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Title: Electrospinning of PVdF-HFP: novel composite polymer electrolytes (CPES) with enhanced ionic conductivities for lithium-sulfur batteries

Patent ·
OSTI ID:2222137

The invention relates to lithium ion batteries and, more particularly, to lithium ion conducting composite polymer electrolyte separators. The separators include a nanofiber mat composed of electrospun nanofibers. The nanofibers include a polymer having one or more polar halogen groups, a lithium-containing solid or liquid electrolyte and nanoparticle filler. The polymer, electrolyte and filler are combined to form a solution that is subjected to the electro-spinning process to produce electrospun nanofibers in the form of the mat.

Research Organization:
Univ. of Pittsburgh, PA (United States)
Sponsoring Organization:
USDOE; National Science Foundation (NSF)
DOE Contract Number:
EE0006825; CBET11511390
Assignee:
University of Pittsburgh - Of the Commonwealth System of Higher Education (Pittsburgh, PA)
Patent Number(s):
11,728,543
Application Number:
16/628,837
OSTI ID:
2222137
Resource Relation:
Patent File Date: 07/09/2018
Country of Publication:
United States
Language:
English

References (9)

Preparation of PVDF/SiO<sub>2</sub> Composite Nanofiber Membrane Using Electrospinning for Polymer Electrolyte Analysis journal January 2013
Porous Nano-Fiber Mats to Reinforce Proton Conducting Membranes for PEM Applications patent-application October 2013
Novel electrospun poly(vinylidene fluoride-co-hexafluoropropylene)–in situ SiO2 composite membrane-based polymer electrolyte for lithium batteries journal October 2008
Lithium secondary battery comprising a super fine fibrous polymer separator film and its fabrication method patent October 2007
Polypropylene-supported and nano-Al2O3 doped poly(ethylene oxide)–poly(vinylidene fluoride-hexafluoropropylene)-based gel electrolyte for lithium ion batteries journal February 2011
LITHIUM ION BATTERIES COMPRISING NANOFIBERS patent-application April 2015
Effect of Oxide Nanoparticles on Thermal and Mechanical Properties of Electrospun Separators for Lithium-Ion Batteries journal January 2012
Alkali Metal Secondary Battery Containing a Carbon Matrix- or Carbon Matrix Composite-based Dendrite-Intercepting Layer patent-application November 2016
High performance electrospun PVdF‐HFP/SiO2 nanocomposite membrane electrolyte for Li‐ion capacitors journal April 2017

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