Coupling, lifetimes, and “strong coupling” maps for single molecules at plasmonic interfaces

Mondal, Monosij; Ochoa, Maicol A.; Sukharev, Maxim; Nitzan, Abraham

doi:10.1063/5.0077739

Title: Coupling, lifetimes, and “strong coupling” maps for single molecules at plasmonic interfaces

Journal Article · Mon Apr 18 00:00:00 EDT 2022 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/5.0077739· OSTI ID:1982373

^[1];

^[2];

^[3]

Univ. of Pennsylvania, Philadelphia, PA (United States)
Arizona State Univ., Mesa, AZ (United States); Arizona State Univ., Tempe, AZ (United States)
Univ. of Pennsylvania, Philadelphia, PA (United States); Tel Aviv Univ., Tel Aviv (Israel)

The interaction between excited states of a molecule and excited states of a metal nanostructure (e.g., plasmons) leads to hybrid states with modified optical properties. When plasmon resonance is swept through molecular transition frequency, an avoided crossing may be observed, which is often regarded as a signature of strong coupling between plasmons and molecules. Such strong coupling is expected to be realized when 2|$$\langle$$U$$\rangle$$|/ℏΓ > 1, where $$\langle$$U$$\rangle$$ and Γ are the molecule–plasmon coupling and the spectral width of the optical transition, respectively. Because both $$\langle$$U$$\rangle$$ and Γ strongly increase with decreasing distance between a molecule and a plasmonic structure, it is not obvious that this condition can be satisfied for any molecule–metal surface distance. Here, in this work, we investigate the behavior of $$\langle$$U$$\rangle$$ and Γ for several geometries. Surprisingly, we find that if the only contributions to Γ are lifetime broadenings associated with the radiative and nonradiative relaxation of a single molecular vibronic transition, including effects on molecular radiative and nonradiative lifetimes induced by the metal, the criterion 2|$$\langle$$U$$\rangle$$|/ℏΓ > 1 is easily satisfied by many configurations irrespective of the metal–molecule distance. This implies that the Rabi splitting can be observed in such structures if other sources of broadening are suppressed. Additionally, when the molecule–metal surface distance is varied keeping all other molecular and metal parameters constant, this behavior is mitigated due to the spectral shift associated with the same molecule–plasmon interaction, making the observation of Rabi splitting more challenging.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: US Department of Energy (USDOE), Washington, DC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); US Air Force Office of Scientific Research (AFOSR); USDOE

Grant/Contract Number:: FA9550-19-1-0009

OSTI ID:: 1982373

Alternate ID(s):: OSTI ID: 1863470

Journal Information:: Journal of Chemical Physics, Vol. 156, Issue 15; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (105)

