A polyoxommetalate-based single-molecule magnet with an S = 21/2 ground state
Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn{sup III}{sub 3}Mn{sup IV}O{sub 4}] core into a centrosymmetric [Mn{sup III}{sub 6}Mn{sup IV}O{sub 8}] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn{sub 4}O{sub 4}] cubane-based single-molecule magnets.
- Research Organization:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- AC02-07CH11358
- OSTI ID:
- 1044634
- Report Number(s):
- IS-J 7659
- Journal Information:
- Chemical Communications, Journal Name: Chemical Communications Journal Issue: 9 Vol. 48; ISSN 1359-7345
- Country of Publication:
- United States
- Language:
- English
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