Fusing porphyrins with polycyclic aromatic hydrocarbons and heterocycles for optoelectronic applications

Thompson, Mark E.; Diev, Viacheslav; Hanson, Kenneth; Forrest, Stephen R.

Fusing porphyrins with polycyclic aromatic hydrocarbons and heterocycles for optoelectronic applications

Patent · Tue Aug 18 04:00:00 EDT 2015

OSTI ID:1210220

Thompson, Mark E.; Diev, Viacheslav; Hanson, Kenneth; Forrest, Stephen R.

A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated heterocyclic rings can be obtained by a thermal fusion process. The compounds can include structures of Formula I: ##STR00001## By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyclic rings or heterocyclic rings to the non-activated porphyrin core in meso,.beta. fashion is achieved resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.

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Research Organization:: The University of Southern California, Los Angeles, CA (United States)

Sponsoring Organization:: USDOE

Assignee:: The University of Southern California (Los Angeles, CA)

Patent Number(s):: 9,113,535

Application Number:: 12/985,439

OSTI ID:: 1210220

Country of Publication:: United States

Language:: English

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