Production of chemical products using electrochemical flow systems and mediators and associated methods

Murray, Alexander; Voskian, Sahag; Hatton, Trevor Alan; Surendranath, Yogesh

Title: Production of chemical products using electrochemical flow systems and mediators and associated methods

Patent · Tue Mar 14 00:00:00 EDT 2023

OSTI ID:1987219

Murray, Alexander; Voskian, Sahag; Hatton, Trevor Alan; Surendranath, Yogesh

Systems and methods for electrochemically producing chemical products are provided. In certain cases, the systems and methods described herein are capable of producing chemical products such as hydrogen peroxide in solutions with relatively low concentrations of electrolyte or other dissolved species at high efficiencies and/or low energetic cost. In some cases, redox mediators are used to spatially decouple direct electrochemical processes from the production of the chemical product.

View Patent

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: Massachusetts Institute of Technology (Cambridge, MA)

Patent Number(s):: 11,603,597

Application Number:: 16/450,847

OSTI ID:: 1987219

Resource Relation:: Patent File Date: 06/24/2019

Country of Publication:: United States

Language:: English

References (29)

Process for on-site production of ultra-high-purity hydrogen peroxide for the electronics industry Ledon, Henry; Guillard, Roger; Tabard, Alain https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6274114 US Patent Document 6,274,114	patent	August 2001
Applications of Transition-Metal Catalysts to Textile and Wood-Pulp Bleaching Hage, Ronald; Lienke, Achim Angewandte Chemie International Edition, Vol. 45, Issue 2 https://doi.org/10.1002/anie.200500525	journal	January 2006
Chemical Process Albers, Rolf Edvinsson; Rosvall, Magnus https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070012578 US Patent Application 11/477150; 20070012578	patent-application	January 2007
Erratum: Enabling direct H2O2 production through rational electrocatalyst design Siahrostami, Samira; Verdaguer-Casadevall, Arnau; Karamad, Mohammadreza Nature Materials, Vol. 13, Issue 2 https://doi.org/10.1038/nmat3871	journal	January 2014
Method of making hydrogen peroxide Kastening, Bertel; Schmitz, Heinrich https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4067787 US Patent Document 4,067,787	patent	January 1978
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2 Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10942	journal	March 2016
Decoupling hydrogen and oxygen evolution during electrolytic water splitting using an electron-coupled-proton buffer Symes, Mark D.; Cronin, Leroy Nature Chemistry, Vol. 5, Issue 5 https://doi.org/10.1038/nchem.1621	journal	April 2013
Polyanthraquinone as a Reliable Organic Electrode for Stable and Fast Lithium Storage Song, Zhiping; Qian, Yumin; Gordin, Mikhail L. Angewandte Chemie International Edition, Vol. 54, Issue 47 https://doi.org/10.1002/anie.201506673	journal	September 2015
Production of Chemical Products Using Electrochemical Flow Systems and Slug Flow and Associated Methods Voskian, Sahag; Murray, Alexander; Hatton, Trevor Alan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20200056298 US Patent Application 16/450859; 20200056298	patent-application	February 2020
Toward the Decentralized Electrochemical Production of H ₂ O ₂ : A Focus on the Catalysis Yang, Sungeun; Verdaguer-Casadevall, Arnau; Arnarson, Logi ACS Catalysis, Vol. 8, Issue 5 https://doi.org/10.1021/acscatal.8b00217	journal	March 2018
Alkaline Quinone Flow Battery with Long Lifetime at pH 12 Kwabi, David G.; Lin, Kaixiang; Ji, Yunlong Joule, Vol. 2, Issue 9 https://doi.org/10.1016/j.joule.2018.07.005	journal	September 2018
High-Yield Electrosynthesis of Hydrogen Peroxide from Oxygen Reduction by Hierarchically Porous Carbon Liu, Yanming; Quan, Xie; Fan, Xinfei Angewandte Chemie International Edition, Vol. 54, Issue 23 https://doi.org/10.1002/anie.201502396	journal	April 2015
Electrosynthesis of Hydrogen Peroxide by Phase-Transfer Catalysis Murray, Alexander T.; Voskian, Sahag; Schreier, Marcel Joule, Vol. 3, Issue 12 https://doi.org/10.1016/j.joule.2019.09.019	journal	December 2019
Recovering zinc from a material containing zinc and iron Reinhardt, Hans; Ottertun, Harald D.; Andersson, Sven https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4124462 US Patent Document 4,124,462	patent	November 1978