Meeting the Clean Energy Demand: Nanostructure Architectures for Solar Energy Conversion Kamat, Prashant V. The Journal of Physical Chemistry C, Vol. 111, Issue 7 https://doi.org/10.1021/jp066952u	journal	January 2007
Polariton-Mediated Electron Transfer via Cavity Quantum Electrodynamics Mandal, Arkajit; Krauss, Todd D.; Huo, Pengfei The Journal of Physical Chemistry B, Vol. 124, Issue 29 https://doi.org/10.1021/acs.jpcb.0c03227	journal	June 2020
Creating, characterizing, and controlling chemistry with SERS hot spots Kleinman, Samuel L.; Frontiera, Renee R.; Henry, Anne-Isabelle Phys. Chem. Chem. Phys., Vol. 15, Issue 1 https://doi.org/10.1039/c2cp42598j	journal	January 2013
Numerical Calculations of Radiative and Non-Radiative Relaxation of Molecules Near Metal Particles Sukharev, Maxim; Freifeld, Noa; Nitzan, Abraham The Journal of Physical Chemistry C, Vol. 118, Issue 20 https://doi.org/10.1021/jp4104245	journal	May 2014
Light-Harvesting and Amplified Energy Transfer in Conjugated Polymer Nanoparticles Jiang, Yifei; McNeill, Jason Chemical Reviews, Vol. 117, Issue 2 https://doi.org/10.1021/acs.chemrev.6b00419	journal	March 2016
Can Ultrastrong Coupling Change Ground-State Chemical Reactions? Martínez-Martínez, Luis A.; Ribeiro, Raphael F.; Campos-González-Angulo, Jorge ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b00610	journal	November 2017
Molecular polaritons for controlling chemistry with quantum optics Herrera, Felipe; Owrutsky, Jeffrey The Journal of Chemical Physics, Vol. 152, Issue 10 https://doi.org/10.1063/1.5136320	journal	March 2020
Theory of Nanoscale Organic Cavities: The Essential Role of Vibration-Photon Dressed States Herrera, Felipe; Spano, Frank C. ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b00728	journal	November 2017
Plasmon-induced resonance energy transfer for solar energy conversion Li, Jiangtian; Cushing, Scott K.; Meng, Fanke Nature Photonics, Vol. 9, Issue 9 https://doi.org/10.1038/nphoton.2015.142	journal	August 2015
Vacuum Rabi splitting in a plasmonic cavity at the single quantum emitter limit Santhosh, Kotni; Bitton, Ora; Chuntonov, Lev Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11823	journal	June 2016
Suppression of photo-oxidation of organic chromophores by strong coupling to plasmonic nanoantennas Munkhbat, Battulga; Wersäll, Martin; Baranov, Denis G. Science Advances, Vol. 4, Issue 7 https://doi.org/10.1126/sciadv.aas9552	journal	July 2018
Strong coupling as an interplay of quantum emitter hybridization with plasmonic dark and bright modes Rousseaux, Benjamin; Baranov, Denis G.; Antosiewicz, Tomasz J. Physical Review Research, Vol. 2, Issue 3 https://doi.org/10.1103/physrevresearch.2.033056	journal	July 2020
Near-field strong coupling of single quantum dots Groß, Heiko; Hamm, Joachim M.; Tufarelli, Tommaso Science Advances, Vol. 4, Issue 3 https://doi.org/10.1126/sciadv.aar4906	journal	March 2018
Dielectric Function for Gold in Plasmonics Applications: Size Dependence of Plasmon Resonance Frequencies and Damping Rates for Nanospheres Derkachova, Anastasiya; Kolwas, Krystyna; Demchenko, Iraida Plasmonics, Vol. 11, Issue 3 https://doi.org/10.1007/s11468-015-0128-7	journal	November 2015
Entanglement Detection in Coupled Particle Plasmons del Pino, Javier; Feist, Johannes; García-Vidal, F. J. Physical Review Letters, Vol. 112, Issue 21 https://doi.org/10.1103/physrevlett.112.216805	journal	May 2014
