Hydrophobic, Thermal Shock-and-Corrosion-Resistant XSBR Latex-Modified Lightweight Class G Cement Composites in Geothermal Well Energy Storage Systems

Sugama, Toshifumi; Pyatina, Tatiana

doi:10.3390/ma16175792

Title: Hydrophobic, Thermal Shock-and-Corrosion-Resistant XSBR Latex-Modified Lightweight Class G Cement Composites in Geothermal Well Energy Storage Systems

Journal Article · Thu Aug 24 00:00:00 EDT 2023 · Materials

DOI:https://doi.org/10.3390/ma16175792· OSTI ID:1997933

Sugama, Toshifumi ^[1]; Pyatina, Tatiana ^[1]

Brookhaven National Laboratory (BNL), Upton, NY (United States)

Energy losses can be significantly reduced if thermally insulating cement is used for energy storage and recovery. The thermal conductivity (TC) of the currently used cement is between 1 and 1.2 W/mK. In this study we assessed the ability of polystyrene (PS)–polybutadiene (PB)–polyacrylic acid (PAA) terpolymer (cross-linked styrene–butadiene rubber, XSBR) latex to improve thermal insulating properties and thermal shock (TS) resistance of class G ordinary Portland cement (OPC) and fly ash cenosphere (FCSs) composites in the temperature range of 100–175 °C. The composites autoclaved at 100 °C were subjected to three cycles, one cycle: 175 °C heat → 25 °C water quenching). In hydrothermal and thermal (TS) environments at elevated temperatures in cement slurries the XSBR latex formed acrylic calcium complexes through acid–base reactions, and the number of such complexes increased at higher temperatures due to the XSBR degradation with formation of additional acrylic groups. As a result, these complexes offered the following five advanced properties to the OPC-based composites: (1) enhanced hydrophobicity; (2) decreased water-fillable porosity; (3) reduced TC for water-saturated composites; (4) minimized loss of compressive strength, Young’s modulus, and compressive fracture toughness after TS; and (5) abated pozzolanic activity of FCSs, which allowed FCSs to persist as thermal insulators under strongly alkaline conditions of cement slurries. Additionally, XSBR-modified slurries possessed improved workability and decreased slurry density due to the air-entraining effect of latex, which resulted in further improvement of thermal insulation performance of the modified composites.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Geothermal Technologies Office

Grant/Contract Number:: SC0012704

OSTI ID:: 1997933

Report Number(s):: BNL-224739-2023-JAAM

Journal Information:: Materials, Vol. 16, Issue 17; ISSN 1996-1944

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Title: Hydrophobic, Thermal Shock-and-Corrosion-Resistant XSBR Latex-Modified Lightweight Class G Cement Composites in Geothermal Well Energy Storage Systems

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