Cooperative Electrocatalytic O ₂ Reduction Involving Co(salophen) with p- Hydroquinone as an Electron–Proton Transfer Mediator Anson, Colin W.; Stahl, Shannon S. Journal of the American Chemical Society, Vol. 139, Issue 51 https://doi.org/10.1021/jacs.7b11362	journal	December 2017
Alloy Catalyst Metal Stephens, Ifan; Verdaguer-Casadevall, Arnau; Wickman, Bjorn https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160068973 US Patent Application 14/786,888; 2016/0068973	patent-application	March 2016
Electrochemical process for gas separation Voskian, Sahag; Hatton, Trevor Alan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170113182 US Patent Application 15/335258; 20170113182	patent-application	April 2017
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects Savéant, Jean-Michel Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378 https://doi.org/10.1021/cr068079z	journal	July 2008
Redox catalysis in organic electrosynthesis: basic principles and recent developments Francke, Robert; Little, R. Daniel Chemical Society Reviews, Vol. 43, Issue 8 https://doi.org/10.1039/c3cs60464k	journal	January 2014
Development of a reactor with carbon catalysts for modular-scale, low-cost electrochemical generation of H ₂ O ₂ Chen, Zhihua; Chen, Shucheng; Siahrostami, Samira Reaction Chemistry & Engineering, Vol. 2, Issue 2 https://doi.org/10.1039/C6RE00195E	journal	January 2017
A Bio-Inspired, Small Molecule Electron-Coupled-Proton Buffer for Decoupling the Half-Reactions of Electrolytic Water Splitting Rausch, Benjamin; Symes, Mark D.; Cronin, Leroy Journal of the American Chemical Society, Vol. 135, Issue 37 https://doi.org/10.1021/ja4071893	journal	September 2013
Chemical and Technical Aspects of Propene Oxide Production via Hydrogen Peroxide (HPPO Process) Russo, V.; Tesser, R.; Santacesaria, E. Industrial & Engineering Chemistry Research, Vol. 52, Issue 3 https://doi.org/10.1021/ie3023862	journal	January 2013
A metal-free organic–inorganic aqueous flow battery Huskinson, Brian; Marshak, Michael P.; Suh, Changwon Nature, Vol. 505, Issue 7482, p. 195-198 https://doi.org/10.1038/nature12909	journal	January 2014
A Model of a Phase Transfer Catalyst Liquid/Liquid Electrochemical Membrane Reactor Scott, K. Electrochemical Engineering and Energy https://doi.org/10.1007/978-1-4615-2514-1_21	book	January 1995
Advances in the direct synthesis of hydrogen peroxide from hydrogen and oxygen Edwards, Jennifer K.; Freakley, Simon J.; Lewis, Richard J. Catalysis Today, Vol. 248 https://doi.org/10.1016/j.cattod.2014.03.011	journal	June 2015
Manufacture of Hydrogen Peroxide Gustav, Adolph; Bretschger, Max E. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/2234908 US Patent Document 2234908	patent	March 1941
Poly(anthraquinone)s Having a .pi.-Conjugation System along the Main Chain. Synthesis by Organometallic Polycondensation, Redox Behavior, and Optical Properties Yamamoto, Takakazu; Etori, Hideki Macromolecules, Vol. 28, Issue 9 https://doi.org/10.1021/ma00113a042	journal	April 1995
A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities Kirkaldy, Niall; Chisholm, Greig; Chen, Jia-Jia Chemical Science, Vol. 9, Issue 6 https://doi.org/10.1039/C7SC05388F	journal	January 2018
Regenerative fuel cell with catholyte comprising a polyoxometalate and a vanadium (IV) - compound Knuckey, Kathryn; Kangati, Belloumi; Downs, Clare https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140004391 US Patent Application 13/996490; 20140004391	patent-application	January 2014

Similar Records

Production of chemical products using electrochemical flow systems and slug flow and associated methods

Patent · Tue Feb 01 00:00:00 EST 2022 · OSTI ID:1987219

Voskian, Sahag; Murray, Alexander; Hatton, Trevor Alan; +1 more

Electrochemically primed functional redox mediator generator from the decomposition of solid state electrolyte

Journal Article · Tue Apr 23 00:00:00 EDT 2019 · Nature Communications · OSTI ID:1987219

Li, Matthew; Bai, Zhengyu; Li, Yejing; +10 more

Tuning the Stability of Organic Active Materials for Nonaqueous Redox Flow Batteries via Reversible, Electrochemically Mediated Li ⁺ Coordination

Journal Article · Thu Mar 24 00:00:00 EDT 2016 · Chemistry of Materials · OSTI ID:1987219

Carino, Emily V.; Staszak-Jirkovsky, Jakub; Assary, Rajeev S.; +3 more

Title: Production of chemical products using electrochemical flow systems and mediators and associated methods

Citation Formats

References (29)

Similar Records

Related Subjects