Strong coupling between a metallic nanoparticle and a single molecule Trügler, Andreas; Hohenester, Ulrich Physical Review B, Vol. 77, Issue 11 https://doi.org/10.1103/physrevb.77.115403	journal	March 2008
Towards femtosecond on-chip electronics based on plasmonic hot electron nano-emitters Karnetzky, Christoph; Zimmermann, Philipp; Trummer, Christopher Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04666-y	journal	June 2018
Polaritonic Chemistry with Organic Molecules Feist, Johannes; Galego, Javier; Garcia-Vidal, Francisco J. ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b00680	journal	October 2017
Light-matter interactions within the Ehrenfest–Maxwell–Pauli–Kohn–Sham framework: fundamentals, implementation, and nano-optical applications Jestädt, René; Ruggenthaler, Michael; Oliveira, Micael J. T. Advances in Physics, Vol. 68, Issue 4 https://doi.org/10.1080/00018732.2019.1695875	journal	October 2019
Plasmon-Enhanced Multicarrier Photocatalysis Shaik, Firdoz; Peer, Imanuel; Jain, Prashant K. Nano Letters, Vol. 18, Issue 7 https://doi.org/10.1021/acs.nanolett.8b01392	journal	June 2018
Plasmonic Cavity Coupling Hugall, James T.; Singh, Anshuman; van Hulst, Niek F. ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b01139	journal	November 2017
Cavity-assisted mesoscopic transport of fermions: Coherent and dissipative dynamics Hagenmüller, David; Schütz, Stefan; Schachenmayer, Johannes Physical Review B, Vol. 97, Issue 20 https://doi.org/10.1103/physrevb.97.205303	journal	May 2018
Optimal Dimensions of Gold Nanorod for Plasmonic Nanosensors Sekhon, Jagmeet Singh; Verma, S. S. Plasmonics, Vol. 6, Issue 1 https://doi.org/10.1007/s11468-010-9182-3	journal	October 2010
Optical Spectroscopy of Conductive Junctions in Plasmonic Cavities Pérez-González, O.; Zabala, N.; Borisov, A. G. Nano Letters, Vol. 10, Issue 8 https://doi.org/10.1021/nl1017173	journal	August 2010
Enhanced water splitting under modal strong coupling conditions Shi, Xu; Ueno, Kosei; Oshikiri, Tomoya Nature Nanotechnology, Vol. 13, Issue 10 https://doi.org/10.1038/s41565-018-0208-x	journal	July 2018
Nanopolaritons: Vacuum Rabi Splitting with a Single Quantum Dot in the Center of a Dimer Nanoantenna Savasta, Salvatore; Saija, Rosalba; Ridolfo, Alessandro ACS Nano, Vol. 4, Issue 11 https://doi.org/10.1021/nn100585h	journal	October 2010
Ab initio polaritonic potential-energy surfaces for excited-state nanophotonics and polaritonic chemistry Flick, Johannes; Narang, Prineha The Journal of Chemical Physics, Vol. 153, Issue 9 https://doi.org/10.1063/5.0021033	journal	September 2020
Plasmon-Driven Catalysis on Molecules and Nanomaterials Zhang, Zhenglong; Zhang, Chengyun; Zheng, Hairong Accounts of Chemical Research, Vol. 52, Issue 9 https://doi.org/10.1021/acs.accounts.9b00224	journal	August 2019
Principles of Nano-Optics Novotny, Lukas; Hecht, Bert Cambridge University Press https://doi.org/10.1017/CBO9780511813535	book	January 2006
Electron transfer in confined electromagnetic fields Semenov, Alexander; Nitzan, Abraham The Journal of Chemical Physics, Vol. 150, Issue 17 https://doi.org/10.1063/1.5095940	journal	May 2019
Long-distance operator for energy transfer Garcia-Vidal, Francisco J.; Feist, Johannes Science, Vol. 357, Issue 6358 https://doi.org/10.1126/science.aao4268	journal	September 2017
Size-Dependent Coupling of Hybrid Core–Shell Nanorods: Toward Single-Emitter Strong-Coupling Stete, Felix; Schoßau, Phillip; Bargheer, Matias The Journal of Physical Chemistry C, Vol. 122, Issue 31 https://doi.org/10.1021/acs.jpcc.8b04204	journal	July 2018
