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Title: SULFUR POLYMER STABILIZATION/SOLIDIFICATION (SPSS) TREATABILITY OF SIMULATED MIXED-WASTE MERCURY CONTAMINATED SLUDGE.

Technical Report ·
DOI:https://doi.org/10.2172/791141· OSTI ID:791141

The Environmental Protection Agency (EPA) is currently seeking to validate technologies that can directly treat radioactively contaminated high mercury (Hg) subcategory wastes without removing the mercury from the waste. The Sulfur Polymer Stabilization/Solidification (SPSS) process developed at Brookhaven National Laboratory is one of several candidate technologies capable of successfully treating various Hg waste streams. To supplement previously supplied data on treatment of soils, EPA needs additional data concerning stabilization of high Hg subcategory waste sludges. To this end, a 5000 ppm sludge surrogate, containing approximately 50 wt% water, was successfully treated by pilot-scale SPSS processing. In two process runs, 85 and 95 wt% of water was recovered from the sludge during processing. At waste loadings of 30 wt% dry sludge, the treated waste form had no detectable mercury (<10 ppb) in TCLP leachates. Data gathered from the demonstration of treatment of this sludge will provide EPA with information to support revisions to current treatment requirements for high Hg subcategory wastes.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
ORNL/DOE/ER (US)
DOE Contract Number:
AC02-98CH10886
OSTI ID:
791141
Report Number(s):
BNL-52648; 4000008873; R&D Project: 86576; 4000008873; TRN: US0200576
Resource Relation:
Other Information: PBD: 1 Oct 2002
Country of Publication:
United States
Language:
English