A co-crystal of polyoxometalates exhibiting single-molecule magnet behavior: the structural origin of a large magnetic anisotropy
A polyoxometalate-based {MnIII3MnIV} single-molecule magnet exhibits a large axial anisotropy (D = −0.86 cm−1) resulting from a near-parallel alignment of Jahn–Teller axes. Its rigorous three-fold symmetry (i.e. rhombicity E → 0) and increased intercluster separation via co-crystallization effectively hamper quantum tunnelling of the magnetization. Graphical abstract: A co-crystal of polyoxometalates exhibiting single-molecule magnet behavior: the structural origin of a large magnetic anisotropy
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- DE-AC02-07CH11358
- OSTI ID:
- 1053241
- Report Number(s):
- IS-J 7783
- Journal Information:
- Dalton Transactions, Vol. 41, Issue 33
- Country of Publication:
- United States
- Language:
- English
Similar Records
Single-ion magnetism in the extended solid-state: insights from X-ray absorption and emission spectroscopy
Assembly of new polyoxometalate–templated metal–organic frameworks based on flexible ligands
Magnetic anisotropies in SmCo thin films
Journal Article
·
Wed Oct 07 00:00:00 EDT 2020
· Chemical Science
·
OSTI ID:1053241
+9 more
Assembly of new polyoxometalate–templated metal–organic frameworks based on flexible ligands
Journal Article
·
Sun Mar 15 00:00:00 EDT 2015
· Journal of Solid State Chemistry
·
OSTI ID:1053241
+1 more
Magnetic anisotropies in SmCo thin films
Miscellaneous
·
Fri Dec 31 00:00:00 EST 1993
·
OSTI ID:1053241