Nanoplasmonics for chemistry Baffou, Guillaume; Quidant, Romain Chemical Society Reviews, Vol. 43, Issue 11 https://doi.org/10.1039/c3cs60364d	journal	January 2014
Plasmonic Control of Multi-Electron Transfer and C–C Coupling in Visible-Light-Driven CO ₂ Reduction on Au Nanoparticles Yu, Sungju; Wilson, Andrew J.; Heo, Jaeyoung Nano Letters, Vol. 18, Issue 4 https://doi.org/10.1021/acs.nanolett.7b05410	journal	February 2018
Optimizing Brownian escape rates by potential shaping Chupeau, Marie; Gladrow, Jannes; Chepelianskii, Alexei Proceedings of the National Academy of Sciences, Vol. 117, Issue 3 https://doi.org/10.1073/pnas.1910677116	journal	December 2019
Phonon heat transport in cavity-mediated optomechanical nanoresonators Yang, Cheng; Wei, Xinrui; Sheng, Jiteng Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18426-4	journal	September 2020
Nanoplasmonics: past, present, and glimpse into future Stockman, Mark I. Optics Express, Vol. 19, Issue 22 https://doi.org/10.1364/oe.19.022029	journal	January 2011
Nano-Optical Tweezing of Single Proteins in Plasmonic Nanopores Verschueren, Daniel; Shi, Xin; Dekker, Cees Small Methods, Vol. 3, Issue 5 https://doi.org/10.1002/smtd.201800465	journal	January 2019
Plasmonic Nanosensors: Review and Prospect Choi, Inhee; Choi, Yeonho IEEE Journal of Selected Topics in Quantum Electronics, Vol. 18, Issue 3 https://doi.org/10.1109/jstqe.2011.2163386	journal	May 2012
Study on spontaneous emission in complex multilayered plasmonic system via surface integral equation approach with layered medium Green’s function Chen, Yongpin P.; Sha, Wei E. I.; Choy, Wallace C. H. Optics Express, Vol. 20, Issue 18 https://doi.org/10.1364/oe.20.020210	journal	January 2012
Lifetime of an emitting dipole near various types of interfaces including magnetic and negative refractive materials Ruppin, Raphael; Martin, Olivier J. F. The Journal of Chemical Physics, Vol. 121, Issue 22 https://doi.org/10.1063/1.1812742	journal	January 2004
Strong coupling between surface plasmon polaritons and emitters: a review Törmä, P.; Barnes, W. L. Reports on Progress in Physics, Vol. 78, Issue 1 https://doi.org/10.1088/0034-4885/78/1/013901	journal	December 2014
Quantum Emitters Near a Metal Nanoparticle: Strong Coupling and Quenching Delga, A.; Feist, J.; Bravo-Abad, J. Physical Review Letters, Vol. 112, Issue 25 https://doi.org/10.1103/physrevlett.112.253601	journal	June 2014
Polariton chemistry: Thinking inside the (photon) box Yuen-Zhou, Joel; Menon, Vinod M. Proceedings of the National Academy of Sciences, Vol. 116, Issue 12 https://doi.org/10.1073/pnas.1900795116	journal	March 2019
Photocatalytic reduction of p-nitrophenol over plasmonic M (M = Ag, Au)/SnNb2O6 nanosheets Wu, Junshu; Wang, Jinshu; Wang, Tianning Applied Surface Science, Vol. 466 https://doi.org/10.1016/j.apsusc.2018.09.222	journal	February 2019
Ultrastrong coupling between light and matter Frisk Kockum, Anton; Miranowicz, Adam; De Liberato, Simone Nature Reviews Physics, Vol. 1, Issue 1 https://doi.org/10.1038/s42254-018-0006-2	journal	January 2019
Non-adiabatic dynamics of molecules in optical cavities Kowalewski, Markus; Bennett, Kochise; Mukamel, Shaul The Journal of Chemical Physics, Vol. 144, Issue 5 https://doi.org/10.1063/1.4941053	journal	February 2016
Remote Control of Chemistry in Optical Cavities Du, Matthew; Ribeiro, Raphael F.; Yuen-Zhou, Joel Chem, Vol. 5, Issue 5 https://doi.org/10.1016/j.chempr.2019.02.009	journal	May 2019
