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Title: Doping strategy for layered oxide electrode materials used in lithium-ion batteries

Patent ·
OSTI ID:2222134

The present invention features a new way of doping layered cathode materials in lithium ion batteries. Using a “high entropy” doping strategy, more than four impurity elements can be introduced to the host materials. The present invention applies this high entropy doping strategy to a high nickel content layered oxide material and a lithium-manganese rich material. This new high entropy doping strategy allows the layered oxide materials used in the positive electrode of lithium ion battery to achieve high energy density, long life cycle and reduced reliance on the expensive and toxic cobalt, all of which are desired attributes for improving the performance of lithium ion batteries and reducing their cost.

Research Organization:
Univ. of California, Irvine, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
EE0008444
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Number(s):
11,728,482
Application Number:
17/508,540
OSTI ID:
2222134
Resource Relation:
Patent File Date: 10/22/2021
Country of Publication:
United States
Language:
English

References (4)

Compositionally complex doping for zero-strain zero-cobalt layered cathodes journal September 2022
Solid state synthesis of lithium ion battery cathode material patent February 2009
Host Structural Stabilization of Li 1.232 Mn 0.615 Ni 0.154 O 2 through K-Doping Attempt: toward Superior Electrochemical Performances journal January 2016
Mitigating voltage and capacity fading of lithium-rich layered cathodes by lanthanum doping journal December 2016