Directly Spun Epoxy-Crosslinked Polyethylenimine Fiber Sorbents for Direct Air Capture and Postcombustion Capture of CO2

Wilfong, Walter C.; Wang, Qiuming; Ji, Tuo; Baker, James S.; Shi, Fan; Yi, Shouliang; Gray, McMahan L.

doi:10.1002/ente.202200356

Title: Directly Spun Epoxy-Crosslinked Polyethylenimine Fiber Sorbents for Direct Air Capture and Postcombustion Capture of CO₂

Journal Article · Thu Jun 30 00:00:00 EDT 2022 · Energy Technology

DOI:https://doi.org/10.1002/ente.202200356· OSTI ID:1981411

^[1]; Wang, Qiuming ^[1]; Ji, Tuo ^[1]; Baker, James S. ^[1]; Shi, Fan ^[2]; Yi, Shouliang ^[1]; Gray, McMahan L. ^[2]

National Energy Technology Laboratory (NETL), Pittsburgh, PA (United States); NETL Support Contractor, Pittsburgh, PA (United States)
National Energy Technology Laboratory (NETL), Pittsburgh, PA (United States)

A novel, directly‐injected solid fiber sorbent is synthesized from a solvent‐stable, epoxy‐crosslinked basic immobilized amine sorbent (BIAS) for CO ₂ capture. Leach resistance of the BIAS organics toward 1‐methyl‐2‐pyrrolidone/H ₂ O (90/10, fiber solvent) reaches near 100% at the expense of CO ₂ capture and is achieved by increasing the extent of crosslinking. The optimized fiber sorbent, prepared with an N,N‐diglycidyl‐4‐glycidyloxyaniline/polyethylenimine (PEI)‐0.35/1 wt. ratio, retains 79.2% of PEI and captures 0.37 (direct air capture [DAC]) and 0.67 (postcombustion) mmol CO ₂ g‐fiber ⁻¹ . A nonoptimized prototype hollow fiber exhibits a stable 0.2 mmol CO ₂ g‐fiber ⁻¹ during DAC cycling and is assembled into a ten‐fiber module. These results demonstrate a large step toward practical application of this material.

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Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE

OSTI ID:: 1981411

Alternate ID(s):: OSTI ID: 1995344

Journal Information:: Energy Technology, Vol. 10, Issue 9; ISSN 2194-4288

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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42 ENGINEERING
Energy & Fuels
adsorption
amines
CO2
direct air capture
fibers

Title: Directly Spun Epoxy-Crosslinked Polyethylenimine Fiber Sorbents for Direct Air Capture and Postcombustion Capture of CO2

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References (34)

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Title: Directly Spun Epoxy-Crosslinked Polyethylenimine Fiber Sorbents for Direct Air Capture and Postcombustion Capture of CO₂