Self-Optimized Catalysts: Hot-Electron Driven Photosynthesis of Catalytic Photocathodes Kontoleta, Evgenia; Askes, Sven H. C.; Garnett, Erik C. ACS Applied Materials & Interfaces, Vol. 11, Issue 39 https://doi.org/10.1021/acsami.9b10913	journal	September 2019
Plasmon–Exciton Coupling in Photosystem I Based Biohybrid Photoelectrochemical Cells Zeng, Zheng; Mabe, Taylor; Zhang, Wendi ACS Applied Bio Materials, Vol. 1, Issue 3 https://doi.org/10.1021/acsabm.8b00249	journal	August 2018
Quantum Control of Ultrafast Internal Conversion Using Nanoconfined Virtual Photons Avramenko, Aleksandr G.; Rury, Aaron S. The Journal of Physical Chemistry Letters, Vol. 11, Issue 3 https://doi.org/10.1021/acs.jpclett.9b03447	journal	January 2020
Tilting a ground-state reactivity landscape by vibrational strong coupling Thomas, A.; Lethuillier-Karl, L.; Nagarajan, K. Science, Vol. 363, Issue 6427 https://doi.org/10.1126/science.aau7742	journal	February 2019
Few-Molecule Strong Coupling with Dimers of Plasmonic Nanoparticles Assembled on DNA Heintz, Jeanne; Markešević, Nemanja; Gayet, Elise Y. ACS Nano, Vol. 15, Issue 9 https://doi.org/10.1021/acsnano.1c04552	journal	September 2021
Can photochemistry be enhanced on rough surfaces? Nitzan, Abraham; Brus, L. E. The Journal of Chemical Physics, Vol. 74, Issue 9 https://doi.org/10.1063/1.441699	journal	May 1981
Selective Branching of Plasmonic Photosynthesis into Hydrocarbon Production and Hydrogen Generation Yu, Sungju; Jain, Prashant K. ACS Energy Letters, Vol. 4, Issue 9 https://doi.org/10.1021/acsenergylett.9b01688	journal	August 2019
Revisiting strong coupling between a single molecule and surface plasmons Dvoynenko, Mykhaylo M.; Wang, Juen-Kai Optics Letters, Vol. 38, Issue 5 https://doi.org/10.1364/ol.38.000760	journal	January 2013
Colloidal Nanodisk Shaped Plexcitonic Nanoparticles with Large Rabi Splitting Energies Balci, Fadime Mert; Sarisozen, Sema; Polat, Nahit The Journal of Physical Chemistry C, Vol. 123, Issue 43 https://doi.org/10.1021/acs.jpcc.9b08834	journal	October 2019
Strong Light–Matter Interaction in Quantum Emitter/Metal Hybrid Nanostructures Vasa, Parinda; Lienau, Christoph ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b00650	journal	October 2017
Electronic Structure Effects in the Coupling of a Single Molecule with a Plasmonic Antenna Aguilar-Galindo, Fernando; Díaz-Tendero, Sergio; Borisov, Andrei G. The Journal of Physical Chemistry C, Vol. 123, Issue 7 https://doi.org/10.1021/acs.jpcc.8b11872	journal	January 2019
Surface plasmon lifetime in metal nanoshells Kirakosyan, Arman S.; Stockman, Mark I.; Shahbazyan, Tigran V. Physical Review B, Vol. 94, Issue 15 https://doi.org/10.1103/physrevb.94.155429	journal	October 2016
Surface plasmon subwavelength optics Barnes, William L.; Dereux, Alain; Ebbesen, Thomas W. Nature, Vol. 424, Issue 6950, p. 824-830 https://doi.org/10.1038/nature01937	journal	August 2003
Plasmonic tunnel junctions for single-molecule redox chemistry de Nijs, Bart; Benz, Felix; Barrow, Steven J. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00819-7	journal	October 2017
Light–Matter Coupling Strength Controlled by the Orientation of Organic Crystals in Plasmonic Cavities Berghuis, Anton Matthijs; Serpenti, Vincent; Ramezani, Mohammad The Journal of Physical Chemistry C, Vol. 124, Issue 22 https://doi.org/10.1021/acs.jpcc.0c00692	journal	May 2020
