Preparation and hydrogen-deuterium exchange of alkyl and hydride bis(trimethylsilyl)amido derivatives of the actinide elements
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
The monomeric, hydrocarbon-soluble monohydrides and monodeuterides of the actinide metals (thorium or uranium) of the type HM[N(SiMe3)2]3 have been prepared for this research. Their reaction chemistry, n-BuLi followed by MeBr yields MeM[N(SiMe3)2]3 and borane in tetrahydrofuran yields BH4M[N(SiMe3)2]3, suggests that the hydrogen atom is hydridic. Pyrolysis of the hydrides yields the novel, four-membered ring metallocycle [(Me3Si)2N]2MCH2Si(Me)2NSiMe3 where M is Th or U. In conclusion, these metallocycles are the key intermediates in the hydrogen-deuterium exchange reaction that yields {[(CD3)3Si]2N}3MD.
- Research Organization:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- DOE Contract Number:
- AC02-05CH11231; W-7405-ENG-48
- OSTI ID:
- 1077840
- Report Number(s):
- LBL--11609
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 9 Vol. 20; ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
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