials, Vol. 4, Issue 5, p. 354-357 https://doi.org/10.1002/adma.19920040508	journal	May 1992
Photoelectrochemical characterisation of porphyrin-coated electrodes Basu, J.; Rohatgi-Mukherjee, K. K. Solar Energy Materials, Vol. 21, Issue 4, p. 317-325 https://doi.org/10.1016/0165-1633(91)90029-K	journal	January 1991
Immobilization of metalloporphyrins in electropolymerized films: design and applications Bedioui, Fethi; Devynck, Jacques; Bied-Charreton, Claude Accounts of Chemical Research, Vol. 28, Issue 1 https://doi.org/10.1021/ar00049a005	journal	January 1995
Porphyrin electrode films prepared by electrooxidation of metalloprotoporphyrins Macor, K. A.; Spiro, T. G. Journal of the American Chemical Society, Vol. 105, Issue 17 https://doi.org/10.1021/ja00355a012	journal	August 1983
Electroactive porphyrin films from electropolymerized metallotetra(o-aminophenyl)porphyrins White, B. A.; Murray, Royce W. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 189, Issue 2, p. 345-352 https://doi.org/10.1016/0368-1874(85)80078-2	journal	July 1985
Photovoltaic effects in porphyrin polymer films and heterojunctions Marée, C. H. M.; Roosendaal, S. J.; Savenije, T. J. Journal of Applied Physics, Vol. 80, Issue 6 https://doi.org/10.1063/1.363203	journal	September 1996
Electrochemical and resonance Raman spectroscopic characterization of polyaniline and polyaniline-metalloporphyrin electrode films Macor, Kathleen A.; Su, Y. Oliver; Miller, Lisa A. Inorganic Chemistry, Vol. 26, Issue 16 https://doi.org/10.1021/ic00263a009	journal	August 1987
Excited-State Energy-Transfer Dynamics in Self-Assembled Triads Composed of Two Porphyrins and an Intervening Bis(dipyrrinato)metal Complex Yu, Lianhe; Muthukumaran, Kannan; Sazanovich, Igor V. Inorganic Chemistry, Vol. 42, Issue 21 https://doi.org/10.1021/ic034559m	journal	October 2003
DFT study on the influence of meso-phenyl substitution on the geometric, electronic structure and vibrational spectra of free base porphyrin Zhang, Ying-Hui; Ruan, Wen-Juan; Li, Zhi-Yun Chemical Physics, Vol. 315, Issue 1-2, p. 201-213 https://doi.org/10.1016/j.chemphys.2005.04.004	journal	August 2005
Electropolymerization of Tetrakis(o-aminophenyl)porphyrin and Relevant Transition Metal Complexes from Aqueous Solution. The Resulting Modified Electrodes as Potentiometric Sensors Bruti, Enrico Maria; Giannetto, Marco; Mori, Giovanni Electroanalysis, Vol. 11, Issue 8, p. 565-572 https://doi.org/10.1002/(SICI)1521-4109(199906)11:8<565::AID-ELAN565>3.0.CO;2-V	journal	June 1999
Lead structures for applications in photodynamic therapy. Part 1: Synthesis and variation of m-THPC (Temoporfin) related amphiphilic A₂BC-type porphyrins Wiehe, Arno; Shaker, Yasser M.; Brandt, Johan C. Tetrahedron, Vol. 61, Issue 23, p. 5535-5564 https://doi.org/10.1016/j.tet.2005.03.086	journal	June 2005
Electrochemical polymerization of amino-, pyrrole-, and hydroxy-substituted tetraphenylporphyrins Bettelheim, A.; White, B. A.; Raybuck, S. A. Inorganic Chemistry, Vol. 26, Issue 7 https://doi.org/10.1021/ic00254a011	journal	April 1987
An efficient synthesis of highly functionalized asymmetric porphyrins with organolithium reagents Feng, Xiangdong; Senge, Mathias O. Journal of the Chemical Society, Perkin Transactions 1, Issue 9 https://doi.org/10.1039/B100012H	journal	January 2001
Synthesis of covalently-linked linear donor-acceptor copolymers containing porphyrins and oligothiophenes Duanmu, Chuan-Song; Chen, Zhang-Ping; Yu, Xue-Song Chinese Journal of Chemistry, Vol. 22, Issue 8 https://doi.org/10.1002/cjoc.20040220803	journal	August 2004
Porphyrins, phthalocyanines and related systems in polymer phases Wohrle, Dieter Journal of Porphyrins and Phthalocyanines (JPP), Vol. 04, Issue 04, p. 418-424 https://doi.org/10.1002/(SICI)1099-1409(200006/07)4:4<418::AID-JPP239>3.0.CO;2-V	journal	June 2000

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