Cascaded nanooptics to probe microsecond atomic-scale phenomena Kamp, Marlous; de Nijs, Bart; Kongsuwan, Nuttawut Proceedings of the National Academy of Sciences, Vol. 117, Issue 26 https://doi.org/10.1073/pnas.1920091117	journal	June 2020
Atoms and molecules in cavities, from weak to strong coupling in quantum-electrodynamics (QED) chemistry Flick, Johannes; Ruggenthaler, Michael; Appel, Heiko Proceedings of the National Academy of Sciences, Vol. 114, Issue 12 https://doi.org/10.1073/pnas.1615509114	journal	March 2017
Plasmon-enhanced photo(electro)chemical nitrogen fixation under ambient conditions using visible light responsive hybrid hollow Au-Ag2O nanocages Nazemi, Mohammadreza; El-Sayed, Mostafa A. Nano Energy, Vol. 63 https://doi.org/10.1016/j.nanoen.2019.103886	journal	September 2019
Energy transfer in plasmonic systems Pustovit, Vitaliy N.; Urbas, Augustine M.; Shahbazyan, Tigran V. Journal of Optics, Vol. 16, Issue 11 https://doi.org/10.1088/2040-8978/16/11/114015	journal	November 2014
Cavity Femtochemistry: Manipulating Nonadiabatic Dynamics at Avoided Crossings Kowalewski, Markus; Bennett, Kochise; Mukamel, Shaul The Journal of Physical Chemistry Letters, Vol. 7, Issue 11 https://doi.org/10.1021/acs.jpclett.6b00864	journal	May 2016
Cavity Catalysis by Cooperative Vibrational Strong Coupling of Reactant and Solvent Molecules Lather, Jyoti; Bhatt, Pooja; Thomas, Anoop Angewandte Chemie International Edition, Vol. 58, Issue 31 https://doi.org/10.1002/anie.201905407	journal	July 2019
Cavity-Enhanced Transport of Charge Hagenmüller, David; Schachenmayer, Johannes; Schütz, Stefan Physical Review Letters, Vol. 119, Issue 22 https://doi.org/10.1103/PhysRevLett.119.223601	journal	November 2017
Surface-Plasmon-Driven Hot Electron Photochemistry Zhang, Yuchao; He, Shuai; Guo, Wenxiao Chemical Reviews, Vol. 118, Issue 6 https://doi.org/10.1021/acs.chemrev.7b00430	journal	November 2017
Tip-enhanced strong coupling spectroscopy, imaging, and control of a single quantum emitter Park, Kyoung-Duck; May, Molly A.; Leng, Haixu Science Advances, Vol. 5, Issue 7 https://doi.org/10.1126/sciadv.aav5931	journal	July 2019
Dispersion and shape engineered plasmonic nanosensors Jeong, Hyeon-Ho; Mark, Andrew G.; Alarcón-Correa, Mariana Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11331	journal	April 2016
Modifying Chemical Landscapes by Coupling to Vacuum Fields Hutchison, James A.; Schwartz, Tal; Genet, Cyriaque Angewandte Chemie International Edition, Vol. 51, Issue 7 https://doi.org/10.1002/anie.201107033	journal	January 2012
Long-Range Transport of Organic Exciton-Polaritons Revealed by Ultrafast Microscopy Rozenman, Georgi Gary; Akulov, Katherine; Golombek, Adina ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b01332	journal	November 2017
Spectroscopic properties of molecules interacting with small dielectric particles Gersten, Joel; Nitzan, Abraham The Journal of Chemical Physics, Vol. 75, Issue 3 https://doi.org/10.1063/1.442161	journal	August 1981
Plasmon-Driven Reaction Mechanisms: Hot Electron Transfer versus Plasmon-Pumped Adsorbate Excitation Tesema, Tefera E.; Kafle, Bijesh; Habteyes, Terefe G. The Journal of Physical Chemistry C, Vol. 123, Issue 14 https://doi.org/10.1021/acs.jpcc.8b12054	journal	February 2019
Coherent Light Harvesting through Strong Coupling to Confined Light Groenhof, Gerrit; Toppari, J. Jussi The Journal of Physical Chemistry Letters, Vol. 9, Issue 17 https://doi.org/10.1021/acs.jpclett.8b02032	journal	August 2018
