Pop plot and Arrhenius parameters for <110> pentaerythritol tetranitrate single crystals
Plane shock initiation sensitivity measurements for <110> single crystal pentaerythritol tetranitrate were extended to 20 GPa. The data of run distance versus input stress do not fall on the usual straight line on the Pop plot. From these data Arrhenius parameters were calculated. Computed activation energy was 6.4 kcal/mole, and the frequency factor was 5 x 10/sup 6//s. These are much lower than values obtained from isothermal heating experiments. These results can be used to support the idea that the uniaxial strain due to the shock leads to heterogeneous heating of the homogeneous material. 11 refs., 3 figs., 1 tab.
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- DOE Contract Number:
- W-7405-ENG-36
- OSTI ID:
- 5374013
- Report Number(s):
- LA-UR-85-2310; CONF-850736-49; ON: DE85015685
- Resource Relation:
- Conference: American Physical Society topical conference on shock waves in condensed matter, Spokane, WA, USA, 22 Jul 1985
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE
PETN
ACTIVATION ENERGY
SENSITIVITY
SHOCK WAVES
ARRHENIUS EQUATION
EXPERIMENTAL DATA
MONOCRYSTALS
STRAINS
STRESSES
VERY HIGH PRESSURE
CHEMICAL EXPLOSIVES
CRYSTALS
DATA
ENERGY
EQUATIONS
ESTERS
EXPLOSIVES
INFORMATION
NITRATES
NITRIC ACID ESTERS
NITROGEN COMPOUNDS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
450100* - Military Technology
Weaponry
& National Defense- Chemical Explosions & Explosives
PETN
ACTIVATION ENERGY
SENSITIVITY
SHOCK WAVES
ARRHENIUS EQUATION
EXPERIMENTAL DATA
MONOCRYSTALS
STRAINS
STRESSES
VERY HIGH PRESSURE
CHEMICAL EXPLOSIVES
CRYSTALS
DATA
ENERGY
EQUATIONS
ESTERS
EXPLOSIVES
INFORMATION
NITRATES
NITRIC ACID ESTERS
NITROGEN COMPOUNDS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
450100* - Military Technology
Weaponry
& National Defense- Chemical Explosions & Explosives