Raman Spectroscopy of UH3 from the Hydrogen Corrosion of Uranium
Conference
·
OSTI ID:1018044
Hydrogen reacts with a uranium surface to form a fine, pyrophoric metal power (UH{sub 3}). Few spectroscopic studies have been conducted to study this reaction. Advances in Raman spectroscopy permit the application of the Raman method to formally difficult areas of chemistry such as the hydrogen corrosion of uranium: availability of multiple laser excitation wavelengths; fiber optics delivery and collection systems; upgraded instrumentation and detection techniques; and development of special enclosed in situ reactor cells. UH{sub 3} vibrations are expected to occur at low frequencies due to extended U-H-U structure.
- Research Organization:
- Oak Ridge Y-12 Plant (Y-12), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Defense Programs (DP)
- DOE Contract Number:
- AC05-00OR22800
- OSTI ID:
- 1018044
- Report Number(s):
- Y/DZ-3215
- Country of Publication:
- United States
- Language:
- English
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