Single-molecule strong coupling at room temperature in plasmonic nanocavities Chikkaraddy, Rohit; de Nijs, Bart; Benz, Felix Nature, Vol. 535, Issue 7610 https://doi.org/10.1038/nature17974	journal	June 2016
Hot spots in different metal nanostructures for plasmon-enhanced Raman spectroscopy Wei, Hong; Xu, Hongxing Nanoscale, Vol. 5, Issue 22 https://doi.org/10.1039/c3nr02924g	journal	January 2013
Optical dielectric function of silver Yang, Honghua U.; D'Archangel, Jeffrey; Sundheimer, Michael L. Physical Review B, Vol. 91, Issue 23 https://doi.org/10.1103/physrevb.91.235137	journal	June 2015
Polariton panorama Basov, D. N.; Asenjo-Garcia, Ana; Schuck, P. James Nanophotonics, Vol. 10, Issue 1 https://doi.org/10.1515/nanoph-2020-0449	journal	November 2020
Atom Assisted Photochemistry in Optical Cavities Davidsson, Eric; Kowalewski, Markus The Journal of Physical Chemistry A, Vol. 124, Issue 23 https://doi.org/10.1021/acs.jpca.0c03867	journal	May 2020
Coupling of Molecular Emitters and Plasmonic Cavities beyond the Point-Dipole Approximation Neuman, Tomáš; Esteban, Ruben; Casanova, David Nano Letters, Vol. 18, Issue 4 https://doi.org/10.1021/acs.nanolett.7b05297	journal	March 2018
Hybrid nanostructures for efficient light harvesting Mackowski, Sebastian Journal of Physics: Condensed Matter, Vol. 22, Issue 19 https://doi.org/10.1088/0953-8984/22/19/193102	journal	April 2010
Resonant catalysis of thermally activated chemical reactions with vibrational polaritons Campos-Gonzalez-Angulo, Jorge A.; Ribeiro, Raphael F.; Yuen-Zhou, Joel Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12636-1	journal	October 2019
Strong Coupling with Light Enhances the Photoisomerization Quantum Yield of Azobenzene Fregoni, Jacopo; Granucci, Giovanni; Persico, Maurizio Chem, Vol. 6, Issue 1 https://doi.org/10.1016/j.chempr.2019.11.001	journal	January 2020
Plasmon-mediated superradiance near metal nanostructures Pustovit, Vitaliy N.; Shahbazyan, Tigran V. Physical Review B, Vol. 82, Issue 7 https://doi.org/10.1103/physrevb.82.075429	journal	August 2010
Quantum electrodynamics in the presence of dielectrics and conductors. IV. General theory for spontaneous emission in finite geometries Agarwal, G. S. Physical Review A, Vol. 12, Issue 4 https://doi.org/10.1103/physreva.12.1475	journal	October 1975
Investigating New Reactivities Enabled by Polariton Photochemistry Mandal, Arkajit; Huo, Pengfei The Journal of Physical Chemistry Letters, Vol. 10, Issue 18 https://doi.org/10.1021/acs.jpclett.9b01599	journal	August 2019
Overcoming quantum decoherence with plasmonics Bogdanov, Simeon I.; Boltasseva, Alexandra; Shalaev, Vladimir M. Science, Vol. 364, Issue 6440 https://doi.org/10.1126/science.aax3766	journal	May 2019
Applications of Plasmon-Enhanced Nanocatalysis to Organic Transformations Gellé, Alexandra; Jin, Tony; de la Garza, Luis Chemical Reviews, Vol. 120, Issue 2 https://doi.org/10.1021/acs.chemrev.9b00187	journal	November 2019
Suppressed Quenching and Strong-Coupling of Purcell-Enhanced Single-Molecule Emission in Plasmonic Nanocavities Kongsuwan, Nuttawut; Demetriadou, Angela; Chikkaraddy, Rohit ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b00668	journal	November 2017
Theoretical model for enhanced photochemistry on rough surfaces Nitzan, Abraham; Brus, L. E. The Journal of Chemical Physics, Vol. 75, Issue 5 https://doi.org/10.1063/1.442333	journal	September 1981
Hybrid Light–Matter States in a Molecular and Material Science Perspective Ebbesen, Thomas W. Accounts of Chemical Research, Vol. 49, Issue 11 https://doi.org/10.1021/acs.accounts.6b00295	journal	October 2016
