Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations

Long, Jeffrey R.; Milner, Phillip J.; Siegelman, Rebecca L.

Title: Amine-appended metal-organic frameworks exhibiting a new adsorption mechanism for carbon dioxide separations

Patent · Tue Oct 04 00:00:00 EDT 2022

OSTI ID:1986639

Long, Jeffrey R.; Milner, Phillip J.; Siegelman, Rebecca L.

An adsorption material is disclosed that comprises a metal-organic framework and a plurality of ligands. The metal-organic framework comprising a plurality of metal ions. Each respective ligand in the plurality of ligands is amine appended to a respective metal ion in the plurality of metal ions of the metal-organic framework. Each respective ligand in the plurality of ligands comprises a substituted 1,3-propanediamine. The adsorbent has a CO₂ adsorption capacity of greater than 2.50 mmol/g at 150 mbar CO₂ at 40° C. Moreover, the adsorbent is configured to regenerate at less than 120° C. An example ligand is diamine 2,2-dimethyl-1,3-propanediamine. An example of the metal-organic framework is Mg₂(dobpdc), where dobpdc⁴⁻ is 4,4′-dioxidobiphenyl-3,3′-dicarboxylate. Example applications for the adsorption material are removal of carbon dioxide from flue gas and biogasses.

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Research Organization:: Univ. of California, Berkeley, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0001015

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Number(s):: 11,458,431

Application Number:: 16/481,039

OSTI ID:: 1986639

Resource Relation:: Patent File Date: 02/17/2018

Country of Publication:: United States

Language:: English

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