A co-crystal of polyoxometalates exhibiting single-molecule magnet behavior: the structural origin of a large magnetic anisotropy

Fang, Xikui; McCallum, Kendall; Pratt III, Harry D.; Anderson, Travis M.; Dennis, Kevin; Luban, Marshall

doi:10.1039/c2dt30451a

A co-crystal of polyoxometalates exhibiting single-molecule magnet behavior: the structural origin of a large magnetic anisotropy

Journal Article · Thu Mar 29 00:00:00 EDT 2012 · Dalton Transactions

DOI:https://doi.org/10.1039/c2dt30451a· OSTI ID:1053241

Fang, Xikui ^[1]; McCallum, Kendall ^[1]; Pratt III, Harry D. ^[2]; Anderson, Travis M. ^[2]; Dennis, Kevin ^[1]; Luban, Marshall ^[1]

Ames Laboratory, and Iowa State University, Ames, IA (United States)
Sandia National Laboratory (SNL-NM), Albuquerque, NM (United States)

A polyoxometalate-based {Mn^III₃Mn^IV} single-molecule magnet exhibits a large axial anisotropy (D = -0.86 cm^-1) resulting from a near-parallel alignment of Jahn–Teller axes. Its rigorous three-fold symmetry (i.e. rhombicity E → 0) and increased intercluster separation via co-crystallization effectively hamper quantum tunnelling of the magnetization.

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States); Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program

DOE Contract Number:: AC02-07CH11358; AC04-94AL85000

OSTI ID:: 1053241

Report Number(s):: IS-J--7783

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 33 Vol. 41; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (32)

Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates Fang, Xikui; Speldrich, Manfred; Schilder, Helmut Chemical Communications, Vol. 46, Issue 16 https://doi.org/10.1039/b925947c	journal	January 2010
A Survey of Cocrystals Reported Prior to 2000 Stahly, G. Patrick Crystal Growth & Design, Vol. 9, Issue 10 https://doi.org/10.1021/cg900873t	journal	August 2009
Utilizing the Adaptive Polyoxometalate [As₂W₁₉O₆₇(H₂O)]^14– To Support a Polynuclear Lanthanoid-Based Single-Molecule Magnet Ritchie, Chris; Speldrich, Manfred; Gable, Robert W. Inorganic Chemistry, Vol. 50, Issue 15 https://doi.org/10.1021/ic200366a	journal	July 2011
Single-crystal x-ray structures of the polyoxotungstate salts K8.3Na1.7[Cu4(H2O)2(PW9O34)2].cntdot.24H2O and Na14Cu[Cu4(H2O)2(P2W15O56)2].cntdot.53H2O Weakley, Timothy J. R.; Finke, Richard G. Inorganic Chemistry, Vol. 29, Issue 6 https://doi.org/10.1021/ic00331a025	journal	March 1990
Mononuclear Lanthanide Single-Molecule Magnets Based on Polyoxometalates AlDamen, Murad A.; Clemente-Juan, Juan M.; Coronado, Eugenio Journal of the American Chemical Society, Vol. 130, Issue 28 https://doi.org/10.1021/ja801659m	journal	July 2008
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics Cole, Kenneth S.; Cole, Robert H. The Journal of Chemical Physics, Vol. 9, Issue 4 https://doi.org/10.1063/1.1750906	journal	April 1941
Single-Molecule Magnets: Preparation and Properties of Low Symmetry [Mn₄O₃(O₂CPh-R)₄(dbm)₃] Complexes with S = ⁹/₂ Aliaga-Alcalde, Núria; Edwards, Rachel S.; Hill, Stephen O. Journal of the American Chemical Society, Vol. 126, Issue 39 https://doi.org/10.1021/ja047527m	journal	September 2004
The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4] Bagai, Rashmi; Christou, George Chemical Society Reviews, Vol. 38, Issue 4 https://doi.org/10.1039/b811963e	journal	January 2009
Mixed Transition Metal−Lanthanide Complexes at High Oxidation States: Heteronuclear Ce ^IV Mn ^IV Clusters Tasiopoulos, Anastasios J.; Milligan, Paul L.; Abboud, Khalil A. Inorganic Chemistry, Vol. 46, Issue 23 https://doi.org/10.1021/ic700994p	journal	October 2007
A Record Anisotropy Barrier for a Single-Molecule Magnet Milios, Constantinos J.; Vinslava, Alina; Wernsdorfer, Wolfgang Journal of the American Chemical Society, Vol. 129, Issue 10 https://doi.org/10.1021/ja068961m	journal	March 2007
A N ₂ ^3– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K Rinehart, Jeffrey D.; Fang, Ming; Evans, William J. Journal of the American Chemical Society, Vol. 133, Issue 36 https://doi.org/10.1021/ja206286h	journal	September 2011
A Stable Hybrid Bisphosphonate Polyoxometalate Single‐Molecule Magnet El Moll, Hani; Dolbecq, Anne; Marrot, Jérôme Chemistry – A European Journal, Vol. 18, Issue 13 https://doi.org/10.1002/chem.201200140	journal	February 2012
Trivacant heteropolytungstate derivatives. 3. Rational syntheses, characterization, two-dimensional tungsten-183 NMR, and properties of tungstometallophosphates P2W18M4(H2O)2O6810- and P4W30M4(H2O)2O11216- (M = cobalt, copper, zinc) Finke, Richard G.; Droege, Michael W.; Domaille, Peter J. Inorganic Chemistry, Vol. 26, Issue 23 https://doi.org/10.1021/ic00270a014	journal	November 1987
Exchange-biased quantum tunnelling in a supramolecular dimer of single-molecule magnets Wernsdorfer, Wolfgang; Aliaga-Alcalde, Núria; Hendrickson, David N. Nature, Vol. 416, Issue 6879 https://doi.org/10.1038/416406a	journal	March 2002
A Criterion for the Anisotropy Barrier in Single-Molecule Magnets Waldmann, Oliver Inorganic Chemistry, Vol. 46, Issue 24 https://doi.org/10.1021/ic701365t	journal	November 2007
Route for the Elaboration of Functionalized Hybrid 3d-Substituted Trivacant Keggin Anions Rousseau, Guillaume; Oms, Olivier; Dolbecq, Anne Inorganic Chemistry, Vol. 50, Issue 16 https://doi.org/10.1021/ic2011088	journal	July 2011
Preparation, structure, and magnetic properties of a dodecanuclear mixed-valence manganese carboxylate Lis, T. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 36, Issue 9 https://doi.org/10.1107/S0567740880007893	journal	September 1980
Activated dynamics in a two-dimensional Ising spin glass: Rb 2 Cu 1 − x Co x F 4 Dekker, C.; Arts, A. F. M.; de Wijn, H. W. Physical Review B, Vol. 40, Issue 16 https://doi.org/10.1103/PhysRevB.40.11243	journal	December 1989
A Pentanuclear Manganese Single-Molecule Magnet with a Large Anisotropy Yang, Chen-I; Wernsdorfer, Wolfgang; Lee, Gene-Hsiang Journal of the American Chemical Society, Vol. 129, Issue 3 https://doi.org/10.1021/ja066533a	journal	December 2006
Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials Gatteschi, Dante; Sessoli, Roberta Angewandte Chemie International Edition, Vol. 42, Issue 3 https://doi.org/10.1002/anie.200390099	journal	January 2003
Nickel(II)−Molybdenum(III)−Cyanide Clusters: Synthesis and Magnetic Behavior of Species Incorporating [(Me₃tacn)Mo(CN)₃] Shores, Matthew P.; Sokol, Jennifer J.; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 124, Issue 10 https://doi.org/10.1021/ja011645h	journal	February 2002
How to Build Molecules with Large Magnetic Anisotropy Cirera, Jordi; Ruiz, Eliseo; Alvarez, Santiago Chemistry - A European Journal, Vol. 15, Issue 16 https://doi.org/10.1002/chem.200801608	journal	April 2009
Polyoxometalate-Mediated Self-Assembly of Single-Molecule Magnets: {[XW ₉ O ₃₄ ] ₂ [Mn ^III ₄ Mn ^II ₂ O ₄ (H ₂ O) ₄ ]} ¹²⁻ Ritchie, Chris; Ferguson, Alan; Nojiri, Hiroyuki Angewandte Chemie International Edition, Vol. 47, Issue 30 https://doi.org/10.1002/anie.200801281	journal	June 2008
A [Mn ^III ₃ O] ⁷⁺ Single-Molecule Magnet: the Anisotropy Barrier Enhanced by Structural Distortion Yang, Chen-I; Wernsdorfer, Wolfgang; Cheng, Kai-Hung Inorganic Chemistry, Vol. 47, Issue 22 https://doi.org/10.1021/ic8012238	journal	November 2008
What is not required to make a single molecule magnet Neese, Frank; Pantazis, Dimitrios A. Faraday Discuss., Vol. 148 https://doi.org/10.1039/C005256F	journal	January 2011
Polyoxometalate-Supported 3d–4f Heterometallic Single-Molecule Magnets Feng, Xiaojia; Zhou, Wenzhe; Li, Yangguang Inorganic Chemistry, Vol. 51, Issue 5 https://doi.org/10.1021/ic202418y	journal	February 2012
Hexadecacobalt(II)‐Containing Polyoxometalate‐Based Single‐Molecule Magnet Ibrahim, Masooma; Lan, Yanhua; Bassil, Bassem S. Angewandte Chemie International Edition, Vol. 50, Issue 20 https://doi.org/10.1002/anie.201100280	journal	April 2011
Mixed Transition-Metal—Lanthanide Complexes at Higher Oxidation States: Heteronuclear CeIV–MnIV Clusters Tasiopoulos, Anastasios J.; O'Brien, Ted A.; Abboud, Khalil A. Angewandte Chemie International Edition, Vol. 43, Issue 3 https://doi.org/10.1002/anie.200352898	journal	January 2004
The Heteropolyoxotungstates: Relationships Between Routes of Formation and Structures Contant,, R.; Herveb,, G. Reviews in Inorganic Chemistry, Vol. 22, Issue 2 https://doi.org/10.1515/REVIC.2002.22.2.63	journal	April 2002
A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state Fang, Xikui; Kögerler, Paul; Speldrich, Manfred Chem. Commun., Vol. 48, Issue 9 https://doi.org/10.1039/C1CC15520B	journal	January 2012
Iron Polyoxometalate Single‐Molecule Magnets Compain, Jean‐Daniel; Mialane, Pierre; Dolbecq, Anne Angewandte Chemie International Edition, Vol. 48, Issue 17 https://doi.org/10.1002/anie.200900117	journal	April 2009
Magnetic Bistability of Individual Single‐Molecule Magnets Grafted on Single‐Wall Carbon Nanotubes Giusti, Anna; Charron, Gaëlle; Mazerat, Sandra Angewandte Chemie International Edition, Vol. 48, Issue 27 https://doi.org/10.1002/anie.200901806	journal	June 2009

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