skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Lithium ion battery cathode and anode materials as tunable and dynamically responsive support materials for single site heterogeneous catalysis

Patent ·
OSTI ID:1987101

A method of turning a catalytic material by altering the charge state of a catalyst support. The catalyst support is intercalated with a metal ion, altering the charge state to alter and/or augment the catalytic activity of the catalyst material.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Number(s):
11,571,684
Application Number:
17/077,630
OSTI ID:
1987101
Resource Relation:
Patent File Date: 10/22/2020
Country of Publication:
United States
Language:
English

References (57)

Positive electrode for non-aqueous electrolyte lithium secondary battery and method of manufacturing the same patent March 1997
Spinel-type lithium-manganese oxide containing heteroelements, preparation process and use thereof patent January 2001
Bimolecular Coupling as a Vector for Decomposition of Fast-Initiating Olefin Metathesis Catalysts journal April 2018
Well-Defined Surface Species [(≡Si—O—)W(═O)Me 3 ] Prepared by Direct Methylation of [(≡Si—O—)W(═O)Cl 3 ], a Catalyst for Cycloalkane Metathesis and Transformation of Ethylene to Propylene journal March 2015
Electrochemical tuning of layered lithium transition metal oxides for improvement of oxygen evolution reaction journal July 2014
Direct and continuous strain control of catalysts with tunable battery electrode materials journal November 2016
Method for Catalytic Reduction of Nitrogen Oxide Emissions patent-application September 2003
Method of Preparing a Material of a Battery Cell patent-application April 2021
Nickel--containing compounds useful as electrodes and method for preparing same patent May 1999
A Well-Defined Silica-Supported Tungsten Oxo Alkylidene Is a Highly Active Alkene Metathesis Catalyst journal December 2013
Surface Organometallic Chemistry: Paving the Way Beyond Well-Defined Supported Organometallics and Single-Site Catalysis journal July 2017
Upcycling Single-Use Polyethylene into High-Quality Liquid Products journal September 2019
Electrophilic Organoiridium(III) Pincer Complexes on Sulfated Zirconia for Hydrocarbon Activation and Functionalization journal March 2019
Electronically Modified Cobalt Aminopyridine Complexes Reveal an Orthogonal Axis for Catalytic Optimization for CO 2 Reduction journal August 2020
Single-site nickel-grafted anatase TiO 2 for hydrogen production: Toward understanding the nature of visible-light photocatalysis journal December 2014
Isolated, well-defined organovanadium( iii ) on silica: single-site catalyst for hydrogenation of alkenes and alkynes journal January 2017
The use of a well-defined surface organometallic complex as a probe molecule: [(SiO)Ta V Cl 2 Me 2 ] shows different isolated silanol sites on the silica surface journal January 2014
Design and synthesis of heterogeneous catalysts: the thermolytic molecular precursor approach journal May 2003
Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities journal January 2016
TiO 2 -supported Pt single atoms by surface organometallic chemistry for photocatalytic hydrogen evolution journal January 2019
Oxidative Addition of Carbon–Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex journal October 2012
Alkane Metathesis with the Tantalum Methylidene [(≡SiO)Ta(═CH 2 )Me 2 ]/[(≡SiO) 2 Ta(═CH 2 )Me] Generated from Well-Defined Surface Organometallic Complex [(≡SiO)Ta V Me 4 ] journal January 2015
Catalytic chemoselective functionalization of methane in a metal−organic framework journal May 2018
Electrochemical tuning of vertically aligned MoS2 nanofilms and its application in improving hydrogen evolution reaction journal November 2013
Lithium transition metal oxide patent November 1992
[(SiO)TaVCl2Me2]: A Well‐Defined Silica‐Supported Tantalum(V) Surface Complex as Catalyst Precursor for the Selective Cocatalyst‐Free Trimerization of Ethylene journal October 2012
WMe 6 Tamed by Silica: ≡Si–O–WMe 5 as an Efficient, Well-Defined Species for Alkane Metathesis, Leading to the Observation of a Supported W–Methyl/Methylidyne Species journal January 2014
Method of producing lithium ion cathode materials patent July 2009
Structures of paramagnetic Viv amido complexes grafted onto metal oxide surfaces: Model systems for heterogeneous vanadium catalysts journal March 2003
Zr(IV) surface sites determine CH3OH formation rate on Cu/ZrO2/SiO2 - CO2 hydrogenation catalysts journal November 2019
A Long-Lived Mononuclear Cyclopentadienyl Ruthenium Complex Grafted onto Anatase TiO 2 for Efficient CO 2 Photoreduction journal May 2016
A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts journal May 2012
Ethylene Hydrogenation over Pt/TiO 2 : A Charge-Sensitive Reaction journal February 2017
Evidence for Redox Mechanisms in Organometallic Chemisorption and Reactivity on Sulfated Metal Oxides journal April 2018
A Novel Redox Precipitation to Synthesize Au-Doped α-MnO 2 with High Dispersion toward Low-Temperature Oxidation of Formaldehyde journal March 2018
Well-Defined Silica-Supported Tungsten(IV)–Oxo Complex: Olefin Metathesis Activity, Initiation, and Role of Brønsted Acid Sites journal October 2019
Lithium manganese oxide compound and method of preparation patent August 1998
A molecular catalyst for water oxidation that binds to metal oxide surfaces journal March 2015
Nuclearity effects in supported, single-site Fe( ii ) hydrogenation pre-catalysts journal January 2018
Mechanistic Aspects of a Surface Organovanadium(III) Catalyst for Hydrocarbon Hydrogenation and Dehydrogenation journal November 2019
Enhanced Performance and Conversion Pathway for Catalytic Ozonation of Methyl Mercaptan on Single-Atom Ag Deposited Three-Dimensional Ordered Mesoporous MnO 2 journal October 2018
Activation of Low-Valent, Multiply M–M Bonded Group VI Dimers toward Catalytic Olefin Metathesis via Surface Organometallic Chemistry journal February 2020
Nontraditional Catalyst Supports in Surface Organometallic Chemistry journal September 2020
Combined action of metal and semiconductor catalysts journal June 1968
Surface organometallic chemistry: reaction of tris(allyl)rhodium with surfaces of silica, alumina, titania and magnesia journal May 1992
Formation of Gold Clusters on TiO 2 from Adsorbed Au(CH 3 ) 2 (C 5 H 7 O 2 ): Characterization by X-ray Absorption Spectroscopy journal May 2004
The Comparison between Single Atom Catalysis and Surface Organometallic Catalysis journal October 2019
Atomically Dispersed Iridium on Indium Tin Oxide Efficiently Catalyzes Water Oxidation journal July 2020
Synthesis and Electronic Structure of Cationic, Neutral, and Anionic Bis(imino)pyridine Iron Alkyl Complexes: Evaluation of Redox Activity in Single-Component Ethylene Polymerization Catalysts journal October 2010
Iron-Catalyzed [2π + 2π] Cycloaddition of α,ω-Dienes:  The Importance of Redox-Active Supporting Ligands journal October 2006
Low-Aspect-Ration Battery Cells patent-application November 2018
Atomically Precise Strategy to a PtZn Alloy Nanocluster Catalyst for the Deep Dehydrogenation of n -Butane to 1,3-Butadiene journal September 2018
Charge Transfer in Metal Catalysts Supported on Doped TiO2: A Theoretical Approach Based on Metal–Semiconductor Contact Theory journal July 1996
Reversible Carbon–Carbon Bond Formation Induced by Oxidation and Reduction at a Redox-Active Cobalt Complex journal April 2013
Process for preparing mixed metal oxides patent January 1986
PREPARATIONS OF TiO 2 -ATTACHED Rh CATALYSTS AND THEIR CATALYSIS journal April 1985
Bulky Aryloxide Ligand Stabilizes a Heterogeneous Metathesis Catalyst journal October 2014

Related Subjects