P-V-T equation of state of boron carbide

Somayazulu, Maddury; Ahart, Muhtar; Meng, Yue; Ciezak, Jennifer; Velisavlevic, Nenad; Hemley, Russell J.

doi:10.1098/rsta.2022.0331

Title: P-V-T equation of state of boron carbide

Journal Article · Mon Aug 28 00:00:00 EDT 2023 · Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences

DOI:https://doi.org/10.1098/rsta.2022.0331· OSTI ID:2006510

^[1]; Ahart, Muhtar ^[2]; Meng, Yue ^[1]; Ciezak, Jennifer ^[3]; Velisavlevic, Nenad ^[4]; Hemley, Russell J. ^[2]

Argonne National Laboratory (ANL), Argonne, IL (United States)
University of Illinois, Chicago, IL (United States)
Army Research Laboratory, Aberdeen, MD (United States)
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

We report the P-V-T equation of state measurements of B₄C to 50 GPa and approximately 2500 K in laser-heated diamond anvil cells. We obtain an ambient temperature, third-order Birch–Murnaghan fit to the P-V data that yields a bulk modulus K₀ of 221(2) GPa and derivative, (dK/dP)₀ of 3.3(1). These were used in fits with both a Mie–Grüneisen–Debye model and a temperature-dependent, Birch–Murnaghan equation of state that includes thermal pressure estimated by thermal expansion (α) and a temperature-dependent bulk modulus (dK₀/dT). The ambient pressure thermal expansion coefficient (α₀ + α₁T), Grüneisen γ(V) = γ₀(V/V₀)^q and volume-dependent Debye temperature, were used as input parameters for these fits and found to be sufficient to describe the data in the whole P-T range of this study.

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Research Organization:: University of Illinois, Chicago, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF)

Grant/Contract Number:: NA0003975; AC02-06CH11357; AC52-07NA27344; DMR-2119308

OSTI ID:: 2006510

Journal Information:: Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences, Vol. 381, Issue 2258; ISSN 1364-503X

Publisher:: The Royal Society PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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P-V-T equation of state
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