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Title: Form-stable crystalline polymer pellets for thermal energy storage: high density polyethylene intermediate products. Final report, October 1, 1977--January 31, 1978

Technical Report ·
DOI:https://doi.org/10.2172/6675561· OSTI ID:6675561

The primary objectives of this program were to demonstrate: (1) that form-stable high density polyethylene (HDPE), which has been shown to have desirable properties as a phase-change type of thermal energy storage material, could be produced by processing in a polyethylene plant for a projected price near 26 cents/lb; and (2) that the raw material, ethylene, will be available in the very long-term from alternate sources (other than petroleum and natural gas). These objectives were accomplished. Production of useful, form-stable HDPE pellets by radiation cross-linking was demonstrated. Such pellets are estimated to be obtainable at 26 cents/lb, using large-volume (> or equal to 10,000,000 lb/yr) in-plant processing. Well-developed technologies exist for obtaining ethylene from coal and plant (or biomass) sources, thus assuring its long-term availability and therefore that of polyethylene. A cost-benefit analysis of the HDPE thermal energy storage system was conducted over its 120 to 140/sup 0/C optimum operating range which is most suited for absorption air conditioning. The HDPE is more cost effective than either rocks, ethylene glycol, or pressurized water and is even competitive with a hypothetical 5 cents/lb salt-hydrate melting in this temperature range. These results applied, as appropriate, to both air and liquid transfer systems.

Research Organization:
Monsanto Research Corp., Dayton, OH (USA). Dayton Lab.
DOE Contract Number:
W-7405-ENG-26
OSTI ID:
6675561
Report Number(s):
ORNL/SUB-7398/4; MRC-DA-760
Country of Publication:
United States
Language:
English