Single Turnover Measurements of Nanoparticle Catalysis Analyzed with Dwell Time Correlation Functions and Constrained Mean Dwell Times Ochoa, Maicol A.; Chen, Peng; Loring, Roger F. The Journal of Physical Chemistry C, Vol. 117, Issue 37 https://doi.org/10.1021/jp4065246	journal	September 2013
Plasmonic hot carrier dynamics in solid-state and chemical systems for energy conversion Narang, Prineha; Sundararaman, Ravishankar; Atwater, Harry A. Nanophotonics, Vol. 5, Issue 1 https://doi.org/10.1515/nanoph-2016-0007	journal	January 2016
Ground-State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field Thomas, Anoop; George, Jino; Shalabney, Atef Angewandte Chemie International Edition, Vol. 55, Issue 38 https://doi.org/10.1002/anie.201605504	journal	August 2016
Plasmons in Strongly Coupled Metallic Nanostructures Halas, Naomi J.; Lal, Surbhi; Chang, Wei-Shun Chemical Reviews, Vol. 111, Issue 6 https://doi.org/10.1021/cr200061k	journal	June 2011
Effect of surface-plasmon polaritons on spontaneous emission and intermolecular energy-transfer rates in multilayered geometries Marocico, C. A.; Knoester, J. Physical Review A, Vol. 84, Issue 5 https://doi.org/10.1103/physreva.84.053824	journal	November 2011
Single-Molecule Vacuum Rabi Splitting: Four-Wave Mixing and Optical Switching at the Single-Photon Level Pscherer, André; Meierhofer, Manuel; Wang, Daqing Physical Review Letters, Vol. 127, Issue 13 https://doi.org/10.1103/physrevlett.127.133603	journal	September 2021
Synergy between Plasmonic and Electrocatalytic Activation of Methanol Oxidation on Palladium–Silver Alloy Nanotubes Huang, Lin; Zou, Jiasui; Ye, Jin‐Yu Angewandte Chemie, Vol. 131, Issue 26 https://doi.org/10.1002/ange.201903290	journal	May 2019
Application of Nanoparticle Antioxidants to Enable Hyperstable Chloroplasts for Solar Energy Harvesting Boghossian, Ardemis A.; Sen, Fatih; Gibbons, Brenna M. Advanced Energy Materials, Vol. 3, Issue 7 https://doi.org/10.1002/aenm.201201014	journal	March 2013
Nanooptics of Molecular-Shunted Plasmonic Nanojunctions Benz, Felix; Tserkezis, Christos; Herrmann, Lars O. Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl5041786	journal	December 2014
Nanooptics of Plasmonic Nanomatryoshkas: Shrinking the Size of a Core–Shell Junction to Subnanometer Lin, Li; Zapata, Mario; Xiong, Min Nano Letters, Vol. 15, Issue 10 https://doi.org/10.1021/acs.nanolett.5b02931	journal	September 2015

Similar Records

Observing pre-edge

K

-shell resonances in Kr, Xe, and

{XeF}_{2}

Journal Article · Fri Aug 09 00:00:00 EDT 2019 · Physical Review A · OSTI ID:1982373

Southworth, S. H.; Dunford, R. W.; Ray, D.; +11 more

Formation of Bound States in the Continuum in Hybrid Plasmonic-Photonic Systems

Journal Article · Thu Dec 20 00:00:00 EST 2018 · Physical Review Letters · OSTI ID:1982373

Azzam, Shaimaa I.; Shalaev, Vladimir M.; Boltasseva, Alexandra; +1 more

Optical absorption and luminescence spectroscopy of U{sup 3+} in K{sub 2}La{ital X}{sub 5} ({ital X}=Cl,Br,I)

Journal Article · Thu Aug 01 00:00:00 EDT 1996 · Physical Review, B: Condensed Matter · OSTI ID:1982373

Andres, H P; Kraemer, K; Guedel, H

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Plasmonics
Atomic spectral lines
Nanomaterials
Nanoparticle
Metal nanostructure
Vibronic transitions

Title: Coupling, lifetimes, and “strong coupling” maps for single molecules at plasmonic interfaces

Citation Formats

References (105)

Similar Records

Related Subjects