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HYDROGEN CORROSION IN ORGANIC REACTOR COLLANTS. PART 2. HYDROGEN CORROSION OF URANIUM

Journal Article · · Corrosion
OSTI ID:4163025

Uranium was exposed to organic reactor coolants at temperatures up to 400 deg C under various conditions of constant hydrogen partial pressure and low water concentration. Uranium reacts with hydrogen to form uranium trinydride according to the rate law: rate = k(P -- P/sub D)/sup 2.5. The presence of the organic coolant reduces the rate to an eighth of the rate in dry hydrogen. At 375 deg C and above, UH/sub 3/ reacts with the organic coolant to form UC and in a confined system this reaction can result in an autocatalytic destruction of uranium. (auth)

Research Organization:
General Electric Co., Richland, Wash.
NSA Number:
NSA-14-016967
OSTI ID:
4163025
Journal Information:
Corrosion, Journal Name: Corrosion Vol. Vol: 16
Country of Publication:
Country unknown/Code not available
Language:
English

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