CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTIS (BIS(TRIMETHYLSILYL)AMIDO]URANIUM(IV)
Journal Article
·
· Inorganic Chemistry
OSTI ID:1030601
New hydride derivatives of thorium (IV) and uranium (IV), HM[N(SiMe{sub 3}){sub 2}]{sub 3}, have recently been prepared. This paper describes the crystal structure of the uranium species, though the hydride-ion was not located, and shows that the thorium analogue is isostructural. The reaction chemistry and spectroscopy leave no doubt that these derivatives are authentic examples of four-coordinate, monomeric hydride, compounds.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- Materials Sciences Division
- DOE Contract Number:
- DE-AC02-05CH11231
- OSTI ID:
- 1030601
- Report Number(s):
- LBL-10489; INOCAJ; TRN: US201124%%348
- Journal Information:
- Inorganic Chemistry, Vol. 20, Issue 2; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:1030601