Spectroscopy of transition metal species in rare gas matrices. I. Vanadium metal. II. Sulfides. III. Carbonyl complexes. IV. Dinitrogen complexes. V. Homonuclear diatomic compounds

Thesis/Dissertation · Wed Oct 01 00:00:00 EDT 1975

DOI:https://doi.org/10.2172/5099999· OSTI ID:5099999

DeVore, Thomas Carroll ^[1]

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1. Iowa State Univ., Ames, IA (United States)

The spectrum of V isolated in Ar and Kr matrices at 10°K has been correlated with the gas phase spectrum. The electron configuration was found to be a major factor in determining the direction and the magnitude of the matrix shift for this system. A model calculation was performed using extended Huckel theory. A plausible explanation for the origin of the matrix shifts and the altered intensity relationships observed in the matrix has been developed.

• Research Organization: Ames Lab., Ames, IA (United States)
• Sponsoring Organization: US Energy Research and Development Administration (ERDA)
• DOE Contract Number: W-7405-ENG-82
• OSTI ID: 5099999
• Report Number(s): IS-T-686
• Resource Relation: Other Information: Thesis
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
INFRARED SPECTRA
ULTRAVIOLET SPECTRA
CHROMIUM COMPLEXES
CHROMIUM SULFIDES
ELECTRONIC STRUCTURE
IRON
ABSORPTION SPECTRA
IRON SULFIDES
MANGANESE
MANGANESE SULFIDES
NICKEL
NICKEL SULFIDES
NITROGEN COMPLEXES
TITANIUM SULFIDES
VANADIUM
VANADIUM COMPLEXES
VANADIUM COMPOUNDS
VANADIUM SULFIDES
ARGON
KRYPTON
ULTRALOW TEMPERATURE
CHALCOGENIDES
CHROMIUM COMPOUNDS
COMPLEXES
ELEMENTS
IRON COMPOUNDS
MANGANESE COMPOUNDS
METALS
NICKEL COMPOUNDS
NONMETALS
RARE GASES
SPECTRA
SULFIDES
SULFUR COMPOUNDS
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties