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Title: CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTIS (BIS(TRIMETHYLSILYL)AMIDO]URANIUM(IV)

Abstract

New hydride derivatives of thorium (IV) and uranium (IV), HM[N(SiMe{sub 3}){sub 2}]{sub 3}, have recently been prepared. This paper describes the crystal structure of the uranium species, though the hydride-ion was not located, and shows that the thorium analogue is isostructural. The reaction chemistry and spectroscopy leave no doubt that these derivatives are authentic examples of four-coordinate, monomeric hydride, compounds.

Authors:
; ;
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
Materials Sciences Division
OSTI Identifier:
1030601
Report Number(s):
LBL-10489
Journal ID: ISSN 0020-1669; INOCAJ; TRN: US201124%%348
DOE Contract Number:  
DE-AC02-05CH11231
Resource Type:
Journal Article
Journal Name:
Inorganic Chemistry
Additional Journal Information:
Journal Volume: 20; Journal Issue: 2; Journal ID: ISSN 0020-1669
Country of Publication:
United States
Language:
English
Subject:
99 GENERAL AND MISCELLANEOUS//MATHEMATICS, COMPUTING, AND INFORMATION SCIENCE; CHEMISTRY; CRYSTAL STRUCTURE; HYDRIDES; MOLECULAR STRUCTURE; SPECTROSCOPY; THORIUM; URANIUM

Citation Formats

Andersen, Richard A, Zalkin, Allen, and Templeton, David H. CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTIS (BIS(TRIMETHYLSILYL)AMIDO]URANIUM(IV). United States: N. p., 1980. Web.
Andersen, Richard A, Zalkin, Allen, & Templeton, David H. CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTIS (BIS(TRIMETHYLSILYL)AMIDO]URANIUM(IV). United States.
Andersen, Richard A, Zalkin, Allen, and Templeton, David H. 1980. "CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTIS (BIS(TRIMETHYLSILYL)AMIDO]URANIUM(IV)". United States. https://www.osti.gov/servlets/purl/1030601.
@article{osti_1030601,
title = {CRYSTAL AND MOLECULAR STRUCTURE OF HYDRIDOTIS (BIS(TRIMETHYLSILYL)AMIDO]URANIUM(IV)},
author = {Andersen, Richard A and Zalkin, Allen and Templeton, David H},
abstractNote = {New hydride derivatives of thorium (IV) and uranium (IV), HM[N(SiMe{sub 3}){sub 2}]{sub 3}, have recently been prepared. This paper describes the crystal structure of the uranium species, though the hydride-ion was not located, and shows that the thorium analogue is isostructural. The reaction chemistry and spectroscopy leave no doubt that these derivatives are authentic examples of four-coordinate, monomeric hydride, compounds.},
doi = {},
url = {https://www.osti.gov/biblio/1030601}, journal = {Inorganic Chemistry},
issn = {0020-1669},
number = 2,
volume = 20,
place = {United States},
year = {Thu May 01 00:00:00 EDT 1980},
month = {Thu May 01 00:00:00 EDT 1980}
}