Effect of Cationic (Na+) and Anionic (F–) Co-Doping on the Structural and Electrochemical Properties of LiNi1/3Mn1/3Co1/3O2 Cathode Material for Lithium-Ion Batteries

Wang, Hua; Hashem, Ahmed M.; Abdel-Ghany, Ashraf E.; Abbas, Somia M.; El-Tawil, Rasha S.; Li, Tianyi; Li, Xintong; El-Mounayri, Hazim; Tovar, Andres; Zhu, Likun; Mauger, Alain; Julien, Christian M.

doi:10.3390/ijms23126755

Title: Effect of Cationic (Na⁺) and Anionic (F^–) Co-Doping on the Structural and Electrochemical Properties of LiNi_1/3Mn_1/3Co_1/3O₂ Cathode Material for Lithium-Ion Batteries

Journal Article · Fri Jun 17 00:00:00 EDT 2022 · International Journal of Molecular Sciences (Online)

DOI:https://doi.org/10.3390/ijms23126755· OSTI ID:2217534

Wang, Hua ^[1]; Hashem, Ahmed M. ^[2];

^[2]; Abbas, Somia M. ^[2]; El-Tawil, Rasha S. ^[2];

^[3];

^[1]; El-Mounayri, Hazim ^[1];

^[1];

^[1]; Mauger, Alain ^[4];

^[4]

Indiana Univ.-Purdue Univ. Indianapolis (IUPUI), Indianapolis, IN (United States)
National Research Centre, Giza (Egypt)
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Centre National de la Recherche Scientifique (CNRS) (France); Sorbonne Univ., Paris (France)

Elemental doping for substituting lithium or oxygen sites has become a simple and effective technique to improve the electrochemical performance of layered cathode materials. Compared with single-element doping, this work presents an unprecedented contribution to the study of the effect of Na⁺/F^– co-doping on the structure and electrochemical performance of LiNi_1/3Mn_1/3Co_1/3O₂. The co-doped Li_1-zNa_zNi_1/3Mn_1/3Co_1/3O_2-zF_z (z = 0.025) and pristine LiNi_1/3Co_1/3Mn_1/3O₂ materials were synthesized via the sol–gel method using EDTA as a chelating agent. Structural analyses, carried out by X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy, revealed that the Na⁺ and F^– dopants were successfully incorporated into the Li and O sites, respectively. The co-doping resulted in larger Li-slab spacing, a lower degree of cation mixing, and the stabilization of the surface structure, which substantially enhanced the cycling stability and rate capability of the cathode material. The Na/F co-doped LiNi_1/3Mn_1/3Co_1/3O₂ electrode delivered an initial specific capacity of 142 mAh g^–1 at a 1C rate (178 mAh g^–1 at 0.1C), and it maintained 50% of its initial capacity after 1000 charge–discharge cycles at a 1C rate.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2217534

Journal Information:: International Journal of Molecular Sciences (Online), Vol. 23, Issue 12; ISSN 1422-0067

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Title: Effect of Cationic (Na+) and Anionic (F–) Co-Doping on the Structural and Electrochemical Properties of LiNi1/3Mn1/3Co1/3O2 Cathode Material for Lithium-Ion Batteries

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Title: Effect of Cationic (Na⁺) and Anionic (F^–) Co-Doping on the Structural and Electrochemical Properties of LiNi_1/3Mn_1/3Co_1/3O₂ Cathode Material for Lithium-Ion Batteries