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Title: Low temperature production of large-grain polycrystalline semiconductors

Patent ·
OSTI ID:908831

An oxide or nitride layer is provided on an amorphous semiconductor layer prior to performing metal-induced crystallization of the semiconductor layer. The oxide or nitride layer facilitates conversion of the amorphous material into large grain polycrystalline material. Hence, a native silicon dioxide layer provided on hydrogenated amorphous silicon (a-Si:H), followed by deposited Al permits induced crystallization at temperatures far below the solid phase crystallization temperature of a-Si. Solar cells and thin film transistors can be prepared using this method.

Research Organization:
DOE/EPSCOR
Sponsoring Organization:
USDOE
DOE Contract Number:
0402-03027-21-0000
Assignee:
The Board of Trustees of the University of Arkansas (Little Rock, AR)
Patent Number(s):
7,202,143
Application Number:
10/972,760
OSTI ID:
908831
Country of Publication:
United States
Language:
English

References (16)

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Pd induced lateral crystallization of amorphous Si thin films journal March 1995
An investigation of laser annealed and metal-induced crystallized polycrystalline silicon thin-film transistors journal June 2001
Al-Induced Crystallization of an Amorphous Si Thin Film in a Polycrystalline Al/Native SiO 2 /Amorphous Si Structure journal April 1996
Characterization of the MIC/MILC interface and its effects on the performance of MILC thin-film transistors journal May 2000
Metal induced crystallization of amorphous silicon
  • Robertson, A. E.; Hultman, L. G.; Hentzell, H. T. G.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 5, Issue 4 https://doi.org/10.1116/1.574618
journal July 1987
Crystallization of silicon in aluminium/amorphous-silicon multilayers journal December 1992
Low temperature solid phase crystallization of amorphous silicon at 380 °C journal December 1998
Kinetics of solid phase interaction between Al and a ‐Si:H journal November 1994
Silicide mediated low temperature crystallization of hydrogenated amorphous silicon in contact with aluminum journal July 1995
Low temperature poly-Si thin-film transistor fabrication by metal-induced lateral crystallization journal April 1996
Back electrode formation for poly-Si thin film solar cells on glass having AIC-grown seeding layer journal October 2002
Interaction of aluminum with hydrogenated amorphous silicon at low temperatures journal April 1994
Influence of interface and Al structure on layer exchange during aluminum-induced crystallization of amorphous silicon journal July 2000
Surface morphology of poly-Si films made by aluminium-induced crystallisation on glass substrates journal July 2002