Catalysts and methods for forming alkenyl and alkyl substituted arenes

Gunnoe, Thomas B.; Vaughan, Benjamin Austin; Webster-Gardiner, Michael S.

Title: Catalysts and methods for forming alkenyl and alkyl substituted arenes

Patent · Tue Oct 03 00:00:00 EDT 2023

OSTI ID:2293682

Gunnoe, Thomas B.; Vaughan, Benjamin Austin; Webster-Gardiner, Michael S.

Embodiments of the present disclosure provide for Rh(I) catalysts, methods of making alkenyl substituted arenes (e.g., allyl arene, vinyl arene, and the like), methods of making alkyl substituted arenes, and the like.

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Research Organization:: Univ. of Virginia, Charlottesville, VA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0000776; SC0001298

Assignee:: University of Virginia Patent Foundation (Charlottesville, VA)

Patent Number(s):: 11,772,083

Application Number:: 17/188,535

OSTI ID:: 2293682

Resource Relation:: Patent File Date: 03/01/2021

Country of Publication:: United States

Language:: English

References (7)

A rhodium catalyst for single-step styrene production from benzene and ethylene Vaughan, B. A.; Webster-Gardiner, M. S.; Cundari, T. R. Science, Vol. 348, Issue 6233 https://doi.org/10.1126/science.aaa2260	journal	April 2015
Homogeneous catalysis in supercritical carbon dioxide with rhodium catalysts tethering fluoroacrylate polymer ligands Kani, Ibrahim; Omary, Mohammad A.; Rawashdeh-Omary, Manal A. Tetrahedron, Vol. 58, Issue 20 https://doi.org/10.1016/S0040-4020(02)00219-3	journal	May 2002
Arene C–H activation using Rh( i ) catalysts supported by bidentate nitrogen chelates Webster-Gardiner, Michael S.; Fu, Ross; Fortman, George C. Catalysis Science & Technology, Vol. 5, Issue 1 https://doi.org/10.1039/C4CY00972J	journal	January 2015
Process for preparation of substituted olefins Hong, Pangbu; Yamazaki, Hiroshi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4263212 US Patent Document 4,263,212	patent	April 1981
Exploring Oxidation of Half-Sandwich Rhodium Complexes: Oxygen Atom Insertion into the Rhodium–Carbon Bond of κ ² -Coordinated 2-Phenylpyridine Turlington, Christopher R.; Morris, James; White, Peter S. Organometallics, Vol. 33, Issue 17 https://doi.org/10.1021/om500660n	journal	August 2014
Oxidative coupling of olefins and aromatics using a rhodium catalyst and a copper(II) redox agent Taube, Douglas; Periana, Roy A.; Matsumoto, Takaya https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6127590 US Patent Document 6,127,590	patent	October 2000
Reductive Functionalization of a Rhodium(III)–Methyl Bond in Acidic Media: Key Step in the Electrophilic Functionalization of Methane O’Reilly, Matthew E.; Pahls, Dale R.; Cundari, Thomas R. Organometallics, Vol. 33, Issue 22 https://doi.org/10.1021/om5008456	journal	November 2014

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