Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof

Li, Fanxing; Neal, Luke Michael; Gao, Yunfei; Yusuf, Seif; Dudek, Ryan

Title: Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof

Patent · Tue Nov 14 00:00:00 EST 2023

OSTI ID:2293854

Li, Fanxing; Neal, Luke Michael; Gao, Yunfei; Yusuf, Seif; Dudek, Ryan

Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region such as CaMnO₃, BaMnO_3−δ, SrMnO_3−δ, Mn₂SiO₄, Mn₂MgO_4−δ, La_0.8Sr_0.2O_3−δ, La_0.8Sr_0.2FeO_3−δ, Ca₉Ti_0.1Mn_0.9O_3−δ, Pr₆O_11−δ, manganese ore, or a combination thereof; and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region. The outer shell can include, for example a salt selected such as Li₂WO₄, Na₂WO₄, K₂WO₄, SrWO₄, Li₂MoO₄, Na₂MoO₄, K₂MoO₄, CsMoO₄, Li₂CO₃, Na₂CO₃, K₂CO₃, or a combination thereof.

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Research Organization:: North Carolina State University, Raleigh, NC (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); National Science Foundation (NSF)

DOE Contract Number:: AR0000327; 1254351

Assignee:: North Carolina State University (Raleigh, NC)

Patent Number(s):: 11,813,592

Application Number:: 16/622,627

OSTI ID:: 2293854

Resource Relation:: Patent File Date: 06/14/2018

Country of Publication:: United States

Language:: English

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