Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks

Long, Jeffrey R.; Keitz, Benjamin K.; Reed, Douglas

Title: Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks

Patent · Tue Dec 06 00:00:00 EST 2022

OSTI ID:1986889

Long, Jeffrey R.; Keitz, Benjamin K.; Reed, Douglas

An adsorbate-selective metal organic framework includes a transition metal; and a plurality of organic molecules coordinated to the transition metal so as to preserve open coordination sites for selectively adsorbing molecules that have low-lying π* orbitals. The transition metal has a lowest energy spin state in the presence of the selectively adsorbed molecules that are strongly bonding to the transition metal through π-donating interactions which is different than the lowest energy spin state in the absence of these adsorbed molecules. The transition metal has also a lowest energy spin state in the presence of non-selected molecules that are weakly bonding to the transition metal through σ- and/or π-accepting and/or donating interactions.

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Research Organization:: Univ. of California, Berkeley, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0001015

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Number(s):: 11,517,878

Application Number:: 16/089,199

OSTI ID:: 1986889

Resource Relation:: Patent File Date: 03/31/2017

Country of Publication:: United States

Language:: English

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